An improved method for obtaining high fiber volume fraction, long fiber injection molded articles is provided. According to one embodiment, the method includes forming an injection molding feedstock by cutting pre-impregnated fiber-reinforced tape into platelets. The platelets can be coated with a thin layer of polymer to allow sliding of the platelets with respect to each other at the early stages of plastication, rather than forcing relative motion of fibers with respect to each other. The method can further include the dispersion of material only in the final stages of the injection molding screw to promote gentle motion of the feedstock at the earlier stages of the plastication process. The method allows improvement of mechanical properties of articles manufactured with equipment and techniques that are prevalent in high volume automotive and consumer industries.

An adhesive composition is described comprising unpolymerized cyclic olefin, a ring opening metathesis polymerization (ROMP) catalyst or precatalyst thereof, and one or more adhesion promoter polymers. In one embodiment, the adhesion promoter is a polyolefin comprising maleic anhydride or silicon-containing moieties. In one embodiment, a combination of at least one polymeric polyisocyanate and at least one polyolefin comprising maleic anhydride or silicon-containing moieties provides a synergistic improvement. In another embodiment, a polymeric polyisocyanate adhesion promoter comprising oxygen atoms in the backbone has been found useful for bonding substrates such as polyamide, polyether ether ketone, or polyether imide. Also described are methods of bonding a substrate and articles, such as an electric battery cold plate assembly.

A method for producing an object by additive manufacturing using a polyamide filament includes performing the additive manufacturing using the polyamide filament and a fused deposition modeling process. The polyamide is a cast polyamide. Advantageously, it is possible that the polyamide can have a Young's modulus in tension of 3,300 MPa to 4,000 MPa, and/or a heat-distortion temperature HDT A of 80° C. to 150° C. and/or a heat-distortion temperature HDT B of 180° C. to 240° C., and/or a yield stress of 85 MPa to 100 MPa and/or a Vicat softening temperature VST/B/50 of 208° C. to 220° C. Advantageously, it is possible that the polyamide can include a polyamide 6, a polyamide 12, a blend thereof, or a copolymer thereof.

The present invention relates to a polyamide resin composition that has excellent mechanical properties and shows excellent results in a UL94 combustion test, and that comprises an aliphatic polyamide (A), a phosphinic acid salt (B) and a phosphazene compound (C), wherein the aliphatic polyamide (A) is contained in an amount of 60 mass % or more and 85 mass % or less in the polyamide resin composition, and the phosphazene compound (C) is contained in an amount of 3 mass % or more and 20 mass % or less in the polyamide resin composition.

Pile articles (20,22), especially pile weather stripping, and a method and apparatus (10) for making such articles where the backing (24) and the pile (26) are of unlike material, especially nylon yarn for the pile (26) and polypropylene containing material for the backing (24), wherein prior to the welding of the pile (26) to the backing (24) the pile is first pre-heated using ultrasonic energy to melt the pile in a region (65) thereof where the pile is ultrasonically welded to the backing and before the weld is made. The ultrasonic melting occurs upstream of the location where the pile (26) is welded to the backing (24) so that the ultrasonically pre-heated melted region (65) of the pile (26) can cool and become at least partially solidified. Then pile (26) at the pre-heated melted region (65) is welded to the backing (24) and causes a reactive or chemical weld to occur, thereby attaching the pile (26) to the backing (24).

Pile articles (20,22), especially pile weather stripping, and a method and apparatus (10) for making such articles where the backing (24) and the pile (26) are of unlike material, especially nylon yarn for the pile (26) and polypropylene containing material for the backing (24), wherein prior to the welding of the pile (26) to the backing (24) the pile is first pre-heated using ultrasonic energy to melt the pile in a region (65) thereof where the pile is ultrasonically welded to the backing and before the weld is made. The ultrasonic melting occurs upstream of the location where the pile (26) is welded to the backing (24) so that the ultrasonically pre-heated melted region (65) of the pile (26) can cool and become at least partially solidified. Then pile (26) at the pre-heated melted region (65) is welded to the backing (24) and causes a reactive or chemical weld to occur, thereby attaching the pile (26) to the backing (24).

An ethylene-vinyl alcohol copolymer composition is substantially free from coloration, and contains: (A) an ethylene-vinyl alcohol copolymer; (B) a polyamide resin; and (C) an iron compound; wherein the iron compound (C) is present in an amount of 0.01 to 20 ppm on a metal basis based on the weight of the ethylene-vinyl alcohol copolymer composition.

A method for producing metal-polymer composites which include at least one metal part and at least one part made of a polymer composition, the method including the steps of: treating the surface of at least one metal part at least partially with a solution of triazine thiol derivative to obtain a treated metal surface; and contacting the treated metal surface at least partially with at least one polymer composition so as to obtain a metal-polymer composite, wherein the polymer composition includes at least one semi-crystalline polyamide. Also, a metal-polymer composite that includes at least one part made of a polymer composition and at least one metal part and that is obtainable by the method and to a product including the metal-polymer composite.

A method for chemically polishing a metal surface within a metal-polymer composite, where the composite includes at least one metal part and at least one part made of a polymer composition, the method including the step of: (i) contacting the surface of at least one metal part at least partially with an aqueous solution including an oxidizing agent and an alkaline agent, at a temperature and for a duration sufficient to obtain a shiny metal surface. Also a metal-polymer composite that includes at least one part made of a polymer composition and at least one chemically polished metal part and that is obtainable by the method and to a product including the metal-polymer composite.

A method for producing a rubber-plastic composite, including the steps of (a) shaping an unvulcanized elastomer, (b) partially vulcanizing the shaped elastomer at a temperature of at least 140° C. up to a degree of vulcanization in the range from 10% to 40%, (c) cooling the partially vulcanized elastomer to a temperature of less than 100° C. within less than 20 minutes, (d) overmolding the partially vulcanized elastomer with a plastic, and (e) heat treating the partially vulcanized elastomer overmolded with a plastic at a temperature in the range from 100° C. to 170° C. for a duration of from 5 minutes to 5 hours to complete the vulcanization and form a rubber-plastic composite. The method further relates to a rubber-plastic composite obtainable by the method according to the invention and also to a shoe comprising the rubber-plastic composite obtainable by the method according to the invention.