The present invention relates to a synthesis of novel Zn(II)-based Metal Organic Frameworks having mixed organic ligands of 1,3,5-benzene tricarboxylic acid (BTC) and 2-methylimidazole (mIm) through a simple and economic solvothermal method. The synthesized MOFs has cuboids morphology having high surface area (1248 m2/g) capable of hydrogen adsorption at −10° C. to 25° C. temperature and 100 bar pressure. The hydrogen adsorption capabilities of the novel MOFs are in the range of 23-0.2 weight percent.

A method of producing synthesis gas in a dual pressure level ammonia plant having a first synthesis section operated in once through fashion at a first relatively lower high pressure and having a second synthesis section operated in recirculating fashion at a second relatively higher high pressure. In the first synthesis section downstream of an OT reactor of the first synthesis section the synthesis gas is cooled using cooling medium at a pressure below the first high pressure, wherein the cooling medium is provided at a pressure below the first high pressure level by means of a medium pressure steam generator or wherein the cooling is effected by means of the medium pressure steam generator. The disclosure further relates to a synthesis gas cooling assembly in such a dual pressure level ammonia plant and at least one plant component for providing or for utilizing the cooling medium.

A gas supply system includes a first tank, a first path into which a first gas generated by vaporization of a first low-temperature liquefied gas flows, a gas boosting mechanism being disposed in the first path, a second path that is a path configured to extract the first low-temperature liquefied gas from the first tank, a pump and a vaporization mechanism being disposed in the second path and a reliquefaction path that is a path configured to liquefy at least part of the first gas extracted from an upstream side of the gas boosting mechanism in the first path and to cause the liquefied first gas to flow into an upstream side of the pump in the second path, a cooling heat exchanger configured to cool the first gas by a second low-temperature liquefied gas or a second gas being disposed in the reliquefaction path.

A carbon material that is compact and exhibits an excellent hydrogen storage capacity. A carbon material has a specific surface area of 200 m.sup.2/g or less and exhibits a hydrogen storage capacity of 1.5×10.sup.−5 g/m.sup.2 or more at a hydrogen pressure of 10 MPa.

The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibres and a binder, wherein the catalyst loaded fibres and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water.

The present application is generally directed to gas storage materials such as activated carbon comprising enhanced gas adsorption properties. The gas storage materials find utility in any number of gas storage applications. Methods for making the gas storage materials are also disclosed.

A compression apparatus includes at least one compression unit, a voltage applier, an anode end plate provided on an anode separator located at a first end in a direction of stacking, a cathode end plate provided on a cathode separator located at a second end in the direction of stacking, a first seal material that surrounds an outer periphery of the cathode, and a second seal material that surrounds an outer periphery of a first space in which to store compressed hydrogen, the first space being provided between the cathode end plate and the cathode separator located at the second end. The compression apparatus causes, by using the voltage applier to apply a voltage, protons taken out from an anode fluid that is supplied to the anode to move to the cathode via the electrolyte membrane and produces compressed hydrogen. An area of a region surrounded by the second seal material is larger than an area of a region surrounded by the first seal material.

A provided ammonia synthesis catalyst is a composite catalyst including: a catalyst exhibiting catalytic activity for synthesis of ammonia; and a support supporting the catalyst. The support includes a hydrogen storage material. The hydrogen storage material is, for example, a hydrogen storage metal. The hydrogen storage metal is, for example, a hydrogen storage alloy. The hydrogen storage alloy is, for example, a solid solution. The hydrogen storage alloy is, for example, a Ti—Mn-based alloy. The catalyst includes, for example, a transition metal. The transition metal is, for example, at least one selected from the group consisting of Ru, Co, Ni, Fe, Mn, V, and Ti.

The invention provides non-naturally occurring microbial organisms containing butadiene or 2,4-pentadienoate pathways comprising at least one exogenous nucleic acid encoding a butadiene or 2,4-pentadienoate pathway enzyme expressed in a sufficient amount to produce butadiene or 2,4-pentadienoate. The organism can further contain a hydrogen synthesis pathway. The invention additionally provides methods of using such microbial organisms to produce butadiene or 2,4-pentadienoate by culturing a non-naturally occurring microbial organism containing butadiene or 2,4-pentadienoate pathways as described herein under conditions and for a sufficient period of time to produce butadiene or 2,4-pentadienoate. Hydrogen can be produced together with the production of butadiene or 2,4-pentadienoate.

The invention provides non-naturally occurring microbial organisms containing butadiene or 2,4-pentadienoate pathways comprising at least one exogenous nucleic acid encoding a butadiene or 2,4-pentadienoate pathway enzyme expressed in a sufficient amount to produce butadiene or 2,4-pentadienoate. The organism can further contain a hydrogen synthesis pathway. The invention additionally provides methods of using such microbial organisms to produce butadiene or 2,4-pentadienoate by culturing a non-naturally occurring microbial organism containing butadiene or 2,4-pentadienoate pathways as described herein under conditions and for a sufficient period of time to produce butadiene or 2,4-pentadienoate. Hydrogen can be produced together with the production of butadiene or 2,4-pentadienoate.