Patent classifications
B01J37/00
PROCESS FOR PREPARING A MOLDING COMPRISING A ZEOLITE CATALYST AND METHOD FOR CONVERTING OXYGENATES TO OLEFINS USING THE CATALYTIC MOLDING
The present invention relates to a process for preparing a molding comprising a zeolitic material and one or more oxidic binders, the process particularly comprising preparing a mixture of a zeolitic material, such as Mg-ZSM-5, a source of an oxidic binder, and a first plasticizer; admixing an acid to said mixture; and shaping of the mixture, to obtain a precursor of a molding; wherein in said mixture a specific weight ratio of the source of the oxidic binder to the sum of the zeolitic material and the source of the oxidic binder is applied. Further, the present invention relates to a molding obtainable or obtained by the inventive process, and to a molding itself displaying in particular a comparatively improved crush strength. Yet further, the present invention relates to a method for the conversion of oxygenates to olefins and to a use of the inventive molding.
Selective catalytic reduction catalyst composition
A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
Selective catalytic reduction catalyst composition
A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
Alkyl halides conversion into acyclic C3-C6 olefins
The present disclosure relates to a process for converting one or more alkyl halides to acyclic C3-C6 olefins, said process comprising the steps of (a) providing a feedstream comprising one or more alkyl halides; (b) providing a catalyst composition; and (c) contacting said feedstream with said catalyst composition under reaction conditions. The process is remarkable in that said process further comprises a step of steaming said catalyst composition before the step (c) and in that said catalyst composition comprises one or more zeolites and a binder, wherein said one or more zeolites comprise at least one 10-membered ring channel. The present disclosure further relates to the use of a catalyst composition in said process, said catalyst composition comprising one or more zeolites and a binder, wherein said catalyst composition is steamed before use.
Interior material having surface layer having visible light-responsive photocatalytic activity, and method for manufacturing same
The present invention provides: an interior material having a surface layer which has visible light-responsive photocatalytic activity and which contains two types of titanium oxide microparticles, the two types of titanium oxide microparticles comprising first titanium oxide microparticles, in which a tin component and a transition metal component for enhancing visible light responsiveness (excluding iron group components) are in solid solution, and second titanium oxide microparticles, in which an iron group component is in solid solution; and a method for manufacturing the interior material. The present invention makes it possible to provide an interior material in which visible light-responsive photocatalytic titanium oxide microparticles, which make it possible to easily produce a surface layer (photocatalyst thin film) having high transparency and expressing photocatalytic activity even in response to visible light (400-800 nm) only, are applied onto a surface, whereby it is possible to obtain, under indoor illumination, excellent photocatalytic properties such as an antimicrobial property and a property of breaking down chemical substances in indoor air without adversely affecting the design quality of the article in question.
COMPLEX OXIDE, METHOD FOR PRODUCING SAME, AND EXHAUST GAS PURIFYING CATALYST
Disclosed are a composite oxide which is capable of maintaining a large volume of pores even used in a high temperature environment, and which has excellent heat resistance and catalytic activity, as well as a method for producing the composite oxide and a catalyst for exhaust gas purification employing the composite oxide. The composite oxide contains cerium and at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, at a mass ratio of 85:15 to 99:1 in terms oxides, and has a property of exhibiting a not less than 0.30 cm.sup.3/g, preferably not less than 0.40 cm.sup.3/g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours, and is suitable for a co-catalyst in a catalyst for vehicle exhaust gas purification.
STEAM REFORMING CATALYST AND METHOD OF MAKING THEREOF
The invention provides a method for the production of a supported nickel catalyst, in which an aqueous mixture comprising an alkali metal salt plus other metal salts is sintered to form a support material. A supported nickel catalyst comprising potassium β-alumina is also provided.
Article of Manufacture for Securing a Catalyst Substrate
An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.
PROCESS FOR THE PRODUCTION OF DIENES
Process for the production of a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol in the presence of at least one catalytic material comprising at least one acid catalyst based on silica (SiO.sub.2) and alumina (AI.sub.2O.sub.3), preferably a silica-alumina (SiO.sub.2-AI.sub.2O.sub.3), said catalyst having a content of alumina (AI.sub.2O.sub.3) lower than or equal to 12% by weight, preferably ranging from 0.1% by weight to 10% by weight, with respect to the total weight of the catalyst. Preferably, said alkenol can be obtained directly from biosynthesis processes, or through the catalytic dehydration of at least one diol, preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, deriving from biosynthesis processes. Preferably, said 1,3-butadiene is bio-1,3-butadiene.
Method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing containing TiO2 bio-additive, and product thereof
The present invention discloses a method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing, such as white paste, natural stones or clinker, including TiO.sub.2 as bio-additive, and product obtained by the micronized sandstone thereof. The ceramics and industrial wastes of ceramic are grinded in several steps and the resultant powders are collected by means of individual filters and further combined in a nanopowder micronizer for posterior treatment, where TiO.sub.2 hydrolyzed can be optionally added. This micronized sandstone comprising the bio-additive TiO.sub.2 is used in the production of plasters, mortars, grouts and/or as additive for paints and/or epoxy enriched with TiO.sub.2. The micronized sandstone bio-additive with TiO.sub.2 can be additionally subjected to two optional embodiments of the invention: treatment with or without the use of a pigment. In order to obtain the final product that can be used in the production of blocks, floors and other products of various sizes, an agglomerating agent combined with TiO.sub.2 is added to the micronized sandstone comprising the bio-additive TiO.sub.2, either in an aqueous solution or as a dry product, optionally including colored oxides.