Compositions and methods directed to the production of single layer, highly porous, free-standing polytetrafluoroethylene (PTFE) membranes having macro-textured surfaces are provided. The macro-textured surfaces are due to the presence of macroscopic nodal aggregates within the membrane that are connected by fibrils The membranes have high porosity, high airflow, and a bulk density less than 1.0 g/cm3. Articles comprising the porous, single layer PTFE membranes are also provided.

The present invention relates to new anion exchange polymers and (blend) membranes made from polymers containing highly fluorinated aromatic groups by means of nucleophilic substitution and processes for their production by means of nucleophilic aromatic substitution and their areas of application in membrane processes, in particular in electrochemical membrane processes such as fuel cells, electrolysis and redox flow batteries.

The present application relates to an unsupported, permanently hydrophilic filtration membrane, and its method of formation. The membrane comprises a polymeric matrix material and a cross-linked polyoxazoline hydrophilic additive blended throughout said matrix material.

A method for manufacturing a component and a component are provided for sensing a molecule. The method includes controlling a temperature during a reaction of two gases that react to produce a crystalline film spanning at least a cross-sectional area of a nanoaperture defined by a substrate among an array of nanoapertures aligned with crater structures defined by the substrate. A unique chemical vapor deposition (CVD) method that introduces a first gas and a second gas allows for formation of the crystalline film. When used in a molecule sensor, the component enables a user to record double-stranded DNA (dsDNA) translocations at unprecedented high (e.g., 1 MHz) bandwidths. The method for manufacturing the component enables development of applications requiring single-layer membranes built at- scale and enables high throughput 2-dimensional (2D) nanofluidics and nanopore studies.

The present disclosure relates to a composite membrane formed by lamination of two or more separate porous polymeric layers, as well as to a method and system for lamination. Advantageously, the resulting composite is a single layer, being difficult to separate into its component layers, yet effectively maintains the filtering capabilities of the component layers when not laminated.

The present application relates to a multizone, unsupported, microporous, high throughput membrane. The membrane includes a first microporous zone, a second microporous zone, and a third microporous zone, where the third microporous zone is positioned between the first and second microporous zones, with the first, second, and third microporous zones being integral with one another. Further aspects of the present application include a process for making the membrane and a filtration cartridge with the membrane of the present application.

Disclosed herein a monovalent-ion-selective composite membrane comprising a polymeric cation exchange membrane and a metal-oxide-based layer, wherein said metal-oxide-based layer comprises a metal oxide or an organic-inorganic hybrid polymer, of e.g. Zn, Al, Mg, Si, Cu, W, Ni, or Ti. Also disclosed are the methods for the preparation of the membrane, and also electrodialysis assemblies comprising the membranes.

A provided stretched porous polytetrafluoroethylene membrane has a node-fibril structure including a plurality of nodes and a fibril connecting the plurality of nodes. A ratio of an average length of the plurality of nodes in a thickness direction of the stretched porous polytetrafluoroethylene membrane to a thickness of the stretched porous polytetrafluoroethylene membrane is 10% or more. The above stretched porous polytetrafluoroethylene membrane is less likely to suffer breakage. In the above stretched porous polytetrafluoroethylene membrane, assuming that there is a cuboid region having an upper surface and a lower surface respectively positioned at one membrane surface and the other membrane surface of the stretched porous polytetrafluoroethylene membrane, the number of the nodes included in the region may be 4 or less per micrometer thickness, the upper surface and the lower surface each having dimensions of 280 μm×280 μm.

Methods of making membrane elements for fluid or gas filtration, comprising applying feed or reject spacers, or intermediate spacers, or fold line protection strips, or end support strips directly to a membrane sheet, or to a substrate material which are subsequently applied to a membrane sheet, which thereby avoids contamination from directly printed adhesives, inks, or polymers, or damage from heat or radiation damage to the membrane sheet during direct application of spacers or patterns to the surface of the membrane sheet, thereby avoiding utilization of conventional feed spacer mesh materials. Membrane sheets and spiral wound filtration elements having spacers applied to defined regions of the sheet, in some embodiments having spacers mounted on substrates with different material properties, e.g., stiffness, than the underlying membrane.

An ink for three dimensional printing a ceramic material includes metal oxide nanoparticles and a polymer resin, where a concentration of the metal oxide nanoparticles is at least about 50 wt % of a total mass of the ink. A method of forming a porous ceramic material includes obtaining an ink, where the ink comprises a mixture of metal oxide nanoparticles and a polymer, forming a body from the ink, curing the formed body, heating the formed body for removing the polymer and for forming a porous ceramic material from the metal oxide nanoparticles. The forming the body includes an additive manufacturing process with the ink.