A biodegradable and biocompatible three dimensional construct comprising a combination of a nano silicate (e.g., laponite) and two different polymers, the two polymers each individually providing at least one covalently linked polymer chain and at least one ionically linked polymer chain, the polymeric chains forming a dual strengthening intertwined polymeric system. The constructs demonstrate improved mechanical and strength properties, while the bioinks provide a material having superior printability characteristics suitable for printing a three dimensional biodegradable construct having an aspect ratio of greater than 2.0. The bioink may also comprise cells or combinations of cells. Methods of using the constructs and bioinks for wound healing preparations and tissue regeneration are also provided.

A shoe component includes a foam member including a thermoplastic material and a mixed material mixed to each other, wherein the weight percentage of the thermoplastic material is 90 wt % to 99 wt %, and the weight percentage of the mixed material is 10 wt % to 1 wt %. A manufacturing method of the shoe component is also disclosed herein.

Described herein are polymeric composites that can include a kaolin filler dispersed within a thermoplastic polymer matrix. The kaolin filler can exhibit an aspect ratio of from 20 to 50, as measured by laser scattering, a mean particle size of from 0.75 microns to 2 microns e.s.d., as measured by Sedigraph, or a combination thereof. In some embodiments, the kaolin filler exhibits a ratio of aspect ratio to mean particle size ranges from 4 to 5, as measured by laser scattering. In some embodiments, less than 30% by weight of the kaolin filler exhibits a particle size of less than 0.5 microns e.s.d., as measured by Sedigraph. The composites can exhibit improved mechanical properties such as flexural strength, tensile strength, and heat deflection temperature. The composites can be used to form articles, for example, by thermoforming.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object (e.g. comprised of polyurethane, polyurea, or copolymer thereof) is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) contacting the three-dimensional intermediate to water to form the three-dimensional object.

The present invention relates to a surface-treated filler material product comprising filler material comprising at least one epoxy-functional compound having one or more epoxy group(s) and/or reaction products thereof, a process for preparing said surface-treated filler material product, a polymer composition comprising at least one polymeric resin and from 1 to 70 wt.-%, based on the total weight of the polymer composition, of said surface-treated filler material product, a polymeric article comprising said surface-treated filler material product and/or the polymer composition as well as the use of the surface-treated filler material product to reduce degradation of the mechanical properties in a polymeric article comprising the surface-treated filler material product when exposed to UV light.

Formulations usable in additive manufacturing of a three-dimensional object, which comprise a reinforcing material such as silica particles in an amount of from 10 to 30%, or from 15 to 20%, by weight, of the total weight of the formulation, and a designed combination of curable materials as described in the specification, is provided. Additive manufacturing of three-dimensional objects made of such a formulation and featuring enhanced mechanical properties, and objects obtained thereby are also provided.

A recyclable polyethylene man-door comprises an interior panel and an exterior door panel, each panel having a horizontal pattern of cut-outs and optionally comprising a blend of mineral additives that do not adversely affect the recyclability of the finished product.

A method for forming at least one groove in a board element, wherein the board element includes a polymer-based material and, preferably, a filler. The method includes providing a board element including a board portion disposed at an elevated temperature and forming at least one groove by removing material, such as chips, from the board portion by a processing device.