C01G33/00

Exfoliating layered transition metal dichalcogenides

A technique for exfoliating a transition metal dichalcogenide material to produce separated nano-scale platelets includes combining the transition metal dichalcogenide material with a liquid to form a slurry, wherein the transition metal dichalcogenide material includes layers of nano-scale platelets and has a general chemical formula MX.sub.2, and wherein M is a transition metal and X is sulfur, selenium, or tellurium. The slurry of the transition metal dichalcogenide material is treated with an oxidant to form peroxo-metalate intermediates on an edge region of the layers of nano-scale platelets of the transition metal dichalcogenide material. The peroxo-metalate intermediates is treated with a reducing agent to form negatively charged poly-oxo-metalates to induce separation of the transition metal dichalcogenide material into the separated nano-scale platelets of the transition metal dichalcogenide material.

Lithium—transition metal oxide powder and method of producing the same, positive electrode active material for lithium ion battery, and lithium ion secondary battery
09761868 · 2017-09-12 · ·

There is provided a lithium-transition metal oxide powder with a coating layer containing lithium niobate formed on a part or the whole part of a surface of a lithium-transition metal oxide particle and having a low powder compact resistance, and a positive electrode active material for a lithium ion battery containing the lithium-transition metal oxide powder. Specifically, there is provided the lithium-transition metal oxide powder composed of a lithium-transition metal oxide particle with a part or the whole part of a surface coated with a coating layer containing lithium niobate, wherein a carbon-content is 0.03 mass % or less.

Lithium—transition metal oxide powder and method of producing the same, positive electrode active material for lithium ion battery, and lithium ion secondary battery
09761868 · 2017-09-12 · ·

There is provided a lithium-transition metal oxide powder with a coating layer containing lithium niobate formed on a part or the whole part of a surface of a lithium-transition metal oxide particle and having a low powder compact resistance, and a positive electrode active material for a lithium ion battery containing the lithium-transition metal oxide powder. Specifically, there is provided the lithium-transition metal oxide powder composed of a lithium-transition metal oxide particle with a part or the whole part of a surface coated with a coating layer containing lithium niobate, wherein a carbon-content is 0.03 mass % or less.

Lithium ion-conducting garnet-like compounds

A lithium ion-conducting compound, having a garnet-like crystal structure, and having the general formula: Li.sub.n[A.sub.(3-a′-a″)A′.sub.(a′)A″.sub.(a″)][B.sub.(2-b′-b″)B′.sub.(b′)B″.sub.(b″)][C′.sub.(c′)C″.sub.(c″)]O.sub.12, where A, A′, A″ stand for a dodecahedral position of the crystal structure, where A stands for La, Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and/or Yb, A′ stands for Ca, Sr and/or Ba, A″ stands for Na and/or K, 0<a′<2 and 0<a″<1, where B, B′, B″ stand for an octahedral position of the crystal structure, where B stands for Zr, Hf and/or Sn, B′ stands for Ta, Nb, Sb and/or Bi, B″ stands for at least one element selected from the group including Te, W and Mo, 0<b′<2 and 0<b″<2, where C and C″ stand for a tetrahedral position of the crystal structure, where C stands for Al and Ga, C″ stands for Si and/or Ge, 0<c′<0.5 and 0<c″<0.4, and where n=7+a′+2.Math.a″−b′−2.Math.b″−3.Math.c′−4.Math.c″ and 5.5<n<6.875.

Chiral nematic nanocrystalline metal oxides

A mesoporous metal oxide materials with a chiral organization; and a method for producing it, in the method a polymerizable metal oxide precursor is condensed inside the pores of chiral nematic mesoporous silica by the so-called “hard templating” method. As a specific example, mesoporous titanium dioxide is formed inside of a chiral nematic silica film templated by nanocrystalline cellulose (NCC). After removing the silica template such as by dissolving the silica in concentrated aqueous base, the resulting product is a mesoporous titania with a high surface area. These mesoporous metal oxide materials with high surface area and chiral nematic structures that lead to photonic properties may be useful for photonic applications as well as enantioselective catalysis, photocatalysis, photovoltaics, UV filters, batteries, and sensors.

