A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.

A process for welding a first molding to a second molding. The process uses an implement including first and second external surfaces. Each external surface further includes a duct. An end of the first molding is heated by a hot gas while the end is at a distance from the duct-entry plane in the range from 3 mm outside the duct to 10 mm inside the duct. A junction area of the second molding is heated by a hot gas while the junction area is at a distance from the duct-entry plane in a range from 3 mm outside the duct to 10 mm inside the duct. The heated end and the heated junction area are then brought into contact with one another and cooled, forming a weld between the first molding and the second molding. Also disclosed is a welded molding obtainable by the process of the invention.

A process for welding a first molding to a second molding. The process uses an implement including first and second external surfaces. Each external surface further includes a duct. An end of the first molding is heated by a hot gas while the end is at a distance from the duct-entry plane in the range from 3 mm outside the duct to 10 mm inside the duct. A junction area of the second molding is heated by a hot gas while the junction area is at a distance from the duct-entry plane in a range from 3 mm outside the duct to 10 mm inside the duct. The heated end and the heated junction area are then brought into contact with one another and cooled, forming a weld between the first molding and the second molding. Also disclosed is a welded molding obtainable by the process of the invention.

Disclosed are processes for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula: A-S-P, wherein A is a chemical group containing at least one aliphatic double bond, S is a sulfur atom, and P is a protecting group.

A polyarylene sulfide-based resin composition is disclosed containing a polyarylene sulfide-based resin A, an inorganic filler B, and olefinic copolymers C and D each having predetermined structural units, wherein: the inorganic filler B contains a fibrous inorganic filler B1 having a different diameter ratio of 1.5 or less and a fibrous inorganic filler B2 having a different diameter ratio of 3.0 or more; a mass ratio B1/B2 of the fibrous inorganic filler B1 and the fibrous inorganic filler B2 is 0.2 or more and 5.0 or less; and the contents of the olefinic copolymers C and D are respectively 3 parts by mass or more and less than 19 parts by mass and 3 parts by mass or more and 30 parts by mass or less with respect to 100 parts by mass of the polyarylene sulfide-based resin A.

A polyarylene sulfide-based resin composition is disclosed containing a polyarylene sulfide-based resin A, an inorganic filler B, and olefinic copolymers C and D each having predetermined structural units, wherein: the inorganic filler B contains a fibrous inorganic filler B1 having a different diameter ratio of 1.5 or less and a fibrous inorganic filler B2 having a different diameter ratio of 3.0 or more; a mass ratio B1/B2 of the fibrous inorganic filler B1 and the fibrous inorganic filler B2 is 0.2 or more and 5.0 or less; and the contents of the olefinic copolymers C and D are respectively 3 parts by mass or more and less than 19 parts by mass and 3 parts by mass or more and 30 parts by mass or less with respect to 100 parts by mass of the polyarylene sulfide-based resin A.

The present disclosure relates to the use of occluding fluids, such as a high-density fluid (a “z-fluid”) or a low-density fluid (an “a-fluid”), to displace resin within a vat during 3D printing. Further, an a-fluid may act as a protective boundary for a 3D printing resin wherein the a-fluid sits on top of the printing resin. Another embodiment of the disclosure provides a process of assessing which regions of a computer-aided design (CAD) model take advantage of a buoying force supplied by the occluding fluid, such that fewer support structures are needed for printing a final CAD model compared to printing the CAD model without the occluding fluid.

A diffraction light guide plate having excellent thickness uniformity and flatness, and having low haze, and excellent mechanical properties such as pencil hardness and strength at the same time, and a method for manufacturing the diffraction light guide plate.

A method of recycling and reusing a tap water-soluble sulfonated polymer material from a structural component made using an additive manufacturing process comprises dissolving the structural component in water to disperse the sulfonated polymer material into the water. The sulfonated polymer material is precipitated from the water and recovered; then dried and reformed into a form suitable for subsequent use as a consumable feedstock in a subsequent additive manufacturing process.

Compounds and compositions are provided which are useful in additive printing, particularly additive printing techniques such as stereolithography (SLA) wherein a macromer is photopolymerized to form a manufactured article. Representative compounds comprise a polyaxial central core (CC) and 2-4 arms of the formula (A)-(B) or (B)-(A) extending from the central core, where at least one of the arms comprise a light-reactive functional group (Q) and (A) is the free-radical polymerization product from monomers selected from trimethylene carbonate (T) and ε-caprolactone (C), while (B) is the free-radical polymerization product from monomers selected from glycolide, lactide and p-dioxanone.