C01F17/00

Beneficiation of rare earth elements bearing ancylite
10618058 · 2020-04-14 ·

Disclosed herein are methods and systems for recovery of ancylite, a rare earth mineral comprising strontium carbonate, from rare earth ore. In many embodiments, the disclosed methods and systems provide for recovery of greater than 50% of the ancylite from an ancylite containing ore. In many embodiments, the ore is subjected to flotation in the presence of an acid, for example a hydroxamic acid, such as octanohydroxamic acid. The ore may also be subjected to magnetic separation, for example wet high intensity magnetic separation.

Complex oxide, method for producing same, and exhaust gas purification catalyst

Provided are: a complex oxide that exhibits high redox ability even at low temperatures, has excellent heat resistance, and stably retains these characteristics even on repeated oxidation and reduction at high temperature; a method for producing the same; and an exhaust gas purification catalyst. The inventive complex oxide contains Ce; rare earth metal element other than Ce, including Y; Al and/or Zr; and Si; such that the Ce, and said other elements other than Ce and Si, are present in a mass ratio of 85:15-99:1, calculated as oxides; and has a characteristic such that when it is subjected to temperature-programmed reduction (TPR) measurement in a 10% hydrogen-90% argon atmosphere at from 50 C. to 900 C. with the temperature increasing at a rate of 10 C./min, followed by oxidation treatment at 500 C. for 0.5 hours, and then temperature-programmed reduction measurement is performed again, its calculated reduction rate at and below 400 C. is at least 2.0%.

Thermal spray slurry and method of forming thermal sprayed coating

To provide thermal spray slurry capable of forming a thermal sprayed coating having a high adhesion strength on a thermal spray target surface of a substrate, disclosed is thermal spray slurry for forming a thermal sprayed coating on the thermal spray target surface by spraying the thermal spray slurry on the thermal spray target surface of the substrate, the thermal spray slurry containing: thermal spray particles having a 50% particle diameter D50 equal to or larger than 1 m and equal to or smaller than 5 m in volume-based cumulative particle diameter distribution; and a dispersion medium in which the thermal spray particles are dispersed. In addition, a ratio D10/Ra between a surface roughness Ra (unit: m) of the thermal spray target surface and a 10% particle diameter D10 (unit: m) of the thermal spray particles in the volume-based cumulative particle diameter distribution satisfies a formula 0.4<D10/Ra0.9.

Composite hexagonal ferrite materials

Disclosed herein are embodiments of composite hexagonal ferrite materials formed from a combination of Y phase and Z phase hexagonal ferrite materials. Advantageously, embodiments of the material can have a high resonant frequency as well as a high permeability. In some embodiments, the materials can be useful for magnetodielectric antennas.

Lanthanide fluoride two-dimensional porous nanosheets, and preparation method and applications thereof

The present application provides a method for preparing lanthanide fluoride two-dimensional porous nanosheets and belongs to the field of novel materials. In the present application, mixing a water-soluble lanthanide metal salt and an aqueous solution of sodium acetate in a nitrogen atmosphere to obtain a mixed solution, and adding an aqueous solution of fluorine-containing salt to the mixed solution obtained for precipitation reaction to produce lanthanide fluoride two-dimensional porous nanosheets. In the preparation process provided by the present application, no additional surfactant or template agent needs to be added, the pollution of the surfactant to the surface of the prepared material is avoided and the tedious after-treatment steps to template agent are reduced. Accordingly, the large-scale production can be realized, and the lanthanide fluoride two-dimensional porous nanosheets constructed by nanoparticles are prepared in large scale by one step. Moreover, no other organic solvents are required, and the pollution to the environment during the preparation process is avoided.

Lanthanum Carbonate Hydroxide, Lanthanum Oxycarbonate and Methods of Their Manufacture and Use

The present invention is a method of producing a lanthanum carbonate hydroxide or lanthanum oxycarbonate which has improved properties. The method involves the use of a water soluble lanthanum and a water soluble non-alkali metal carbonate or bicarbonate. The resulting material can be used as a phosphate binder individually or for treating patients with hyperphosphatemia.

LIQUID SUSPENSION OF CERIUM OXIDE PARTICLES
20200087539 · 2020-03-19 ·

The present invention relates to a suspension of cerium oxide particles in a liquid phase, in which said particles comprise secondary particles comprising primary particles, and a process for preparing said liquid suspension in which the cerium IV/total cerium molar ratio before precipitation is comprised between 1/10000 and 1/500000 and that the thermal treatment is being carried out under an inert atmosphere.

Perovskite-type halides and methods thereof

Metal halide optical materials (e.g., scintillator materials or persistent phosphors) are described. More particularly, the optical materials include codoped perovskite-type halides, wherein the codoping ion is present at a molar ratio of 5000 parts per million (ppm) or less with respect to all cations. For example, the optical material can be a codoped trihalide having the formula ABX.sub.3 where A is one or more alkali metal, B is one or more alkali earth metal, and X is one or more halide that is doped with up to about 10 atomic percent of a dopant ion and codoped with up to about 5000 ppm of one or more isovalent or aliovalent codopant ion, such as a tetravalent ion (e.g., Zr.sup.4+), a trivalent ion (e.g., Sc.sup.3+, Y.sup.3+, Gd.sup.3+, or La.sup.3+ ion) or a divalent ion (e.g., Mg.sup.2+). The codoped material can have modified afterglow compared to a noncodoped material.

Single step solution combustion synthesis of crystalline transuranic-doped rare earth zirconate pyrochlores

One-step solution combustion synthesis (SCS) methods for fabricating durable crystalline transuranic-doped rare earth zirconium pyrochlores are described. Methods are fast, amenable to upscaling, and present a simple strategy for producing crystalline ceramic materials that meet the minimum attractiveness criteria for special nuclear material. The methods include analysis of reactants and reaction conditions to select proper fuel as well as proper fuel content so as to encourage formation of the crystalline product in a single-step synthesis procedure.

PRODUCTION OF ETHYLENE WITH NANOWIRE CATALYSTS

Nanowires useful as heterogeneous catalysts are provided. The nanowires catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to ethylene. Related methods for use and manufacture of the same are also disclosed.