An improved superhydrophobic coating and a process of making it is provided herein. More particularly, a robust superhydrophobic coating is produced by using carbon dioxide to enhance the integration of a binder material into the superhydrophobic coating. The carbon dioxide may be used to infiltrate and fill the interstitial voids of a superhydrophobic material, such as diatomaceous earth. Consequently, occupying these voids in the superhydrophobic material effectively blocks other components (e.g., binders) from entering the voids. As a result, the coating formulations of the present invention are more robust and may strongly adhere to the substrates to which they are applied.

An improved superhydrophobic coating and a process of making it is provided herein. More particularly, a robust superhydrophobic coating is produced by using carbon dioxide to enhance the integration of a binder material into the superhydrophobic coating. The carbon dioxide may be used to infiltrate and fill the interstitial voids of a superhydrophobic material, such as diatomaceous earth. Consequently, occupying these voids in the superhydrophobic material effectively blocks other components (e.g., binders) from entering the voids. As a result, the coating formulations of the present invention are more robust and may strongly adhere to the substrates to which they are applied.

A coating liquid composition comprises a resin component, a first solvent having a solubility parameter lower than 23.5 (MPa).sup.0.5, carbon dioxide, and a second solvent having a solubility parameter of 23.5 (MPa).sup.0.5 to 40 (MPa).sup.0.5. An average boiling point bpi of the first solvent and an average boiling point bp.sub.2 of the second solvent satisfy a relationship of bp.sub.1bp.sub.2>0.

A high speed granule delivery system and method is disclosed for dispensing granules in intermittent patterns onto a moving asphalt coated strip in the manufacture of roofing shingles. The system includes a granule hopper and a rotationally indexable pocket wheel in the bottom of the hopper. A series of pockets are formed in the circumference of the wheel and the pockets are separated by raised lands. A seal on the bottom of the hopper seals against the raised lands as the wheel is indexed. In use, the pockets of the pocket wheel drive through and are filled with granules in the bottom of the hopper. As each pocket is indexed beyond the seal, it is exposed to the moving asphalt coated strip below and its granules fall onto the strip to be embedded in the hot tacky asphalt. The speed at which the wheel is indexed is coordinated with the speed of the asphalt coated strip so that granules and strip are moving at about the same forward speed or at a preselected ratio of speeds when the granules fall onto the strip. Well defined patterns of granules are possible at high production rates.

A high speed granule delivery system and method is disclosed for dispensing granules in intermittent patterns onto a moving asphalt coated strip in the manufacture of roofing shingles. The system includes a granule hopper and a rotationally indexable pocket wheel in the bottom of the hopper. A series of pockets are formed in the circumference of the wheel and the pockets are separated by raised lands. A seal on the bottom of the hopper seals against the raised lands as the wheel is indexed. In use, the pockets of the pocket wheel drive through and are filled with granules in the bottom of the hopper. As each pocket is indexed beyond the seal, it is exposed to the moving asphalt coated strip below and its granules fall onto the strip to be embedded in the hot tacky asphalt. The speed at which the wheel is indexed is coordinated with the speed of the asphalt coated strip so that granules and strip are moving at about the same forward speed or at a preselected ratio of speeds when the granules fall onto the strip. Well defined patterns of granules are possible at high production rates.

A method of manufacturing a jacketed metal line is detailed herein. The method of manufacturing a jacketed metal line can include roughening an outer surface of a metal core of the line. An insulating polymer layer can be applied to the metal core, and the insulating polymer layer can include a reinforcing additive comprising: graphite, carbon, glass, aramid, short-fiber filled PolyEtherEtherKetone, mircron-sized polytetrafluoroethylene, or combinations thereof. The roughened metal core can then be exposed a heat source for at least partially melting the polymer layer; and the partially melted polymer layer and insulated roughened metal core can be ran through a set of shaping rollers.

A method of manufacturing a jacketed metal line is detailed herein. The method of manufacturing a jacketed metal line can include roughening an outer surface of a metal core of the line. An insulating polymer layer can be applied to the metal core, and the insulating polymer layer can include a reinforcing additive comprising: graphite, carbon, glass, aramid, short-fiber filled PolyEtherEtherKetone, mircron-sized polytetrafluoroethylene, or combinations thereof. The roughened metal core can then be exposed a heat source for at least partially melting the polymer layer; and the partially melted polymer layer and insulated roughened metal core can be ran through a set of shaping rollers.

A method of powder coating a substrate includes receiving a powder coating material into a feed input, using the feed input, melting the powder coating material into a homogeneous fluid of powder coating material, receiving the homogeneous fluid of powder coating material into a filament extension atomizer positioned in-line with the feed input, atomizing, with the filament extension atomizer, the received homogeneous fluid of powder coating material into multiple droplets of powder coating material, cooling the droplets of powder coating material to a processing temperature that prevents the droplets from agglomerating, and directing the cooled droplets through a deposition passage positioned in-line with the filament extension atomizer, the deposition passage configured to direct at least a portion of the cooled droplets towards a substrate.

Embodiments relate to surface treating a substrate, spraying precursor onto the substrate using supercritical carrier fluid, and post-treating the substrate sprayed with the precursor to form a layer with nanometer thickness of material on the substrate. A spraying assembly for spraying the precursor includes one or more spraying modules and one or more radical injectors at one or more sides of the spraying module. A differential spread mechanism is provided between the spraying module and the radical injectors to inject spread gas that isolates the sprayed precursor and radicals generated by the radical injectors. As relative movement between the substrate and the spraying assembly is made, portions of the substrate is exposed to first radicals, sprayed with precursors either one of the spraying modules or both spraying modules using supercritical carrier fluid, and then exposed to second radicals again.

Embodiments relate to surface treating a substrate, spraying precursor onto the substrate using supercritical carrier fluid, and post-treating the substrate sprayed with the precursor to form a layer with nanometer thickness of material on the substrate. A spraying assembly for spraying the precursor includes one or more spraying modules and one or more radical injectors at one or more sides of the spraying module. A differential spread mechanism is provided between the spraying module and the radical injectors to inject spread gas that isolates the sprayed precursor and radicals generated by the radical injectors. As relative movement between the substrate and the spraying assembly is made, portions of the substrate is exposed to first radicals, sprayed with precursors either one of the spraying modules or both spraying modules using supercritical carrier fluid, and then exposed to second radicals again.