Patent classifications
C01B37/00
METAL ORGANIC FRAMEWORK
A solid metal organic framework composition comprising a solid oxyanion-modified metal organic framework wherein the oxyanion loading is at least 2 per node.
METAL ORGANIC FRAMEWORK
A solid metal organic framework composition comprising a solid oxyanion-modified metal organic framework wherein the oxyanion loading is at least 2 per node.
METHOD OF USING METAL ORGANIC FRAMEWORK
A process comprising a heterogeneous reaction between a solid metal organic framework supported sulfonic acid and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
METHOD OF USING METAL ORGANIC FRAMEWORK
A process comprising a heterogeneous reaction between a solid oxyanion-modified metal organic framework and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
METHOD OF USING METAL ORGANIC FRAMEWORK
A process comprising a heterogeneous reaction between a solid oxyanion-modified metal organic framework and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
METHOD OF USING METAL ORGANIC FRAMEWORK
A process comprising a heterogeneous reaction between a solid oxyanion-modified metal organic framework and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
METHOD OF USING METAL ORGANIC FRAMEWORK
A process comprising a heterogeneous reaction between a solid oxyanion-modified metal organic framework and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.
SOLIDOTHERMAL SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE
The present invention relates to a process for the production of a zeolitic material having an MWW framework structure comprising YO.sub.2 and B.sub.2O.sub.3, wherein Y stands for a tetravalent element, said process comprising (i) preparing a mixture comprising one or more sources for YO.sub.2, one or more sources for B.sub.2O.sub.3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I)
R.sup.1R.sup.2R.sup.3N (I) wherein R.sup.1 is (C.sub.5-C.sub.8)cycloalkyl, and wherein R.sup.2 and R.sup.3 are independently from each other H or alkyl, and wherein the mixture prepared in (i) and crystallized in (ii) contains 35 wt.-% or less of H.sub.2O based on 100 wt.-% of YO.sub.2 contained in the mixture prepared in (i) and crystallized in (ii), as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process and to its use.
METAL-ORGANIC FRAMEWORK MATERIAL/MEMBRANE COMPOSITE MATERIAL, PREPARATION METHOD AND USE THEREOF
The present disclosure provides a metal-organic framework material/membrane composite material, a preparation method and a use thereof, which belongs to the technical field of water treatment. The method includes: mixing a membrane material with an alkali liquor, and performing a hydrolysis to obtain a hydrolyzed membrane; impregnating the hydrolyzed membrane in a metal salt aqueous solution and a framework organic solution in sequence, to form a metal-organic framework material/membrane composite material. In the composite material obtained by this method, the bonding strength between the membrane material and the metal-organic framework material is high, and it is not easy to separate them during the use and the composite material could be widely used. At the same time, the metal-organic framework material/membrane composite material obtained by this method has dual functionality, and thus could improve the efficiency of water treatment.
Solidothermal synthesis of a boron-containing zeolite with an MWW framework structure
Described herein is a process for producing a zeolitic material having an MWW framework structure containing YO.sub.2 and B.sub.2O.sub.3, in which Y stands for a tetravalent element. The process includes the steps of (i) preparing a mixture containing one or more sources for YO.sub.2, one or more sources for B.sub.2O.sub.3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, and (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure. Also disclosed herein are synthetic boron-containing zeolites obtain by the process and uses thereof.