Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.

A honeycomb structure, including: a pillar-shaped honeycomb structure body having a first end face and a second end face and including a porous partition wall disposed so as to surround a plurality of cells, the plurality of cells extending from the first end face to the second end face and serving as a through channel of fluid, wherein the partition wall has a porosity of 45 to 65%, the partition wall has an average pore diameter of 15 to 25 μm, and the partition wall has a cumulative pore volume, which is measured by mercury intrusion porosimetry, such that a pore volume ratio of pores having pore diameters of 10 μm or less relative to the overall pore volume of the partition wall is 10% or less, and a pore volume ratio of pores having pore diameters of 40 μm or more is 10% or less.

A honeycomb structure, including: a pillar-shaped honeycomb structure body having a first end face and a second end face and including a porous partition wall disposed so as to surround a plurality of cells, the plurality of cells extending from the first end face to the second end face and serving as a through channel of fluid, wherein the partition wall has a porosity of 45 to 65%, the partition wall has an average pore diameter of 15 to 25 μm, and the partition wall has a cumulative pore volume, which is measured by mercury intrusion porosimetry, such that a pore volume ratio of pores having pore diameters of 10 μm or less relative to the overall pore volume of the partition wall is 10% or less, and a pore volume ratio of pores having pore diameters of 40 μm or more is 10% or less.

The present invention relates to a catalyst for oxidative dehydrogenation and a method of preparing the same. More particularly, the present invention provides a catalyst for oxidative dehydrogenation having a porous structure which may easily control heat generation due to high-temperature and high-pressure reaction conditions and side reaction due to the porous structure and thus exhibits superior product selectivity, and a method of preparing the catalyst.

The present invention relates to a process for the calcination of a zeolitic material, wherein said process comprises the steps of (i) providing a zeolitic material comprising YO.sub.2 and optionally further comprising X.sub.2O.sub.3 in its framework structure in the form of a powder and/or of a suspension of the zeolitic material in a liquid, wherein Y stands for a tetravalent element and X stands for a trivalent element; (ii) atomization of the powder and/or of the suspension of the zeolitic material provided in (i) in a gas stream for obtaining an aerosol; (iii) calcination of the aerosol obtained in (ii) for obtaining a calcined powder; as well as to a zeolitic material obtainable and/or obtained according the inventive process, and to its use as a molecular sieve, as an adsorbent, for ion-exchange, as a catalyst, and/or as a catalyst support.

According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m.sup.2/g and a pore volume of greater than 0.3 cm.sup.3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m.sup.2/g and a pore volume of greater than 0.3 cm.sup.3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

The invention relates to a molecular sieve modification method and a catalytic cracking catalyst containing a molecular sieve. The method comprises: mixing a solution containing an ion of a Group MB metal in the periodic table, an organic complexing agent, and/or a dispersant and a precipitation agent, and stirring the same to form a suspension containing a precipitant of a Group IIIB element; and mixing the resulting precipitant and a molecular sieve slurry, stirring the same to obtain a mixed slurry containing the precipitant of the Group MB element and a molecular sieve, and performing spray drying and optional calcination, to obtain a modified molecular sieve. The catalyst comprises, as calculated based on the catalyst mass being 100%, 10-55% of a modified molecular sieve (on a dry basis), 10-80% of clay (on a dry basis), 0-40% of an inorganic oxide (on an oxide basis), and 5-40% of a binding agent (on an oxide basis). The catalyst has good activity stability and heavy metal contamination resistance.

A method for preparing catalyst particles that includes providing an average atomic number Zavr for a catalyst starting material, providing an ion beam having an ion beam current and selecting an ion beam dose X expressed in ions/g, based on the weight of the catalyst starting material, where X follows the following equations: (7/Zavr)×10.sup.18 ions/g<X<(7/Zavr)×6×10.sup.19 ions/g, implanting the catalyst starting material with an ion beam dose X primarily comprising the selected ions, where the ratio of the current of the ion beam current to the cross-section area of the ion beam, measured at the point of contact with the catalyst starting material is at least 1.2 μA/mm.sup.2, thereby obtaining a catalyst. The resulting catalyst particles are useful in NOx, CO, and/or HC emission reduction devices, fuel cells, or catalysts in chemical reactions.

The present disclosure relates to a molecular sieve, preparation thereof and acoustic absorption material and speaker containing the same. The molecular sieve having an MFI-structure, comprising a framework and an off-framework cation, wherein the framework comprises SiO.sub.2 and a metal oxide M.sub.xO.sub.y with M comprising boron, gallium or aluminium; the off-framework cation is at least one of hydrogen ion, alkali metal ion and alkaline earth metal ion. The molecular herein can effectively prevent the failure of the molecular sieve and improve the performance stability of the speaker.