Patent classifications
B01J29/00
Hydroisomerization catalyst manufactured using a high nanopore volume alumina supports
The present invention is directed to an improved finished hydroisomerization catalyst manufactured from a first high nanopore volume (HNPV) alumina and a pore size distribution characterized by a full width at half-maximum, normalized to pore volume, of 15 to 25 nm.Math.g/cc, and a second HNPV alumina having a pore size distribution characterized by a full width at half-maximum, normalized to pore volume, of 5 to 15 nm.Math.g/cc. Their combination yields a HNPV base extrudate having a low particle density as compared to a conventional base extrudates.
Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation
Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-70%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element(s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.
PASSIVE NOx ADSORBER
A NO.sub.x absorber catalyst for treating an exhaust gas from a lean burn engine. The NO.sub.x absorber catalyst comprises a molecular sieve catalyst comprising a noble metal and a molecular sieve, wherein the molecular sieve contains the noble metal; an oxygen storage material for protecting the molecular sieve catalyst; and a substrate having an inlet end and an outlet end.
Stable catalysts for electroless metallization
Catalysts include nanoparticles of catalytic metal and cellulose or cellulose derivatives. The catalysts are used in electroless metal plating. The catalysts are free of tin.
Catalyst blends
Provided is a catalyst for the selective reduction of NOx comprising a two molecular sieve materials having a CHA structure, wherein the first molecular sieve has a mean crystal size of about 0.01 to 1 m and the second molecular sieve has a mean crystal size of about 1-5 m, and wherein the first molecular sieve contains a first extra-framework metal, the second molecular sieve contains a second extra-framework metal, and wherein said first and second extra-framework metals are independently selected from the group consisting of cesium, copper, nickel, zinc, iron, tin, tungsten, molybdenum, cobalt, bismuth, titanium, zirconium, antimony, manganese, chromium, vanadium, niobium, and combinations thereof.
Zoned catalysed substrate monolith
A zoned catalyzed substrate monolith comprises a first zone and a second zone that are arranged axially in series. The first zone comprises a platinum group metal loaded on a support and a first base metal oxide or a first base metal loaded on an inorganic oxide. The first base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The first base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second zone comprises copper or iron loaded on a zeolite and a second base metal oxide or a second base metal loaded on an inorganic oxide. The second base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The second base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second base metal is different from the first base metal.
ZONED AMMONIA SLIP CATALYST FOR USE IN COMBUSTION TURBINES
A catalytic article for treating an exhaust gas stream containing one or more of NOx, hydrocarbons, CO, SOx and ammonia from a combustion turbine comprises (a) a substrate having an inlet end and an outlet end defining an axial length; (b) an oxidation layer comprising an oxidation catalyst comprising one or more noble metals, the oxidation layer being positioned on the substrate and covering the axial length of the substrate; and (c) an SCR layer comprising an SCR catalyst, the SCR layer being positioned on the oxidation layer and overlapping a portion of the oxidation layer, wherein the portion is less than 100%.
Visible-light-responsive photocatalyst powder, method of manufacturing the same, and visible-light-responsive photocatalytic material, photocatalytic coating material and photocatalytic product each using the same
A visible-light-responsive photocatalyst powder includes a tungsten oxide powder. When the tungsten oxide powder is measured by X-ray diffractometry, (1) among intensity ratios of a peak A (2=22.8 to 23.4), a peak B (2=23.4 to 23.8), a peak C (2=24.0 to 24.25), and a peak D (2=24.25 to 24.5), an A/D ratio and a B/D ratio each fall within a range of 0.5 to 2.0, and a C/D ratio falls within a range of 0.04 to 2.5, (2) an intensity ratio (E/F) of a peak E (2=33.85 to 34.05) to a peak F (2=34.05 to 34.25) falls within a range of 0.1 to 2.0, and (3) an intensity ratio (G/H) of a peak G (2=49.1 to 49.7) to a peak H (2=49.7 to 50.3) falls within a range of 0.04 to 2.0, and the tungsten oxide powder has a BET specific surface area in a range of 1.5 to 820 m.sup.2/g.
Method for the preparation of a hydrocarbon synthesis catalyst material and the use thereof in a hydrocarbon synthesis process
This invention relates to a method for the preparation of a hydrocarbon synthesis catalyst material, in the form of a hydrocarbon synthesis catalyst precursor and/or catalyst, preferably, a Fischer Tropsch synthesis catalyst precursor and/or catalyst. The invention also extends to the use of a catalyst precursor and/or catalyst prepared by the method according to the invention in a hydrocarbon synthesis process, preferably, a Fischer Tropsch synthesis process. According to this invention, a method for the preparation of a hydrocarbon synthesis catalyst material includes the steps of treating Fe(II) carboxylate in solution with an oxidizing agent to convert it to Fe(III) carboxylate in solution under conditions which ensure that such oxidation does not take place simultaneously with any dissolution of Fe(0); and hydrolyzing the Fe(III) carboxylate solution resulting from step (iii) and precipitating one or more Fe(III) hydrolysis products.
Method for treating arsenic-containing aqueous solution
Provided is a method for treating an arsenic-containing aqueous solution by water treatment employing a titanium dioxide photocatalyst that is excellent in both photocatalytic activity and solid-liquid separation performance. The method according to the present disclosure includes the steps: of adding catalyst particles to the aqueous solution; oxidizing trivalent arsenic by irradiating the aqueous solution with light having a wavelength of 200 nanometers or more and 400 nanometers or less while stirring the catalyst particles in the aqueous solution; and stopping the stirring and separating the catalyst particles from the aqueous solution by sedimentation. Each catalyst particle is composed only of a titanium dioxide particle and a zeolite particle, the titanium dioxide particle is adsorbed on the outer surface of the zeolite particle, the zeolite particle has a silica/alumina molar ratio of 10 or more, and the catalyst particles are contained in the aqueous solution at a concentration of 0.4 grams/liter or more and 16 grams/liter or less.