Methods and systems for forming crystallized products from solutions. Such a method includes depositing an input material in a solvent mixture comprising a solvent and an anti-solvent, increasing the temperature of the solvent mixture with the input material therein to an elevated temperature for a period of time sufficient to fully dissolve the input material in the solvent mixture to form a solution of the material, and performing a series of temperature cycles on the solution to produce a crystallized product from the material in the solution. The solution is alternated between heating cycles and cooling cycles based on the turbidity of the solution, and the solution is filtered to remove and collect the crystallized product therefrom.

The invention relates to a device for drawing off liquid salt, particularly for facilities for purifying wastewater, said device comprising a heating chamber. The heating chamber comprises an inlet for introducing a salt-containing substance and is connected to an outlet for a salt melt. The outlet comprises an outlet channel and an outlet channel end, a cooling region for cooling the salt melt being provided downstream of the outlet channel end. The outlet channel is peripherally surrounded by an outlet wall at least along a section, the outlet comprising a heating element.

A method of treating fly ash containing sodium sulfate from a recovery boiler of a chemical pulp mill. This method includes at least the following steps: a) ash is dissolved in an aqueous solution and the pH of the solution is adjusted with alkali for precipitating impurities, b) the solution is filtered for removing the impurities containing precipitate, c) sodium sulfate is crystallized from the solution and the crystals are separated from the solution by filtering or by centrifugation, and d) the crystallized sodium sulfate is used as initial material for producing sodium and sulfur containing chemicals or as process chemical.

A process to treat water includes adding a salt-forming base to the water thereby producing saline water, or thereby forming a salt in the water which is different from a salt that the water started out with, if the water started out as saline. The saline water is treated, at a temperature T1 which is above the saturation temperature of the saline water, in a first membrane separation stage to provide clean water and a first brine, the salinity of the first brine being higher than the salinity of the saline water. The first brine is cooled to a temperature T2 to precipitate some of the salt from the first brine and the precipitated salt is separated from the first brine producing a second brine, the temperature T2 being below the temperature T1 but above the freezing temperature of the first brine. The second brine is treated at a temperature T3 above the saturation temperature of the second brine in a second membrane separation stage to provide clean water and a third brine. The salt-forming base, the temperature T1 and the temperature T2 are selected so that the salt which is formed in the saline water has a solubility in water at the temperature T1 which is at least 1.5 times the solubility of the salt in water at the temperature T2.

Described is a method of selectively isolating non-rigid structure meroterpenes (for example, cannabidiolic acid) from a complex matrix that may also contain rigid structure meroterpenes (for example, THCa), comprising selectively precipitating the non-rigid structure meroterpenes in the form of a triethylamine salt complex by adding triethylamine; isolating the triethylamine salt complex from the mother liquor; then heating the triethylamine salt complex to vaporize the triethylamine, leaving an isolated neutral non-rigid structure meroterpene. In certain embodiments, the starting product is a cannabis resin that has been solubilized in, for example, d-limonene.

A method for drying and purifying a lithium bis(fluorosulfonyl)imide salt. Also, a method for producing a lithium bis(fluorosulfonyl)imide salt which is then dried and purified by the method. Further, a composition containing lithium bis(fluorosulfonyl)imide salt having a water content by mass of between 5 and 45 ppm. And, the use of the composition C in Li-ion batteries.

Methods and systems for treating brine to produce distilled water and dried NaCl are disclosed. The brine enters a crystallization plant and is heated. Once heated, the brine is circulated to an evaporator. The evaporator increases the concentration of NaCl in the brine to a point about the super saturation level. Once above the super saturation level, NaCl crystals are formed. The larger crystals are circulated to a centrifuge for drying and the smaller crystals are recirculated through the evaporator for continued growth. The NaCl crystals are dried in the centrifuge.

A chemical reaction device that supplies a raw material liquid into a solution and causes particles to precipitate in the solution is provided. The chemical reaction device includes an agitation tank configured to accommodate the solution, an impeller configured to agitate the solution, and a plurality of discharge parts configured to discharge the raw material liquid into the solution.

Disclosed is a method for fast and cost-efficient preparation of ikaite crystals. The method comprises contacting an alkaline aqueous solution, which comprises carbonate and bicarbonate ions, with a water solution, which comprises Ca.sup.2+, at a temperature not exceeding 15° C., wherein contact between the alkaline aqueous solution and the water solution takes place at a permeable or porous surface, through which either solution is fed to the other at a flow rate facilitating formation of ikaite crystals. Also disclosed is system for carrying out the ikaite preparation process. The process and system provides a cost efficient and effective means for capture and storage of carbon dioxide.

The present invention includes compositions and methods for preparing micron-sized or submicron-sized particles by dissolving a water soluble effective ingredient in one or more solvents; spraying or dripping droplets solvent such that the effective ingredient is exposed to a vapor-liquid interface of less than 50, 100, 150, 200, 250, 200, 400 or 500 cm.sup.−1 area/volume to, e.g., increase protein stability; and contacting the droplet with a freezing surface that has a temperature differential of at least 30° C. between the droplet and the surface, wherein the surface freezes the droplet into a thin film with a thickness of less than 500 micrometers and a surface area to volume between 25 to 500 cm.sup.−1.