Patent classifications
B01J6/00
HIGH-TEMPERATURE SHOCK HEATING FOR THERMOCHEMICAL REACTIONS
One or more reactants are flowed into thermal contact with a heating element in a reactor for a first time period. During a first part of a heating cycle, the one or more reactants are provided with a first temperature by heating with the heating element, such that one or more thermochemical reactions is initiated. The one or more thermochemical reactions includes pyrolysis, thermolysis, synthesis, hydrogenation, dehydrogenation, hydrogenolysis, or any combination thereof. The first heating element operates by Joule heating and has a porous construction that allows gas to flow therethrough. During a second part of the heating cycle, the one or more reactants are provided with a second temperature less than the first temperature, for example, by de-energizing the heating element. A duration of the first time period is equal to or greater than a duration of the heating cycle, which is less than five seconds.
CATALYST COMPOSITION FOR DEGRADATION OF ORGANIC COMPOUND USING IRON OXIDE, PREPARATION METHOD THEREOF, AND METHOD FOR DEGRADATION OF ORGANIC COMPOUND USING THE SAME
The present disclosure relates to a catalyst that removes an organic compound by using a metal oxide catalyst and a preparation method thereof and a method for degradation of an organic compound using the same. Particularly, the present disclosure relates to a copper-iron oxide (Cu—Fe.sub.2O.sub.3) catalyst composition that is prepared by following steps of: adding a mixed solution of an iron (Fe) precursor and a copper (Cu) precursor to a precipitator solution (S1); obtaining precipitates by heating a solution prepared in the step S1 (S2); obtaining a metal oxalate by filtering the precipitates obtained in the step S2 (S3); drying the metal oxalate obtained in the step S3 (S4); and obtaining a copper-iron oxide catalyst by calcinating the metal oxalate subjected to the step S4 (S5) and a method for removal of an organic compound using the same.
Shaped catalyst body in the form of tetralobes of uniform wall thickness
The invention relates to a shaped catalyst body in the form of a tetralobe having four circular through-passages, with the midpoints of the through-passages forming a square and the spacings between in each case two adjacent through-passages being from 0.8 to 1.2 times the thickness of the outer walls of the through-passages. The shaped catalyst body is used for the oxidation of S02 to S03.
Method and device for producing lithium transition metal oxide
Provided is a method for producing a lithium transition metal oxide, comprising, A) mixing a lithium salt and a precursor, adding the mixture into a reactor for precalcination; the lithium salt has a particle size D50 of 10-20 μm and the precursor has a particle size D50 of 1-20 μm, and the precursor is one or more selected from transition metal oxyhydroxide, transition metal hydroxide and transition metal carbonate; and B) adding the product obtained from the precalcination into a fluidized bed reactor, subjecting to a first calcination and a second calcination to obtain the lithium transition metal oxide. Raw materials for the lithium transition metal oxide further includes a main-group metal compound containing oxygen, which is added in the precalcination, the first calcination or the second calcination; and the main-group metal compound containing oxygen has an average particle size of 10-100 nm. A fluidized bed reactor is also provided.
Oxidation catalysts for destructing VOCs which contain light alkane compounds in emissions
Disclosed herein are monolith oxidation catalysts for the destruction of CO and volatile organic compounds (VOC) chemical emissions, in particular, the destruction of light alkane organic compounds. The catalysts contain high surface area refractory oxides of silica- and hafnia-doped zirconia and silica, or tin oxide or stabilized alumina; and at least one platinum group metals, in particular platinum metal, or a combination of platinum and palladium.
Method of recycling carbon to a feedstock gas reactor
A method of using a feedstock gas reactor is described. A hydrocarbon, such as methane, is chemical decomposed in the feedstock gas reactor using heat of combustion generated from the combustion of a combustible gas. A mixed product stream is extracted from the feedstock gas reactor. The mixed product stream comprises hydrogen, carbon, and water. At least a portion of the one or more combustion product gases are vented from the combustion chamber. At least some of the carbon is activated using the vented one or more combustion product gases. At least some of the activated carbon is recycled to the feedstock gas reactor.
ULTRA-LOW EMISSION ETHYLENE PLANT
The invention relates to an ethylene plant, comprising a cracking furnace for converting a hydrocarbon feedstock into a cracked gas stream; a separation section to provide at least an ethylene-enriched product stream, a hydrogen-enriched fuel stream and a methane-enriched fuel stream from the cracked gas stream; a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of the cracking furnace and/or a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of a waste heat recovery boiler of a combined cycle gas turbine power plant(CCGT); a methane storage configured for storing methane-enriched fuel and a passage way for feeding at least part of the methane-enriched fuel from the separation section to the storage; the CCGT, comprising a gas turbine—comprising a combustor—and a passage way for feeding at least part of the methane-enriched fuel from the storage to the combustor of the gas turbine of the CCGT, which CCGT is configured to generate electric power and/or to generate high pressure steam to drive a steam turbine forming part of a steam generation circuit of the ethylene plant; and an electric power connection for providing part of the power for operating the plant, which is a connection to an electric power system to produce electric power from a renewable source.
ULTRA-LOW EMISSION ETHYLENE PLANT
The invention relates to an ethylene plant, comprising a cracking furnace for converting a hydrocarbon feedstock into a cracked gas stream; a separation section to provide at least an ethylene-enriched product stream, a hydrogen-enriched fuel stream and a methane-enriched fuel stream from the cracked gas stream; a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of the cracking furnace and/or a passage way for feeding at least part of the hydrogen-enriched fuel from the separation section to a burner of a waste heat recovery boiler of a combined cycle gas turbine power plant(CCGT); a methane storage configured for storing methane-enriched fuel and a passage way for feeding at least part of the methane-enriched fuel from the separation section to the storage; the CCGT, comprising a gas turbine—comprising a combustor—and a passage way for feeding at least part of the methane-enriched fuel from the storage to the combustor of the gas turbine of the CCGT, which CCGT is configured to generate electric power and/or to generate high pressure steam to drive a steam turbine forming part of a steam generation circuit of the ethylene plant; and an electric power connection for providing part of the power for operating the plant, which is a connection to an electric power system to produce electric power from a renewable source.
PHOSPHORUS-CONTAINING/PHOSPHORUS-MODIFIED ZSM-5 MOLECULAR SIEVE, CRACKING AUXILIARY AND CRACKING CATALYST CONTAINING THE SAME, PROCESS OF PREPARING THE SAME, AND USE THEREOF
A phosphorus-containing or phosphorus-modified ZSM-5 molecular sieve is characterized in that in its 27Al MAS-NMR, the ratio of peak area for the resonance signal having a chemical shift of 39±3 ppm to peak area for the resonance signal having a chemical shift of 54 ppm±3 ppm is ≥1; or in its surface XPS elemental analysis, the value of n1/n2 is ≤0.1. n1 represents the mole number of phosphorus, n2 represents the total mole number of silicon and aluminum. A cracking auxiliary or cracking catalyst contains the phosphorus-containing/phosphorus-modified ZSM-5 molecular sieve can be made using the phosphorus-containing or phosphorus-modified ZSM-5 molecular sieve.
Method for preparation of metal nanowires
The present invention refers to a method for the preparation of zero-valent-transition metal nanowires such as crystalline silver nanowires, and to a reactor oven for the preparation of zero-valent-transition metal nanowires.