Disclosed herein is a method and device for production of a new long-term storage-stable allotropic modification of oxygen, tetraoxygen O.sub.4, using a combination of known chemical reactions into one technological sequence, including chemical interaction of negative and positive oxidation state oxygen compounds. The method involves production of dioxygen difluoride by oxidation of molecular oxygen with fluorine, followed by the reaction of dioxygen difluoride with alkali metal peroxide, forming tetraoxygen O.sub.4. Tetraoxygen is stable in its liquid state up to a temperature of +40° C. and can be used for the oxidation of rocket fuel, long-term compact storage of oxygen, and many other purposes.

A reactive oxygen species formulation is provided by preparing a peracid mixture in an activated pH range including mixing alkaline hydrogen peroxide solution with acyl donor in molar proportions with an excess of the acyl donor to hydrogen peroxide. The hydrogen peroxide and acyl donor are reacted to produce a peracid mixture comprising no more than a small quantity of hydrogen peroxide, and pH is adjusted as needed to initially prepare the formulation in the activated pH range. Water treatment with the reactive oxygen species formulation facilitates formation and separation of solids removable during clarification, and which may be followed by a second treatment with the reactive oxygen species formulation for antimicrobial treatment of clarified water.

A reactive oxygen species formulation is provided by preparing a peracid mixture in an activated pH range including mixing alkaline hydrogen peroxide solution with acyl donor in molar proportions with an excess of the acyl donor to hydrogen peroxide. The hydrogen peroxide and acyl donor are reacted to produce a peracid mixture comprising no more than a small quantity of hydrogen peroxide, and pH is adjusted as needed to initially prepare the formulation in the activated pH range. Water treatment with the reactive oxygen species formulation facilitates formation and separation of solids removable during clarification, and which may be followed by a second treatment with the reactive oxygen species formulation for antimicrobial treatment of clarified water.

A process for in situ thermal recovery of hydrocarbons from a reservoir is provided. The process includes: providing an oxygen-enriched mixture, fuel, feedwater and an additive including at least one of ammonia, urea and a volatile amine to a Direct-Contact Steam Generator (DCSG); operating the DCSG, including contacting the feedwater and the additive with hot combustion gas to obtain a steam-based mixture including steam, CO.sub.2 and the additive; injecting the steam-based mixture or a stream derived from the steam-based mixture into the reservoir to mobilize the hydrocarbons therein; and producing a produced fluid including the hydrocarbons.

A composite membrane for hydrogen separation and purification, including: a modified and activated support, a Palladium (Pd) layer, and an interstice layer between the second surface-modifying layer and the Pd layer. The support includes a support substrate, a first surface-modifying layer on the support substrate, and a second surface-modifying layer on the first surface-modifying layer.

An apparatus includes an emitter comprising an ultraviolet light emitting diode (UV-LED) disposed on a first end of an optical cuvette. An extraction cuvette may hold a liquid having a positive Langelier saturation index (LSI), and having a quantity of ozone gas dissolved therein. Air may be bubbled through the liquid in the extraction cuvette, and may then be directed to the optical cuvette. A detector comprising an ultraviolet light sensor (UV sensor) can be disposed on a second end of the optical cuvette. The UV-LED may be a point source, and the emitter may generate a parallel beam of light. A concentration of ozone in the gas in the optical cuvette can be determined based on a diminution of the UV light beam passing therethrough. This concentration can then be used to determine an ozone concentration in the liquid contained in the extraction cuvette.

A process for in situ thermal recovery of hydrocarbons from a reservoir is provided. The process includes: providing an oxygen-enriched mixture, fuel, feedwater and an additive including at least one of ammonia, urea and a volatile amine to a Direct-Contact Steam Generator (DCSG); operating the DCSG, including contacting the feedwater and the additive with hot combustion gas to obtain a steam-based mixture including steam, CO.sub.2 and the additive; injecting the steam-based mixture or a stream derived from the steam-based mixture into the reservoir to mobilize the hydrocarbons therein; and producing a produced fluid including the hydrocarbons.

A process for regulating a unit for the production of oxygen from atmospheric air comprising N adsorbers (, N being = or >2, each according to a PSA, VSA or VPSA adsorption cycle with an offset of a phase time, the regulation process including determining a value of differential pressure characteristic of a step of the adsorption cycle for each adsorber, calculating the difference between the values of differential pressures characteristic of the various adsorbers, comparing this difference with a target value and, in the event of a dissimilarity being noted, correcting by modification of the transfer of at least one oxygen-rich gas stream between adsorbers or optionally between adsorber and storage tank.

Provided is a method for manufacturing a microbicide having high microbicidal performance for eradicating microbes. This method for manufacturing a microbicide comprises: a step for preparing an inorganic aqueous solution containing an inorganic component having seawater as a raw material thereof, an ozone mixing step for mixing ozone into the inorganic aqueous solution, and a stirring step for stirring the inorganic aqueous solution mixed with ozone and passing through a bubble generation nozzle; wherein, the temperature of the inorganic aqueous solution in the ozone mixing step and the stirring step is 0 C. to 30 C., and when the amount of inorganic aqueous solution treated in the ozone mixing step and the stirring step is defined as X liters and the treatment rate of the ozone mixing step and the stirring step is defined as Y liters/minute, then the microbicide is manufactured by alternately repeating the ozone mixing step and the stirring step for A.Math.X/Y minutes (where A is 30 or more).

Disclosed herein are rapid cycle pressure swing adsorption (PSA) process for separating O.sub.2 from N.sub.2 and/or Ar. The processes use a carbon molecular sieve (CMS) adsorbent having an O.sub.2/N.sub.2 and/or O.sub.2/Ar kinetic selectivity of at least 5 and an O.sub.2 adsorption rate (1/s) of at least 0.2000 as determined by linear driving force model at 1 atma and 86 F.