A reactor system includes a reactor vessel configured to contain a process fluid, and a sparger assembly that operably coupled to the reactor vessel and configured to supply a mixture of a gas and a recirculated process fluid to the reactor vessel. The sparger assembly includes a plurality of sparger chambers. Each sparger chamber includes a process fluid conduit fluidly coupled to a process fluid return of the reactor vessel via a process fluid inlet, wherein the process fluid inlet has a first block and bleed valve assembly. Each sparger chamber includes a sparger conduit fluidly coupled to the process fluid conduit and a sparger disposed within the sparger conduit and fluidly coupled to a gas source via a gas inlet. Each sparger chamber also includes a process fluid-gas mixture outlet that fluidly couples the sparger conduit to a sparger outlet of the reactor vessel.

Apparatuses and processes that produce multimodal polyolefins, and in particular, polyethylene resins, are disclosed herein. This is accomplished by using two reactors in series, where one of the reactors is a multi-zone circulating reactor that can circulate polyolefin particles through two polymerization zones optionally having two different flow regimes so that the final multimodal polyolefin has improved product properties and improved product homogeneity.

The invention provides a thermal cracking system which comprises a reactor, and a feed module or a solid product discharge module. The feed module transports a feed material from the outside environment to the reactor. While being transported, the feed material is heated by the feed module to become molten and fills up the interior of the feed module, thereby preventing air from entering the reactor. The solid product discharge module transports a solid product from the reactor to the outside environment. One end of the solid product discharge module is connected with the reactor. The other end of the solid product discharge module comprises a first opening interfacing with the outside environment. When the solid product is transported to the outside environment, the opening size of the first opening is selected such that the speed at which the solid product is entering the solid product discharge module form the reactor is equal to or greater than that at which the solid product is leaving the solid product discharge module, through the first opening, and into the outside environment. Benefit of the invention includes a higher production efficiency and enhanced safety for a thermal cracking system at industrial scale.

A method of agglomerating nanoparticles to form larger agglomerates is shown. The nanoparticles are mixed with a resin to form a first mixture (803) of agglomerates, having sizes over a range that includes agglomerates considered to be too large, suspended in the resin. A bead milling cylinder (802) produces a second mixture (808) with fewer large agglomerates. A filter (1001) removes the remaining large agglomerates. The resulting mill base is cut with a solvent before deployment.

A cyclic metals deactivation system unit for the production of equilibrium catalyst materials including a cracker vessel configured for cracking and stripping a catalyst material; and a regenerator vessel in fluid communication with the cracker vessel, the regenerator vessel configured for regeneration and steam deactivation of the catalyst material.

The invention provides an improved system for separation technology intended to reduce unwanted catalyst/thermal reactions by minimizing contact of the hydrocarbons and the catalyst within the reactor.

A method for removing boron is provided, which includes (a) mixing a carbon source material and a silicon source material in a chamber to form a solid state mixture, (b) heating the solid state mixture to a temperature of 1000° C. to 1600° C., and adjusting the pressure of the chamber to 1 torr to 100 torr. The method also includes (c) conducting a gas mixture of a first carrier gas and water vapor into the chamber to remove boron from the solid state mixture, and (d) conducting a second carrier gas into the chamber.

Methods of reducing heat exchanger fouling rate or of producing polyolefins may include providing a first gas stream comprising a gas and entrained fine polyolefin particles to a gas outlet line; removing a portion of the entrained fine polyolefin particles from the gas outlet line to form a bypass stream; and providing the bypass stream to a bypass line comprising a bypass line inlet and a bypass line outlet. The bypass line inlet and outlet are located upstream and downstream of a first heat exchanger. The methods may further include providing at least a portion of the first gas stream to the first heat exchanger; and combining the bypass stream and a second gas stream at the bypass line outlet to form a combined gas stream comprising one or more olefins or paraffins. A temperature of the combined gas stream is below the dew point of the combined gas stream.

The invention relates to a lining (10) intended to be positioned inside a chamber (1) to promote contact between fluids circulating inside said chamber, said lining comprising a plurality of separate criss-crossing strips (12): —first strips (12.1i) parallel to a first direction (D1) and defining a plurality of first planes spaced apart from each other, —second strips (12.2i) parallel to a second direction (D2) forming an angle with the first direction (D1) and defining a plurality of second planes spaced apart from each other. In each first plane, a free space separates two first adjacent strips I a direction perpendicular to the first direction and receives a second strip, the first and second strips being secured together. Each separate strip of at least one stage is perforated (12) and selected from a strip made from a stamped metal sheet and a strip made from an expanded metal sheet.

The system includes a reactor vessel having a reactor space bound by a reactor wall. The reactor vessel is arranged for holding a mixture of a catalyst and formic acid in the reactor space. The reactor vessel includes a mixture inflow opening for allowing the mixture to enter the reactor space and a mixture outflow opening for allowing said mixture to exit the reactor space, and a gas outflow opening for allowing hydrogen originating from the mixture to exit the reactor space. A method for hydrogen production includes: providing the formic acid and the catalyst into the reactor space; withdrawing the mixture from the reactor space; heating and/or cooling the mixture to a predetermined temperature range outside the reactor space; and introducing the heated and/or cooled mixture into the reactor space in a predetermined direction having a tangential component arranged for stirring said mixture in the reactor space.