A method includes at least partially submerging a substrate in a colloidal mixture of nanocrystals and a first solvent. The nanocrystals have first ligands coupled thereto. The method also includes applying an electric field to the colloidal mixture to form a solvated nanocrystal film and removing the solvated nanocrystal film from the first solvent. The method further includes applying a second solvent to the solvated nanocrystal film for ligand exchange. The second solvent comprises second ligands. A nanocrystal film product formed by one-step ligand exchange includes at least one dimension greater than 100 nm and ordered nanocrystals characterized as having a domain size of greater than 100 nm.

The present invention relates to the field of luminescent crystals (LCs), and more specifically to Quantum Dots (QDs) of formula M.sup.1.sub.aM.sup.2.sub.bX.sub.c, wherein the substituents are as defined in the specification. The invention provides methods of manufacturing such luminescent crystals, particularly by dispersing suitable starting materials in the presence of a liquid and by the aid of milling balls; to compositions comprising luminescent crystals and to electronic devices, decorative coatings; and to intermediates comprising luminescent crystals.

A light-emitting material including aminosiloxane and a light-emitting compound represented by Formula 1, a light-emitting device including the light-emitting material, a method of preparing the light-emitting material, and a method of preparing the light-emitting compound represented by Formula 1:

A.sup.1B.sup.1X.sup.1.sub.3,  Formula 1 wherein A.sup.1 may be an alkali metal, B.sup.1 may be Pb, Sn, or any combination thereof, and X.sup.1 may be a halogen.

Described herein are materials comprising (1) a monomer or a polymer; (2) perovskite quantum dots interspersed in the monomer or the polymer, each of the perovskite quantum dots independently having the formula:

Cs.sub.a(MA).sub.b(FA).sub.cRb.sub.dPb.sub.pSn.sub.rBi.sub.sCl.sub.xBr.sub.yI.sub.z,

wherein: MA is CH.sub.3NH.sub.3; FA is HC(NH.sub.2).sub.2; a, b, c, and d are each independently a number from 0 to 1, provided that the sum of a, b, c, and d is 1; p, r, and s are each independently a number from 0 to 1, provided that the sum of p, r, and s is 1; and x, y, and z are each independently a number from 0 to 3, provided that the sum of x, y, and z is 3; and (3) an additive interspersed in the monomer or the polymer, the additive comprising: a halide-based additive; a light scattering agent having the formula: M.sub.2O.sub.3, wherein M is, at each occurrence, independently, a metal, provided that at most one instance of M is a group 13 element; or both. Also described are devices comprising such materials, as well as methods of forming such materials.

Methods for producing ferric maltol compositions, such as ferric trimaltol, from elemental iron, and ferric maltol compositions produced by these methods and their uses are described.

Bandgap-tunable perovskite compositions are provided having the formula CsPb(A).sub.xB.sub.y).sub.3, wherein A and B are each a halogen. The mixed halide perovskite composition has a morphology which suppresses phase segregation to stabilize a tuned bandgap of the mixed halide perovskite composition. For example, the perovskite may be in the form of nanocrystals embedded in a non-perovskite matrix, which, for example, may have the formula Cs.sub.4Pb(A).sub.xB.sub.y).sub.6, wherein A and B are each a halogen. Solar cells and light-emitting diodes comprising the mixed perovskite compositions are also provided.

A reverse mode light valve, the manufacture of a light control device and a method of controlling light transmittance by using of the reverse mode light valve, the reverse mode light valve containing ABX.sub.3 perovskite particles (200) suspended in a liquid suspension (300) can control light transmittance in a higher light transmittance when the power is turned off (OFF state) and lower light transmittance when the power is turned on (ON state). In the ABX.sub.3 perovskite particles (200), A is at least one of Cs.sup.+, CH.sub.3NH.sub.3.sup.+, and Rb.sup.+, B is at least one of Pb.sup.2+, Ge.sup.2+, and Sn.sup.2+, and X is at least one of Cl.sup.−, Br.sup.−, and I.sup.−.

Described are luminescent components with excellent performance and stability. The luminescent components comprise a first element 1 including first luminescent crystals 11 from the class of perovskite crystals, embedded a first polymer P1 and a second element 2 comprising a second solid polymer composition, said second polymer composition optionally comprising second luminescent crystals 12 embedded in a second polymer P2. Polymers P1 and P2 differ and are further specified in the claims. Also described are methods for manufacturing such components and devices comprising such components.

A flexible photovoltaic device is provided. The flexible photovoltaic device includes a flexible inorganic halide perovskite. The flexible inorganic halide perovskite is free of organic components, has a thickness of greater than or equal to about 1 μm to less than or equal to about 1 nm, and has an average grain size of less than or equal to about 500 nm.

A multi-atomic layered material and methods of making and using the same are described. The material can include a first 2D non-carbon mono-element atomic layer, a second 2D non-carbon mono-element atomic layer, and intercalants positioned between the first and second atomic layers.