C01B32/00

High-pressure homogenizer and method for manufacturing graphene using the same

Provided a high-pressure homogenizer comprising a channel module comprising a microchannel through which an object for homogenization passes, wherein the microchannel is provided with a first flow channel and a second flow channel sequentially arranged along the direction through which the object passes, the first flow channel is provided with a plurality of first baffles disposed so as to partition the microchannel into a plurality of spaces, the second flow channel is provided with a plurality of second baffles disposed so as to partition the microchannel into a plurality of spaces, and at least one of the first baffles is provided to be positioned between two adjacent second baffles.

Continuous manufacture of graphenic compounds

Provided herein are high throughput continuous or semi-continuous reactors and processes for manufacturing graphenic materials, such as graphene oxide. Such processes are suitable for manufacturing graphenic materials at rates that are up to hundreds of times faster than conventional techniques, have little batch-to-batch variation, have a high degree of tunability, and have excellent performance characteristics.

Method of making carbon-zinc oxide nanoparticles

The method of making carbon-zinc oxide (C—ZnO) nanoparticles includes grinding a mixture of zinc nitrate hexahydrate (Zn(NO.sub.3).sub.2.6H.sub.2O) and furfural (C.sub.4H.sub.3OCHO) to produce a ground mixture. As a non-limiting example, the zinc nitrate hexahydrate (Zn(NO.sub.3).sub.2.6H.sub.2O) and the furfural (C.sub.4H.sub.3OCHO) may be placed in a mortar and ground, by hand with a pestle, for approximately 10 minutes. The ground mixture is then heated to produce the C—ZnO nanoparticles. As a non-limiting example, the ground mixture may be heated in a quartz tube at a temperature of approximately 500° C.

THREE-DIMENSIONAL POROUS POLYUREA NETWORKS AND METHODS OF MANUFACTURE

Porous three-dimensional networks of polyurea and porous three-dimensional networks of carbon and methods of their manufacture are described. In an example, polyurea aerogels are prepared by mixing an triisocyanate with water and a triethylamine to form a sol-gel material and supercritically drying the sol-gel material to form the polyurea aerogel.

Subjecting the polyurea aerogel to a step of pyrolysis may result in a three dimensional network having a carbon skeleton, yielding a carbon aerogel. The density and morphology of polyurea aerogels can be controlled by varying the amount of isocyanate monomer in the initial reaction mixture. A lower density in the aerogel gives rise to a fibrous morphology, whereas a greater density in the aerogel results in a particulate morphology. Polyurea aerogels described herein may also exhibit a reduced flammability.

THREE-DIMENSIONAL POROUS POLYUREA NETWORKS AND METHODS OF MANUFACTURE

Porous three-dimensional networks of polyurea and porous three-dimensional networks of carbon and methods of their manufacture are described. In an example, polyurea aerogels are prepared by mixing an triisocyanate with water and a triethylamine to form a sol-gel material and supercritically drying the sol-gel material to form the polyurea aerogel.

Subjecting the polyurea aerogel to a step of pyrolysis may result in a three dimensional network having a carbon skeleton, yielding a carbon aerogel. The density and morphology of polyurea aerogels can be controlled by varying the amount of isocyanate monomer in the initial reaction mixture. A lower density in the aerogel gives rise to a fibrous morphology, whereas a greater density in the aerogel results in a particulate morphology. Polyurea aerogels described herein may also exhibit a reduced flammability.

HEAT RESISTANT AEROGEL MATERIALS

The present disclosure provides an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which also has favorable combustion and self-heating properties. Also provided is a method of preparing an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which has favorable combustion and self-heating properties. Further provided is a method of improving the hydrophobicity, the liquid water uptake, the heat of combustion, or the onset of thermal decomposition temperature of an aerogel composition.

CARBON CATALYST, BATTERY ELECTRODE, AND BATTERY

A carbon catalyst has a carbon structure with a crystallite size Lc falling within 0.90 nm or more and 1.20 nm or less calculated through use of a Bragg angle of a diffraction peak f.sub.broad at a diffraction angle 2θ of 24.0°±4.0° obtained by separating a diffraction peak in the vicinity of a diffraction angle 2θ of 26° in an X-ray diffraction pattern obtained by powder X-ray diffraction using a CuKα ray, and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 97 μmol/g or less, a total of a carbon monoxide desorption amount and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 647 μmol/g or less, or a carbon monoxide desorption amount from 650° C. to 1,200° C. of 549 μmol/g or less in a temperature programmed desorption method including measuring a carbon dioxide desorption amount from 25° C. to 1,200° C.

CARBON NANOPARTICLE-POROUS SKELETON COMPOSITE MATERIAL, ITS COMPOSITE WITH LITHIUM METAL, AND THEIR PREPARATION METHODS AND USE

Carbon nanoparticle-porous skeleton composite material, its composite with lithium metal, and their preparation methods and use A carbon nanoparticle-porous skeleton composite material, its composite with lithium metal, and their preparation methods and use. In the carbon nanoparticle-porous skeleton composite material, the porous skeleton is a carbon-based porous microsphere material with a diameter of 1 to 100 μm or a porous metal material having internal pores with a micrometer-scale pore size distribution, and the carbon nanoparticles are distributed in pores and on the surface of the carbon-based porous microsphere material or the porous metal material. The carbon nanoparticle-porous skeleton composite material is mixed with a molten lithium metal to form a lithium-carbon nanoparticle-porous skeleton composite material. The carbon nanoparticles present in the material can better conduct lithium ions during the battery cycle, thereby inhibiting the formation of lithium dendrites, and improving the safety and cycle stability of the battery.

POROUS CARBON, AND POSITIVE ELECTRODE AND LITHIUM SECONDARY BATTERY COMPRISING SAME

Porous carbon particles, and a positive electrode active material and a lithium secondary battery including the same. This may improve the energy density of the lithium secondary battery by applying a porous electrode containing micropores and mesopores and having a uniform size distribution and shape as a positive electrode material.

CONTINUOUS PROCESS FOR MANUFACTURING HIERARCHICALLY POROUS CARBON MATERIAL

Continuous processes for the manufacture of porous carbon materials are disclosed. The process includes the reaction of a self-assembling polymeric mixture, followed by drying and extrusion of the cured, semi-dry polymeric gel extrudate prior to pyrolysis. Also disclosed are porous carbon materials, such as porous carbon monoliths, produced by these processes. In particular, hierarchically porous carbon materials for use as a catalyst support or for the adsorption of gas and other substances that are manufactured by these processes are also disclosed.