Gallium-68 generators that are capable of producing gallium-68 from a germanium-68 source material are disclosed. The source material may be a matrix material (e.g., zeolite) in which germanium-68 is isomorphously substituted for central atoms in tetrahedra within the matrix material. Methods for forming gallium-68 generators are also disclosed.

Described are luminescent components with excellent performance and stability. The luminescent components comprise a first element 1 including first luminescent crystals 11 from the class of perovskite crystals, embedded a first polymer P1 and a second element 2 comprising a second solid polymer composition, said second polymer composition optionally comprising second luminescent crystals 12 embedded in a second polymer P2. Polymers P1 and P2 differ and are further specified in the claims. Also described are methods for manufacturing such components and devices comprising such components.

A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.

A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.

A method for the production of germane includes reacting an oxide of germanium and/or a non-oxide of germanium compound with a borohydride in a base solution. The method permits production of germane from impure germanium-containing starting materials. Catalysts for the reaction include transition metal elements, as well as oxides, hydroxides, halides, and other complexes or compounds of transition metals. Application of heat increases the efficiency of the catalyst. The methods also include production of germane through oxidation of a pure or impure oxide or non-oxide of germanium. The oxidation is effected by contacting the germanium-containing solid phase starting material with an oxidizing solution. The oxidizing solution may be a basic solution comprising a hydroxide or an acidic solution. The oxidation product of the germanium-containing solid phase starting material is converted to germane through an electrochemical or chemical reduction process.

A method for the manufacture of highly purified .sup.68Ge material for radiopharmaceutical purposes. The invention particularly concerns the production of .sup.68Ge-API (API=Active Pharmaceutical Ingredient) solution complying with the Guidelines for good manufacturing practices (GMP). Starting material for the method of the present invention can be a .sup.68Ge stock solution of commercial or other origin as raw material. Such .sup.68Ge containing raw solutions are purified from potential metal and organic impurities originating from production processes. The radiochemical method disclosed is based on a twofold separation of .sup.68Ge from organic and metallic impurities with two different adsorbent materials. During the first separation phase .sup.68Ge is purified from both organic and metallic impurities by adsorption in germanium tetrachloride form, after which hydrolyzed .sup.68Ge is purified from remaining metallic impurities by cation exchange. The final .sup.68Ge-API-product e.g. fulfills the regulatory requirements for specifications of the GMP production of .sup.68Ge/.sup.68Ga generators.

A multi-atomic layered material and methods of making and using the same are described. The material can include a first 2D non-carbon mono-element atomic layer, a second 2D non-carbon mono-element atomic layer, and intercalants positioned between the first and second atomic layers.

Anhydrous liquid-phase exfoliation of germanium sulfide to provide few-layer germanium sulfide, as can be incorporated into electronic devices such as but not limited to batteries and cells comprising such materials.

Anhydrous liquid-phase exfoliation of germanium sulfide to provide few-layer germanium sulfide, as can be incorporated into electronic devices such as but not limited to batteries and cells comprising such materials.

The present invention relates to a compound represented by the general formula Li.sub.2+2xM.sub.1-xZS.sub.4, wherein 0.3≤x≤0.9; wherein M is one or more elements selected from the group consisting of Pb, Mg, Ca, Ge and Sn; and wherein Z is one or more elements selected from the group consisting of Ge, Si, Sn and Al.

The present invention also relates to a method for preparing the material of the present invention, comprising the steps of: (a) providing a mixture of lithium sulfide Li.sub.2S, sulfides MS and ZS.sub.2, in a stoichiometric ratio ensuring Li.sub.2+2xM.sub.1-xZS.sub.4 to be obtained, wherein M, Z and x are as defined above; (b) pelletizing the mixture prepared in step (a); (c) heating at a maximum plateau temperature.

In still another aspect, the present invention relates to a use of the compound of the present invention as a solid electrolyte, in particular in an all solid-state lithium battery.