A composition of matter having the following chemical structure: $.Math.H_x{O}_{\frac{\left(x-1\right)}{2}}.Math.Z_y$
wherein x is
and odd integer ≥3;
y is an integer between 1 and 20; and
Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or a polyatomic ion having a charge between −1 and −3.

Porous carbon particles, and a positive electrode active material and a lithium secondary battery including the same. This may improve the energy density of the lithium secondary battery by applying a porous electrode containing micropores and mesopores and having a uniform size distribution and shape as a positive electrode material.

Systems and methods for multiple carbon precursors for enhanced battery electrode robustness may include an electrode having an active material, the active material including two or more carbon precursor materials, wherein the carbon precursor materials have different pyrolysis temperatures. A battery may include the electrode. The carbon precursor materials may include polyimide (PI) and polyamide-imide (PAI). The active material may be pyrolyzed at a temperature such that a first carbon precursor material is partially pyrolyzed and a second carbon precursor material is completely pyrolyzed. The carbon precursor materials may include two or more of PI, PAI, carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), and sodium alginate. The active material may include silicon constituting at least 50% of weight of a formed anode after pyrolysis. The active material may include silicon constituting up to 97% of weight of a formed electrode after pyrolysis.

Systems and methods for multiple carbon precursors for enhanced battery electrode robustness may include an electrode having an active material, the active material including two or more carbon precursor materials, wherein the carbon precursor materials have different pyrolysis temperatures. A battery may include the electrode. The carbon precursor materials may include polyimide (PI) and polyamide-imide (PAI). The active material may be pyrolyzed at a temperature such that a first carbon precursor material is partially pyrolyzed and a second carbon precursor material is completely pyrolyzed. The carbon precursor materials may include two or more of PI, PAI, carboxymethyl cellulose (CMC), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), and sodium alginate. The active material may include silicon constituting at least 50% of weight of a formed anode after pyrolysis. The active material may include silicon constituting up to 97% of weight of a formed electrode after pyrolysis.

A process for preparing a porous carbon material. The process comprises the process steps: providing a carbon source; providing an amphiphilic species; contacting the carbon source and the amphiphilic species to obtain a precursor; and heating the precursor to obtain the porous carbon material; wherein the carbon source comprises a carbon source compound, wherein the carbon source compound comprises an aromatic ring having one or more attached OH groups and an ester link.

An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including: a primary particle including an electrochemically active material; and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (I.sub.D) at wave number between 1330 cm.sup.-1 and 1360 cW.sup.-1; a G band having a peak intensity (I.sub.G) at wave number between 1530 cm.sup.-1 and 1580 cm.sup.-1; and a 2D band having a peak intensity (I.sub.2D) at wave number between 2650 cm.sup.-1 and 2750 cm.sup.-1. In one embodiment, a ratio of I.sub.D/I.sub.G ranges from greater than zero to about 1.1, and a ratio of 1.sub.2D/I.sub.G ranges from about 0.4 to about 2.

The invention includes apparatus and methods for instantiating rare earth metals in a nanoporous carbon powder.

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

The present invention provides a porous carbon fiber which has an excellent permeation amount and excellent pressure resistance, which is prevented from the occurrence of detachment or cracking at an interface, and which can exhibit excellent properties needed for use as a support for a fluid separation membrane. The present invention is a porous carbon fiber having a bicontinuous porous structure, wherein the average value R.sub.ave of the R value of the outer surface and the R value of the inside is 1.0 or more and 1.8 or less, the absolute value ΔR of the difference between the R value of the outer surface and the R value of the inside is 0.05 or less, and R value is a carbonization progression degree calculated from a Raman spectrum in accordance with the following formula:
R value=(intensity of scattering spectrum at 1360 cm.sup.−1)/(intensity of scattering spectrum at 1600 cm.sup.−1).

Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof are provided. Embodiments include a silicon-doped anode material for a lithium-ion battery, where the anode material includes beads of polyimide-derived carbon aerogel. The carbon aerogel includes silicon particles and accommodates expansion of the silicon particles during lithiation. The anode material provides optimal properties for use within the lithium-ion battery.