A catalytic system containing a titanium zeolite of structure type MWW optionally containing zinc and containing at least one of an inorganic potassium salt and an organic potassium salt is provided. The catalyst system is useful in the preparation of propylene oxide.

Fluidizable catalysts for oxygen-free oxidative dehydrogenation of alkanes to corresponding olefins. The catalysts contain 10-20% (by weight per total catalyst weight) of one or more vanadium oxides as the catalytic material, which are mounted upon an alumina support that is modified with zirconia at alumina/zirconia ratios of 5:1 up to 1:2. Various methods of preparing and characterizing the fluidizable catalysts are also provided.

Provided is a selective catalytic reduction (SCR) catalyst containing a carbon material loaded with vanadium and tungsten and a method of preparing the same, and relates to a method of loading vanadium and tungsten on a carbon material that exhibits excellent abrasion resistance and excellent strength and can be easily prepared.

An exhaust gas-purifying catalyst material includes first oxide particles having an average particle diameter D.sub.av of 1 m to 95 m and having an oxygen storage capacity, second oxide particles having an average particle diameter D.sub.av of 0.05 m to 0.5 m, containing a metal element, and having no oxygen storage capacity, precious metal particles, and acidic oxide particles. The material has a correlation coefficient of 0.45 or more obtained using first characteristic X-ray intensity for the metal element contained in the second oxide particle, second characteristic X-ray intensity for an element other than oxygen contained in the acidic oxide particle, and third characteristic X-ray intensity for a precious metal element contained in the precious metal particle.

A novel process and a novel catalyst for the production of light olefins. 1-butene is cracked in the presence of an acid- or base-modified silicalite-1 catalyst bed, wherein the modified silicalite-1 has a Si/Al ratio of greater than 1000. The modification procedures described herein increase the selectivity of the silicalite-1 catalyst toward light olefins such as ethylene and propylene. The catalytic cracking of 1-butene may be carried out in a fixed bed reactor or a fluidized bed reactor.

A novel process and a novel catalyst for the production of light olefins. 1-butene is cracked in the presence of an acid- or base-modified silicalite-1 catalyst bed, wherein the modified silicalite-1 has a Si/Al ratio of greater than 1000. The modification procedures described herein increase the selectivity of the silicalite-1 catalyst toward light olefins such as ethylene and propylene. The catalytic cracking of 1-butene may be carried out in a fixed bed reactor or a fluidized bed reactor.

Carbon opals, a form of colloidal crystal, are composed of ordered two-dimensional or three-dimensional arrays of Monodispersed Starburst Carbon Spheres (MSCS). Methods for producing such carbon opals include oxidizing as-synthesized MSCS, for example by heating in air, to increase surface charge. Such oxidation is believed to decrease settling rates of a colloidal suspension, enabling formation of an ordered colloidal crystal. Inverse opals, composed of any of a wide variety of materials, and based on a carbon opal template, have a reciprocal structure to a carbon opal. Inverse opals are formed by methods including: forming a carbon opal as described, impregnating a desired material into pores in the carbon opal to produce a hybrid structure, and removing the carbon portion from the hybrid structure.

The present invention relates to a process for hydroxylation of a compound of formula (I) by reacting the compound of formula (I) with an oxidizing agent, in the presence of a titanium silicalite zeolite prepared by crystallization preceded by a maturing step. The present invention also relates to a titanium silicalite zeolite and to the process for preparing same.

A silica particle includes a silica particle body and a titania coating layer formed on a surface of the silica particle body through a reaction of a titanium compound having a structure in which a hydrocarbon group bonds to a titanium atom through an oxygen atom. The silica particle has absorption at a wavelength of about 400 nm or more and about 800 nm or less in an ultraviolet-visible absorption spectrum.

Disclosed are methods for making monolithic carbon materials as single bodies containing networks of pores in the mesopore and macropores that incorporate nanoparticles of various metals and metal oxides. The disclosed methods have the advantage that such single bodies can be made by mixing the carbon precursors and metal salts together in a single pot followed by appropriate processing. The materials produced are particularly suitable for use as heterogeneous catalysts, particularly in fixed bed and monolithic reactors.