Patent classifications
C01G33/00
COMPOSITE PARTICLES, NEGATIVE ELECTRODE MATERIAL, AND LITHIUM-ION SECONDARY BATTERY
An object of the present invention is to provide composite particles capable of suppressing oxidation over time of a Si—C composite material. Composite particles (B) of the present invention contains composite particles (A) containing carbon and silicon; and amorphous layers coating surfaces thereof, where the composite particles (B) have I.sub.Si/I.sub.G of 0.10 or more and 0.65 or less, and have R value (I.sub.D/I.sub.G) of 1.00 or more and 1.30 or less, when a peak due to silicon is present at 450 to 495 cm.sup.−1, an intensity of the peak is defined as I.sub.Si, an intensity of a G band (peak intensity in the vicinity of 1600 cm.sup.−1) is defined as I.sub.G, and an intensity of a D band (peak intensity in the vicinity of 1360 cm.sup.−1) is defined as I.sub.D in a Raman spectrum, and where the composite particles (B) have a full width at half maximum of a peak of a 111 plane of Si of 3.0 deg. or more using a Cu-Kα ray in an XRD pattern.
COMPOSITE PARTICLES, NEGATIVE ELECTRODE MATERIAL, AND LITHIUM-ION SECONDARY BATTERY
An object of the present invention is to provide composite particles capable of suppressing oxidation over time of a Si—C composite material. Composite particles (B) of the present invention contains composite particles (A) containing carbon and silicon; and amorphous layers coating surfaces thereof, where the composite particles (B) have I.sub.Si/I.sub.G of 0.10 or more and 0.65 or less, and have R value (I.sub.D/I.sub.G) of 1.00 or more and 1.30 or less, when a peak due to silicon is present at 450 to 495 cm.sup.−1, an intensity of the peak is defined as I.sub.Si, an intensity of a G band (peak intensity in the vicinity of 1600 cm.sup.−1) is defined as I.sub.G, and an intensity of a D band (peak intensity in the vicinity of 1360 cm.sup.−1) is defined as I.sub.D in a Raman spectrum, and where the composite particles (B) have a full width at half maximum of a peak of a 111 plane of Si of 3.0 deg. or more using a Cu-Kα ray in an XRD pattern.
NIOBATE COMPOUND AND NIOBIUM-CONTAINING SLURRY
A niobate compound is provided that has excellent reactivity with alkali metal salts and can be reacted with alkali metal salts at room temperature. The niobate compound has a ratio (first peak/second peak) of the intensity of a peak (first peak) having the highest intensity at 2θ=9.4°±1.5° to the intensity of a peak (second peak) having the highest intensity at 2θ=29.0°±1.5° being 1.3 or more in the X-ray diffraction pattern.
NIOBATE COMPOUND AND NIOBIUM-CONTAINING SLURRY
A niobate compound is provided that has excellent reactivity with alkali metal salts and can be reacted with alkali metal salts at room temperature. The niobate compound has a ratio (first peak/second peak) of the intensity of a peak (first peak) having the highest intensity at 2θ=9.4°±1.5° to the intensity of a peak (second peak) having the highest intensity at 2θ=29.0°±1.5° being 1.3 or more in the X-ray diffraction pattern.
POSITIVE-ELECTRODE MATERIAL AND BATTERY
A positive-electrode material according to the present disclosure includes a positive-electrode active material and a coating layer covering the positive-electrode active material, wherein the coating layer contains niobium and carbon, the positive-electrode active material and the coating layer constitute a coated active material, and the ratio Nb/C of the niobium content to the carbon content in a surface layer portion of the coated active material is 0.11 or more based on the atomic ratio.
Ceramic
The present invention relates to a ceramic, to a process for preparing the ceramic and to the use of the ceramic as a dielectric in a capacitor.
Thermoelectric conversion material and thermoelectric conversion module
To provide a thermoelectric conversion material having low environmental load and an excellent thermoelectric figure of merit ZT and a thermoelectric conversion module including the thermoelectric conversion material. A thermoelectric conversion material of the present invention is characterized by being a compound represented by Chemical Formula (1).
Cu.sub.26-xM.sub.xA.sub.2E.sub.6-yS.sub.32 (1)
In Chemical Formula (1), M represents a metal material including at least one of Mn, Fe, Co, Ni, and Zn; A represents a metal material including at least one of Nb and Ta; E represents a metal material including at least one of Si, Ge, and Sn; x represents a numerical value of 0 or more and 4 or less; and y represents a numerical value of more than 0 and 1 or less.
LI/NA-ION BATTERY ANODE MATERIALS
The invention relates to active electrode materials and to methods for the manufacture of active electrode materials. Such materials are of interest as active electrode materials in lithium-ion or sodium-ion batteries. The invention provides an active electrode material expressed by the general formula [M][Nb].sub.y[O].sub.z; wherein the active electrode material is oxygen deficient; wherein M consists of one of Mg, Cr, W, Mo, Cu, Ga, Ge, Ca, K, Ni, Co, Al, Sn, Mn, Ce, Sb, Y, La, Hf, Ta, Zn, In, or Cd; y satisfies 0.5≤y≤49; and z satisfies 4≤z≤124.
ELECTROMECHANICAL RESPONSIVE FILM, STACKED ARRANGEMENT AND METHODS OF FORMING THE SAME
Various embodiments may provide an electromechanical responsive film. The electromechanical responsive film may include a composition including sodium (Na), potassium (K), niobium (Nb) and oxygen (O). The composition may have a formula (Na.sub.xK.sub.y)NbO.sub.3-δ, wherein 0≤x<1, wherein 0≤y<1, and wherein 0<x+y<1. The composition may satisfy at least one condition selected from a group consisting of a first condition of (x+y+4)/2≤(3−δ)≤(x+y+5)/2 and a second condition of 0<δ<1.
ELECTROCHEMICALLY-INDUCED AMORPHOUS TO ROCK SALT PHASE TRANSITIONS IN NIOBIUM OXIDE ELECTRODE FOR LITHIUM-ION BATTERIES
Systems and methods are disclosed for a rock-salt structure formed from an electrochemically-driven amorphous-to-crystalline (a-to-c) transformation of nanostructured Nb.sub.2O.sub.5, the rock-salt structure including, upon cycling with lithium ions (Li+), an insertion of lithium ions (Li+) into Nb.sub.2O.sub.5 to form the rock-salt structure (RS—Nb.sub.2O.sub.5).