The present invention provides compounds that can be used to form antimicrobial coatings on, for example, a surface or textile, including methods of making and using such compounds. In some embodiments, the present invention provides methods of making such compounds by a single-step reaction. In some embodiments, the present invention provides methods of forming an antimicrobial coating on a surface, including applying such compounds to, for example, a surface or textile, and, optionally, treating, for example, the surface or textile, to form a coating.

The present invention provides compounds that can be used to form antimicrobial coatings on, for example, a surface or textile, including methods of making and using such compounds. In some embodiments, the present invention provides methods of making such compounds by a single-step reaction. In some embodiments, the present invention provides methods of forming an antimicrobial coating on a surface, including applying such compounds to, for example, a surface or textile, and, optionally, treating, for example, the surface or textile, to form a coating.

A method is provided for storing and dispensing an antimicrobial solution including providing a bag-on-valve can, and filling the bag-on-valve can with the antimicrobial solution, the antimicrobial solution comprising a silane quaternary ammonium ion or salt thereof. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride.
The solution can further include any one or more of water, isopropyl alcohol, hydrogen peroxide, and hypochlorous acid. A bag-on-valve can is also provided for storing and dispensing an antimicrobial solution, the bag-on-valve can including: a can having an opening; a valve sealed in the opening of the can; a bag attached to the valve and provided in the can, wherein the bag is filled with the antimicrobial solution, which includes a silane quaternary ammonium ion or salt thereof; and an actuator for dispensing the solution.

A method is provided for storing and dispensing an antimicrobial solution including providing a bag-on-valve can, and filling the bag-on-valve can with the antimicrobial solution, the antimicrobial solution comprising a silane quaternary ammonium ion or salt thereof. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride.
The solution can further include any one or more of water, isopropyl alcohol, hydrogen peroxide, and hypochlorous acid. A bag-on-valve can is also provided for storing and dispensing an antimicrobial solution, the bag-on-valve can including: a can having an opening; a valve sealed in the opening of the can; a bag attached to the valve and provided in the can, wherein the bag is filled with the antimicrobial solution, which includes a silane quaternary ammonium ion or salt thereof; and an actuator for dispensing the solution.

A method is provided for storing and dispensing an antimicrobial solution including providing a bag-on-valve can, and filling the bag-on-valve can with the antimicrobial solution, the antimicrobial solution comprising a silane quaternary ammonium ion or salt thereof. The silane quaternary ammonium ion or salt thereof can be one or more of: 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium ion, 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium ion, and 3-(trihydroxysilyl)propyldimethyloctadecyl ammonium chloride.
The solution can further include any one or more of water, isopropyl alcohol, hydrogen peroxide, and hypochlorous acid. A bag-on-valve can is also provided for storing and dispensing an antimicrobial solution, the bag-on-valve can including: a can having an opening; a valve sealed in the opening of the can; a bag attached to the valve and provided in the can, wherein the bag is filled with the antimicrobial solution, which includes a silane quaternary ammonium ion or salt thereof; and an actuator for dispensing the solution.

Fungicidal mixtures, comprising 1) a fungicidal strain (I) selected from a) the Bacillus substilis strain with NRRL Accession No. B-21661, and b) the Bacillus pumilus strain with NRRL Accession No. B-30087, or a mutant of these strains having all the identifying characteristics of the respective strain, or a metabolite produced by the respective strain that exhibits activity against plant pathogenic fungi, and 2) at least one chemical compound (II), selected from the active compound groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using compositions of components 1) and 2), the use of a component 1) with a component 2) for preparing such compositions, and also fungicidal agents and seed comprising such compositions.

Fungicidal mixtures, comprising 1) a fungicidal strain (I) selected from a) the Bacillus substilis strain with NRRL Accession No. B-21661, and b) the Bacillus pumilus strain with NRRL Accession No. B-30087, or a mutant of these strains having all the identifying characteristics of the respective strain, or a metabolite produced by the respective strain that exhibits activity against plant pathogenic fungi, and 2) at least one chemical compound (II), selected from the active compound groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using compositions of components 1) and 2), the use of a component 1) with a component 2) for preparing such compositions, and also fungicidal agents and seed comprising such compositions.

Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, ##STR00001##
wherein W is O or S; V is a direct bond or NR.sup.3; Q is or CR.sup.6aR.sup.6b, O, NR.sup.7, C═N—O—R.sup.7 or C(═O); Y is —C(R.sup.5)═N—O—(CR.sup.8aR.sup.8b).sub.p—X—(CR.sup.9aR.sup.9b).sub.q—SiR.sup.10aR.sup.10bR.sup.10c; or a phenyl ring substituted as defined in the disclosure; or Z; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6a, R.sup.6b, R.sup.7, R.sup.8a, R.sup.8b, R.sup.9a, R.sup.9b, R.sup.10a, R.sup.10b, R.sup.10c, Z, p and q are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, ##STR00001##
wherein W is O or S; V is a direct bond or NR.sup.3; Q is or CR.sup.6aR.sup.6b, O, NR.sup.7, C═N—O—R.sup.7 or C(═O); Y is —C(R.sup.5)═N—O—(CR.sup.8aR.sup.8b).sub.p—X—(CR.sup.9aR.sup.9b).sub.q—SiR.sup.10aR.sup.10bR.sup.10c; or a phenyl ring substituted as defined in the disclosure; or Z; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6a, R.sup.6b, R.sup.7, R.sup.8a, R.sup.8b, R.sup.9a, R.sup.9b, R.sup.10a, R.sup.10b, R.sup.10c, Z, p and q are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

The present disclosure relates to substituted thiophene carboxamides and analogues thereof of formula (I) that may be used for protecting plants from bacterial diseases, in particular from bacterial diseases caused by bacteria belonging to the genus Xanthomonas.

##STR00001##