Chiral nematic nanocrystalline metal oxides

A mesoporous metal oxide materials with a chiral organization; and a method for producing it, in the method a polymerizable metal oxide precursor is condensed inside the pores of chiral nematic mesoporous silica by the so-called “hard templating” method. As a specific example, mesoporous titanium dioxide is formed inside of a chiral nematic silica film templated by nanocrystalline cellulose (NCC). After removing the silica template such as by dissolving the silica in concentrated aqueous base, the resulting product is a mesoporous titania with a high surface area. These mesoporous metal oxide materials with high surface area and chiral nematic structures that lead to photonic properties may be useful for photonic applications as well as enantioselective catalysis, photocatalysis, photovoltaics, UV filters, batteries, and sensors.

Eu2+-activated phosphors

The invention relates to Eu.sup.2+-activated phosphors, to a process of its preparation, the use of these phosphors in electronic and electro optical devices, such as light emitting diodes (LEDs) and solar cells and especially to illumination units comprising said magnesium alumosilicate-based phosphors.

BISMUTH AND MAGNESIUM CO-DOPED LITHIUM NIOBATE CRYSTAL, PREPARATION METHOD THEREOF AND APPLICATION THEREOF

A bismuth and magnesium co-doped lithium niobate crystal includes Li.sub.2CO.sub.3, Nb.sub.2O.sub.5, Bi.sub.2O.sub.3 and MgO, wherein the molar ratio of [Li] and [Nb] is 0.90-1.00, the molar percentage of Bi.sub.2O.sub.3 in the mixture is 0.25-0.80%, and the molar percentage of MgO in the mixture is 3.0-7.0%. The bismuth and magnesium co-doped lithium niobate crystal has enhanced photorefraction, improved photorefractive sensitivity, shortened holographic grating saturation writing time, and the photorefractive diffraction efficiency can reach up to 17%. The response time is only 170 ms, when the holographic storage experiment is carried out using 488 nm continuous laser. Therefore, this crystal can be used in the field of holographic imaging.

CLASS OF POROUS METAL OXIDE-BASED ELECTROCHEMICAL ENERGY STORAGE MATERIALS AND PREPARATION METHOD AND APPLICATION THEREOF
20220238875 · 2022-07-28 ·

The invention relates to a class of electrochemical energy storage materials and a preparation method and application thereof. A porous metal oxide-based electrochemical energy storage material at least comprises a host metal oxide with a hierarchical pore structure; wherein, the host metal oxide is a single crystal, quasicrystal, or twin crystal structure with ordered atomic lattice arrangement, the crystal is rich in oxygen atom vacancy defects, the structural general formula is M.sub.xO.sub.y−z, wherein M is selected from one or more combinations of niobium element, molybdenum element, titanium element, vanadium element, manganese element, iron element, cobalt element, nickel element, copper element, zinc element, tungsten element, tantalum element, and zirconium element; and 1≤x≤2, 1≤y≤5, and 0.1≤z≤0.9, preferably Nb.sub.2O.sub.5−z.

Dielectric Ceramic Composition and Ceramic Capacitor Using the Same
20220234958 · 2022-07-28 ·

The present invention discloses a dielectric ceramic formula enabling one to obtain a multilayer ceramic capacitor by alternatively stacking the ceramic dielectric layers and base metal internal electrodes. The dielectric ceramic composition comprises a primary ingredient:


[(Na.sub.1-xK.sub.x).sub.sA.sub.1-s].sub.m[(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]O.sub.3

wherein:
A is at least one selected from the alkaline-earth element group of Mg, Ca, Sr, and Ba;
B1 is at least one selected from the group of Ti, Zr, Hf and Sn;
B2 is at least one selected from transition metal elements;
and wherein:
x, y, s, u, v, and w are molar fractions of respective elements, and m is the molar ratio of [(Na.sub.1-xK.sub.x).sub.sA.sub.1-s] and [(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]. They are in the following respective range:
0.93≤m≤1.07;
0.7≤s≤1.0;
0.00≤x≤0.05; 0.00≤y≤0.65;
0.7≤u≤1.0; 0.0≤v≤0.3; 0.001≤w≤0.100;
a first sub-component composes of at least one selected from the rare-earth compound,
wherein the rare-earth element is no more than 10 mol % parts with respect to the main component; and
a second sub-component composes a compound with low melting temperature to assist the ceramic sintering process, said frit, which is Li free and could be at least one selected from fluorides, silicates, borides, and oxides. The content of frit is within the range of 0.01 mol % to 15.00 mol % parts with respect to the main component.