The present invention relates to a synthesis of novel Zn(II)-based Metal Organic Frameworks having mixed organic ligands of 1,3,5-benzene tricarboxylic acid (BTC) and 2-methylimidazole (mIm) through a simple and economic solvothermal method. The synthesized MOFs has cuboids morphology having high surface area (1248 m2/g) capable of hydrogen adsorption at −10° C. to 25° C. temperature and 100 bar pressure. The hydrogen adsorption capabilities of the novel MOFs are in the range of 23-0.2 weight percent.

The hydrogen storage product comprises one or more reduced-graphene oxide layers functionalized with a boron species and decorated with an alkali or alkaline earth metal. Each layer of the structure further comprises boron-oxygen functional groups comprising oxygen atoms bonded to boron atoms. The hydrogen storage product has a composition suitable for physisorption of hydrogen molecule, and operates to reversibly store hydrogen under operating conditions of low pressure and ambient temperature.

An electrochemical hydrogen compressor includes: a cell including a proton conductive electrolyte membrane having a pair of principal surfaces, a cathode disposed on a first one of the principal surfaces of the electrolyte membrane, and an anode disposed on a second one of the principal surfaces of the electrolyte membrane; a voltage applicator that applies a voltage between the anode and the cathode; a dew point adjuster that adjusts a dew point of a hydrogen-containing gas to be supplied to the anode; and a controller that, when the temperature of the cell increases, controls the dew point adjuster to increase the dew point of the hydrogen-containing gas.

A composition for hydrogen (H.sub.2) storage and generation including lithium aluminum hydride (LAIN is provided. The composition includes a mixture of LiAlH.sub.4 and a catalytic metal additive designed to tailor the kinetics of hydrogen release. The LiAlH.sub.4 and catalytic metal additive and are gently mixed together in order to physically disperse the LiAlH.sub.4 and catalyst powders without causing a detrimental chemical interaction. The hydrogen capacity of the composition is substantially not reduced or decreased (e.g., undergoes less than about 5% reduction) during the mixing process.

A composite structure is disclosed forming part of a wall of a liquid hydrogen tank, and including at least one thermal protection device having one or more of hollow fibers, such as to create thermal protection, for example a thermal barrier or a heat exchanger, which makes it possible to protect the composite structure in case of a high temperature gradient between the two faces thereof, while benefiting from the advantages of a composite material in terms of mass.

A hydrogen system includes: a compressor including at least one cell that includes an electrolyte membrane, an anode catalyst layer provided on one principal surface of the electrolyte membrane, a cathode catalyst layer provided on another principal surface of the electrolyte membrane, an anode gas diffusion layer provided on the anode catalyst layer and including a porous sheet containing a metal, and a cathode gas diffusion layer provided on the cathode catalyst layer, and a voltage applicator that apples a voltage between the anode catalyst layer and the cathode catalyst layer, wherein the compressor that generates compressed hydrogen by causing the voltage applicator to apply the voltage to move hydrogen in hydrogen-containing gas supplied to an anode to the cathode via the electrolyte membrane; and a controller that causes the voltage applicator to apply the voltage after shutdown or at startup.

A vapor chamber has: a container in which a cavity portion is formed in an inside; a wick structure provided in the cavity portion; a working fluid enclosed in the cavity portion; a vapor flow path which is formed in the cavity portion and through which the working fluid in a gas phase flows; and a hydrogen occlusion metal that is disposed in the cavity portion and absorbs hydrogen at 350° C. or lower and does not release hydrogen at 350° C. or lower, the hydrogen occlusion metal being coated in a region in contact with the working fluid in an inner surface of the cavity portion and/or the wick structure.

Some embodiments described herein provide for methods for synthesizing magnesium borohydride from hydrogenation of magnesium boride at moderate temperature and pressure in the presence of a modifier. The modifier may be in form of hydrides, liquid hydrogen carriers, ammonia borane, metallic species, croconate anion based materials, ethers, amines or imines, metal carbides, borides, graphene, arenes, magnesium, aluminum, calcium or ionic liquids. Some embodiments provide for charging magnesium boride in presence of a modifier at high pressure hydrogen while simultaneously heating the material. The modification in some instances may lead to an improved magnesium boride product with enhanced properties for application in other hydrogen storage systems.

A heat generating system includes a heat-generating element cell and a circulation device. The heat-generating element cell includes a container having a recovery port and a discharge port, and a reactant that is provided in the container, is made from a hydrogen storage metal or a hydrogen storage alloy, has metal nanoparticles on a surface of the reactant. The heat-generating element cell generates excess heat when hydrogen-based gas contributing to heat generation is supplied into the container and hydrogen atoms are occluded in the metal nanoparticles. The circulation device circulates the hydrogen-based gas in the heat-generating element cell. The circulation device includes a circulating passage that is provided outside the container and connects the recovery port to the discharge port, a pump circulates the hydrogen-based gas in the container via the circulating passage, and a filter on the circulating passage adsorbs and removes the impurities in the hydrogen-based gas.

A heat generating system includes a heat-generating element cell and a circulation device. The heat-generating element cell includes a container having a recovery port and a discharge port, and a reactant that is provided in the container, is made from a hydrogen storage metal or a hydrogen storage alloy, has metal nanoparticles on a surface of the reactant. The heat-generating element cell generates excess heat when hydrogen-based gas contributing to heat generation is supplied into the container and hydrogen atoms are occluded in the metal nanoparticles. The circulation device circulates the hydrogen-based gas in the heat-generating element cell. The circulation device includes a circulating passage that is provided outside the container and connects the recovery port to the discharge port, a pump circulates the hydrogen-based gas in the container via the circulating passage, and a filter on the circulating passage adsorbs and removes the impurities in the hydrogen-based gas.