Provided are novel ethylene acid copolymers, their ionomers and their use in various articles, including packaging films and injection molded articles. The ethylene acid copolymers comprise copolymerized units of ethylene, about 10 to about 30 wt % of copolymerized units of a first α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms; and about 5 to about 15 wt % of copolymerized units of a derivative of a second α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms. Preferred derivatives include esters, and in particular alkyl esters. These ethylene acid copolymers and ionomers have improved optical properties when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

A golf ball 2 includes a core 4, a mid layer 6, a cover 8, and dimples 10. A difference DH in hardness between a surface and a central point of the core 4, a thickness Tm and a hardness Hm of the mid layer 6, a thickness Tc and a hardness Hc of the cover 8, and an amount of compressive deformation Sb meet the following mathematical formulas.

(DH*Hm)/(Hc*Tc)>80

((Sb*Tc)/(Hc* Hm*Tm))*1000>0.75

An area ratio So of dimples 10 and a ratio Rs of a number of the dimples 10 each having a diameter of equal to or greater than 9.60% but equal to or less than 10.37% of a diameter of the golf ball 2 meet the following mathematical formula (3).

Rs≧−2.5*So+273   (3)

A positioning system includes a golf ball and a mobile terminal. The golf ball includes a battery and a transmitter configured to operate with electric power supplied from the battery and transmit a radio signal to outside of the golf ball. The mobile terminal includes a receiver configured to receive the radio signal from the golf ball and a processor configured to measure the position of the mobile terminal, and to measure the position of the golf ball based on the strength of the radio signal received by the receiver at two or more points at which the measured position of the mobile terminal differs.

A golf ball includes: a radio frequency identification (RFID) tag including an IC chip and an antenna; a protection layer surrounding the outer periphery of the RFID tag; a relaxation layer surrounding the outer periphery of the protection layer; a core surrounding the outer periphery of the relaxation layer; and a cover surrounding the outer periphery of the core. The curing temperature of the protection layer is 60° C. or less, and the protection layer is formed with a material having a hardness of Shore D 60 or more. The relaxation layer is formed with a thermoplastic elastomer-based material having a hardness with a difference from a hardness of a surface of the core on a side contacting the relaxation layer of Shore D 20 or less.

In a golf ball having a core and a cover of at least one layer encasing the core, the core is a product molded under heat from a rubber composition which includes (A) a base rubber, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) an organic peroxide. Letting the content of component (B) in the rubber composition per 100 parts by weight of component (A) be X parts by weight and the concentration of volatile substances from component (B) within the core be A wt %, the value A/X is 0.0123 or less. This golf ball has a low energy loss, enabling a high initial velocity to be obtained.

A rubber composition for golf balls includes (A) a base rubber, (B) two different metal salts of α,β-unsaturated carboxylic acids having 3 to 8 carbon atoms, (C) a metal salt in which at least one bonding site is a fatty acid of 9 or more carbon atoms, and (D) a crosslinking initiator. Letting component (B) include (B-1) an unsaturated metal carboxylate in a high compounding weight and (B-2) an unsaturated metal carboxylate in a low compounding weight, the ratio (B-2)/(B-1) is from 4 to 20 wt % and the ratio (B-2)/(C) is from 20 to 115 wt %. By using this rubber composition in a golf ball core, the golf ball can be endowed with both good spin properties and good durability on impact.

A golf ball includes a core having an outer surface and a geometric center; an inner cover layer, and an outer cover layer. The inner cover layer includes an ionomeric material and has a material hardness of about 60 Shore D or greater. The outer cover layer is formed from a polyurea or polyurethane and has a material hardness of about 60 Shore M or greater. The outer surface of the core has a hardness of about 68 to 92 Shore C. The geometric center of the core has a hardness of about 45 to 85 Shore C. The core outer surface hardness is greater than the geometric center hardness by about 5 to 21 Shore C to define a positive hardness gradient. The core also has a volume weighted average hardness, H.sub.V, of about 70 to 80, where

[00001]${\stackrel{\_}{H}}_V=\frac{I_V}{V_c}.$

A method of manufacturing golf balls having a core and a cover of at least one layer encasing the core includes the steps of producing a core by molding and vulcanizing a rubber composition containing (A) a base rubber, (B) an α,β-unsaturated carboxylic acid and/or a metal salt thereof, and (C) an organic peroxide; and heat-treating the core for 1 to 24 hours at between 175 and 300° C. Golf balls which undergo little energy loss and have a high initial velocity can be obtained by this method.

In a golf ball having a core and a cover of at least one layer, the core and/or at least one layer of the cover are formed of a resin composition that includes (A) 100 parts by weight of a thermoplastic resin, and (B) 1 to 30 parts by weight of a compound having a fluorene skeleton, or a derivative thereof. This resin composition for golf balls has an improved injection-moldability and thus enables the ball to achieve both a reduced spin rate and a good durability (scuff resistance).

In a golf ball having a core and a cover of one or a plurality of layers that encases the core, the core or at least one layer of the cover is formed of a resin composition which contains from 5 to 250 parts by weight of a mechanoluminescent material that receives mechanical energy and luminesces per 100 parts by weight of a base material which is a rubber material or a resin material. This golf ball has an excellent visibility in that, even under dark conditions, the ball impact site can be clearly confirmed visually at the time of impact. Moreover, the ball is able to maintain a good scuff resistance.