Patent classifications
B01J2523/00
Method for producing catalyst for ammoxidation, and method for producing acrylonitrile
The present invention provides a method for producing a catalyst for ammoxidation, comprising steps of: preparing a catalyst precursor slurry comprising a liquid phase and a solid phase; drying the catalyst precursor slurry to obtain dry a particle; and calcining the dry particle to obtain a catalyst for ammoxidation, wherein the solid phase of the catalyst precursor slurry comprises an aggregate containing a metal and a carrier, metal primary particles constituting the aggregate have a particle size of 1 μm or smaller, and an average particle size of the metal primary particles is 40 nm or larger and 200 nm or smaller.
AN EMMISSION CONTROL CATALYST ARTICLE WITH ENRICHED PGM ZONE
The present disclosure generally relates to emission control catalyst articles comprising a platinum group metal (PGM) enriched zone, methods of making such emission control catalyst articles, and methods of using such emission control catalyst articles.
AN EMMISSION CONTROL CATALYST ARTICLE WITH ENRICHED PGM ZONE
The present disclosure generally relates to emission control catalyst articles comprising a platinum group metal (PGM) enriched zone, methods of making such emission control catalyst articles, and methods of using such emission control catalyst articles.
REFORMING CATALYST
A novel steam reforming catalyst comprising hibonite and potassium beta-alumina with improved resilience, improved activity, reduced potassium leaching and reduced coking problems. It also regards a method for producing the novel catalyst and uses of the novel catalyst in reforming reactors, in a plant for producing hydrogen gas, or in a plant for producing synthesis gas.
REFORMING CATALYST
A novel steam reforming catalyst comprising hibonite and potassium beta-alumina with improved resilience, improved activity, reduced potassium leaching and reduced coking problems. It also regards a method for producing the novel catalyst and uses of the novel catalyst in reforming reactors, in a plant for producing hydrogen gas, or in a plant for producing synthesis gas.
CATALYST, METHOD FOR FILLING CATALYST, AND METHOD FOR PRODUCING COMPOUND USING CATALYST
A catalyst containing, as an essential component, molybdenum; bismuth; and cobalt, in which a sum (S) of ratios of peak intensities expressed by the following formula in an X-ray diffraction pattern obtained by using CuKα rays as an X-ray source is 42 or more and 113 or less.
S={(peak intensity at 2θ=14.1°±0.1°+(peak intensity at 2θ=25.4°±0.1°)+(peak intensity at 2θ=28.5°±0.1°)}/(peak intensity at 2θ=26.5°±0.1°)×100
CATALYST, METHOD FOR FILLING CATALYST, AND METHOD FOR PRODUCING COMPOUND USING CATALYST
A catalyst containing, as an essential component, molybdenum; bismuth; and cobalt, in which a sum (S) of ratios of peak intensities expressed by the following formula in an X-ray diffraction pattern obtained by using CuKα rays as an X-ray source is 42 or more and 113 or less.
S={(peak intensity at 2θ=14.1°±0.1°+(peak intensity at 2θ=25.4°±0.1°)+(peak intensity at 2θ=28.5°±0.1°)}/(peak intensity at 2θ=26.5°±0.1°)×100
CATALYST, METHOD FOR PRODUCING COMPOUND USING SAME, AND COMPOUND
A catalyst containing, as an essential component, molybdenum; bismuth; and cobalt, in which, with respect to a peak intensity at 2θ=25.3°±0.2° in an X-ray diffraction pattern obtained by using CuKα rays as an X-ray source, a changing rate (Q1) per 1000 hours of reaction time represented by the following formulae (1) to (4) is 16 or less.
Q1={(U1/F1−1)×100}/T×1000 (1)
F1=(peak intensity of catalyst before oxidation reaction at 2θ=25.3°±)0.2°/(peak intensity of catalyst before oxidation reaction at 2θ=26.5°±0.2°)×100 (2)
U1=(peak intensity of catalyst after oxidation reaction at 2θ=25.3°±0.2°)/(peak intensity of catalyst after oxidation reaction at 2θ=26.5°±0.2°)×100 (3)
T=time (hr) during which oxidation reaction is carried out (4)
CATALYST, METHOD FOR PRODUCING COMPOUND USING SAME, AND COMPOUND
A catalyst containing, as an essential component, molybdenum; bismuth; and cobalt, in which, with respect to a peak intensity at 2θ=25.3°±0.2° in an X-ray diffraction pattern obtained by using CuKα rays as an X-ray source, a changing rate (Q1) per 1000 hours of reaction time represented by the following formulae (1) to (4) is 16 or less.
Q1={(U1/F1−1)×100}/T×1000 (1)
F1=(peak intensity of catalyst before oxidation reaction at 2θ=25.3°±)0.2°/(peak intensity of catalyst before oxidation reaction at 2θ=26.5°±0.2°)×100 (2)
U1=(peak intensity of catalyst after oxidation reaction at 2θ=25.3°±0.2°)/(peak intensity of catalyst after oxidation reaction at 2θ=26.5°±0.2°)×100 (3)
T=time (hr) during which oxidation reaction is carried out (4)
CATALYST AND CATALYST GROUP
A catalyst may suppress pressure loss and coaking and produce a target substance in high yield when a gas-phase catalytic oxidation reaction of a material substance is conducted using the catalyst to produce the target substance. A ring-shaped catalyst may have a straight body part and a hollow body part, which is used when a gas-phase catalytic oxidation reaction of a material substance is conducted to produce a target substance, wherein a length of the straight body part is shorter than a length of the hollow body part and at least at one end part, a region from an end part of the straight body part to an end part of the hollow body part is concavely curved.