Nanocomposite compositions and methods for preparing nanocomposite compositions films are provided. The nanocomposite compositions include dendritic fibrous nanoparticles that have a diameter ranging from 50 to 500 nm, and a polymer matrix comprising poly(methyl methacrylate) (PMMA), where the dendritic fibrous nanoparticles have a hydrophobic coating and are dispersed within the PMMA matrix. Methods of preparing nanocomposite compositions may include introducing dendritic fibrous nanoparticles into a mixture with a poly(methyl methacrylate) and an organic solvent to form a composite solution. Methods further include casting the mixture onto a glass sheet within a mold, evaporating the organic solvent to form the nanocomposite film, and separating the nanocomposite film from the glass sheet.

Photoresponsive materials for use with a volumetric additive manufacturing system are described herein. Some embodiments of photoresponsive materials described herein include at least one constituent selected from the group consisting of (i) a thiol-containing siloxane prepolymer, (ii) a vinyl-containing siloxane prepolymer, (iii) a reinforcing filler, (iv) a photoinitiator (v) a polymerization inhibitor. Various methods of using the same photoresponsive materials in additive manufacturing processes, such as volumetric additive manufacturing, are also described.

The present invention relates to a multilayer composition comprising a surface layer comprising a thermoplastic polymer A and a substrate layer comprising a polymeric composite material based thermoplastic (meth)acrylic matrix and a fibrous material as reinforcement. The multilayer composition is suitable for mechanical or structured parts or articles with a decorative surface aspect The present invention concerns also a manufacturing process for multilayer mechanical or structured parts or articles and three-dimensional mechanical or structured parts.

A sulfonated water-dispersible thermoplastic copolymer material for use as a support material in an additive manufacturing process is made by a method comprising providing a selected thermoplastic copolymer having an acid or an anhydride group; esterifying the acid group of the selected thermoplastic copolymer with a hydroxyl-functionalized sulfonate salt, or amidizing the acid group of the selected thermoplastic copolymer with an amine sulfonate salt, or imidizing the anhydride group of the selected thermoplastic copolymer with an amine sulfonate salt. The esterification, the amidization or the imidization results in a sulfonated water thermoplastic dispersible copolymer having a glass transition temperature suitable to provide an effective support during the additive manufacturing process and wherein the sulfonated water-dispersible thermoplastic copolymer will disperse in tap water in less than 1 hour.

A material that can be formed into a porous prosthetic sleeve liner that provides particularly useful benefits for prosthetics. The material is breathable and sweat-absorbing, thus minimizing skin morbidity when used as a prosthetic liner. The material can include hydrophilic-lined continuous pores within a hydrophobic polymer, wherein the hydrophilic lining is crosslinked together with the hydrophobic polymer via non-degradable covalent interactions using chain crosslinkers.

A dental article such as a dental tray aligner or a dental crown that includes a substrate including a polymeric material having a modulus of elasticity that reduces upon exposure to water and a water-resistant coating on the substrate, where the water-resistant coating comprises parylene. In some examples, the water-resistant coating may include one or more layers that include parylene.

A capsule shell contains 40 to 99% by weight of a core-shell polymer and 1 to 60% by weight of a cellulose. The core-shell polymer contains 50 to 90% by weight of a core, containing polymerized units of 65 to 75% by weight of ethyl acrylate and 25 to 35% by weight of methyl methacrylate; and 10 to 50% by weight of a shell, containing polymerized units of 45 to 55% by weight of ethyl acrylate and 45 to 55% by weight of methacrylic acid.

A three-dimensional object comprises stacked substrate layers infiltrated by a hardened material comprising engineered powder that is transformed into a substance that flows and subsequently hardens into the hardened material in a spatial pattern that infiltrates positive regions, and does not infiltrate negative regions, in the substrate layers. The powder may be emulsion aggregation powder, chemically-produced toner powder, or a combination. It may be a thermoplastic or thermosettable polymer and may include nylon, elastomers, polyolefins, polyethylene, polyether ether ketone, polyimide, polyetherimide, polyphenylene sulfide, polystyrene, polypropylene, polymethyl methacrylate, and polyaryletherketone, or a combination. The powder particles may have a pre-specified controlled shape and/or a non-homogenous composition. Surface treatments and/or additives may be used to control powder flow and charge distribution. Each substrate layer may be a sheet-like structure comprising fibers held together by binder. The binder may include sodium silicate.

A formulation, system, and method for additive manufacturing of a polishing pad. The formulation includes monomer, dispersant, and nanoparticles. A method of preparing the formulation includes adding a dispersant that is a polyester derivative to monomer, adding metal-oxide nanoparticles to the monomer, and subjecting the monomer having the nanoparticles and dispersant to sonication to disperse the nanoparticles in the monomer.

Methods of layerwise fabrication of a three-dimensional object, and objected obtained thereby are provided. The methods are effected by dispensing at least a first modeling formulation and a second modeling formulation to form a core region using both said first and said second modeling formulations, an inner envelope region at least partially surrounding said core region using said first modeling formulation but not said second modeling formulation, and an outer envelope region at least partially surrounding said inner envelope region using said second modeling formulations but not said first modeling formulation; and exposing said layer to curing energy, thereby fabricating the object, The first and second modeling formulations are selected such they differ from one another, when hardened, by at least one of Heat Deflection Temperature (HDT), Izod Impact resistance, Tg and elastic modulus.