The invention generally relates to osmotically driven membrane systems and processes and more particularly to increased brine concentration for zero liquid discharge using osmotically driven membrane systems and processes and the related draw solute recovery techniques for the osmotically driven membrane systems and processes.

The invention relates to a method and apparatus for treatment of produced or process water from hydrocarbon production to reduce the volume of the produced or process water while simultaneously reducing the salinity of a highly saline stream, for example, the brine from a seawater desalination plant. The method includes causing a feed stream comprising produced or process water to flow through the lumen of a hollow fiber osmotic membrane 4 which is immersed in an open channel 2 or tank of flowing draw solution 6 which has high salinity. In this way, water from the feed stream is drawn through the osmotic membrane 4 by an osmotic pressure differential caused by the difference in salinity between the feed stream and the draw solution 6.

An ocean alkalinity enhancement (OAE) system that reduces atmospheric CO.sub.2 and mitigates ocean acidification by electrochemically processing feedstock solution (e.g., seawater or brine) to generate an alkalinity product that is then supplied to the ocean. The OAE system includes a base-generating device and a control circuit disposed within a modular system housing deployed near a salt feedstock. The base-generating device (e.g., a bipolar electrodialysis (BPED) system) generates a base substance that is then tested and processed (e.g., mixed/diluted with processed feedstock solution, seawater or another saltwater solution and/or reacted with CO.sub.2) to generate the ocean alkalinity product. The control circuit controls the base-generating device such that the alkalinity product is supplied to the ocean only when supplying the alkalinity product will not endanger sea life. Modified BPED systems include features that facilitate autonomous system operations including enhanced maintenance cycle operations and a reduced reliance on external fresh water sources.

A water filtration system with power generating capability includes a membrane that receives relatively hot water on a dirty side, purifies the hot water, and transmits it to a clean side having relatively cold purified water. The system further includes at least one thermoelectric element coupled to the membrane that absorbs thermal energy from the dirty side and emits thermal energy into the clean side to generate electrical power. The system further includes at least one conductor electrically coupled to the at least one thermoelectric element that channels generated electrical power away from the at least one thermoelectric element.

A water filtration system with power generating capability includes a membrane that receives relatively hot water on a dirty side, purifies the hot water, and transmits it to a clean side having relatively cold purified water. The system further includes at least one thermoelectric element coupled to the membrane that absorbs thermal energy from the dirty side and emits thermal energy into the clean side to generate electrical power. The system further includes at least one conductor electrically coupled to the at least one thermoelectric element that channels generated electrical power away from the at least one thermoelectric element.

The invention relates to 100% renewably-powered desalination/water purification stations for universal applications, the station is disruptive, scalable, amphibious and deportable to seawater, brackish or spill oil sites for simple wave-powered and autonomous operations, the station has a mooring assembly with pumping-purification-delivery subsystems powered by wave and solar energies, the pumping subsystems has the simplest, most efficient wave push/pull pump mechanisms powered by amplified wave centrifugal forces , the mechanical purifications has turbine filters, reverse-osmosis filters, forward-osmosis filters and relief valves to backwash buildups without releasing brine, release water through collecting spill oil, the solar thermal purifications are provided with distilling processes under vaccine conditions, the delivery subsystems with wave turbines and solar panels for generating electricity, propellering and transferring the stations for delivering fresh waters to destinations under GPS guide with the lowest LCOW.

Provided herein are filtration membranes, method of manufacturing said membranes and use of such membranes for the removal of substances from fluids or substances.

Systems and methods for removing a contaminant from a liquid are generally described. The liquid (e.g., water) containing the contaminant may be flowed across a semipermeable membrane (e.g., via forward osmosis) that is not permeable to the contaminant in order to remove the contaminant from the liquid. A concentration gradient across the semipermeable membrane may be provided and maintained by electrolysis of the liquid and can drive forward osmosis of the liquid through the semipermeable membrane.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

A complete kit, including components to assemble a U-tube apparatus, materials, and methods of using thereof, for the purpose of osmosis pedagogy, is described. The self-contained kit makes possible hands-on osmosis experiments that may be conducted safely at home, and is well-suited for STEM (science, technology, engineering and mathematics) education. The kit supplies unmodified glycerin and unmodified dextran as solutes, and components to assemble a watertight U-tube apparatus capable of accurate, repeatable quantitative measurements and bidirectional osmosis. One method describes osmotic rate measurements using glycerin as solute under varying parameters of solute concentration, temperature, and osmosis direction. Another method describes the comparison of experimental measurement of osmotic pressure at equilibrium to theoretical prediction using dextran as solute.