Patent classifications
C01G49/00
Metal-organic framework manufacturing method
An object of the present invention is to provide a metal-organic framework manufacturing method of manufacturing a metal-organic framework having excellent gas adsorbability and durability. A metal-organic framework manufacturing method according to an embodiment of the present invention includes: a step of mixing a metal salt containing a metal atom and a polydentate ligand in the presence of a solvent to manufacture a metal-organic framework, the polydentate ligand contains a compound represented by Formula (1), a content of the compound represented by Formula (1) in the polydentate ligand is 50 mol % or greater with respect to a total molar amount of the polydentate ligand, the solvent contains an organic solvent having a boiling point of 100° C. or higher, and a water content in the solvent is 0 to 90 mass % with respect to a total mass of the solvent. ##STR00001##
Metal-organic framework manufacturing method
An object of the present invention is to provide a metal-organic framework manufacturing method of manufacturing a metal-organic framework having excellent gas adsorbability and durability. A metal-organic framework manufacturing method according to an embodiment of the present invention includes: a step of mixing a metal salt containing a metal atom and a polydentate ligand in the presence of a solvent to manufacture a metal-organic framework, the polydentate ligand contains a compound represented by Formula (1), a content of the compound represented by Formula (1) in the polydentate ligand is 50 mol % or greater with respect to a total molar amount of the polydentate ligand, the solvent contains an organic solvent having a boiling point of 100° C. or higher, and a water content in the solvent is 0 to 90 mass % with respect to a total mass of the solvent. ##STR00001##
Method for preparing iron nitrate oxyhydroxide, cathode containing iron nitrate oxyhydroxide prepared thereby for lithium secondary battery, and lithium secondary battery comprising same
A method for preparing an iron oxyhydroxynitrate, a positive electrode for a lithium secondary battery including the iron oxyhydroxynitrate prepared therefrom, and a lithium secondary battery including the same. The positive electrode for the lithium secondary battery containing the iron oxyhydroxynitrate includes the iron oxyhydroxynitrate represented by the following Formula 1:
FeO(NO.sub.3).sub.x(OH).sub.1-x, wherein 0<x<1. [Formula 1]
Method for preparing iron nitrate oxyhydroxide, cathode containing iron nitrate oxyhydroxide prepared thereby for lithium secondary battery, and lithium secondary battery comprising same
A method for preparing an iron oxyhydroxynitrate, a positive electrode for a lithium secondary battery including the iron oxyhydroxynitrate prepared therefrom, and a lithium secondary battery including the same. The positive electrode for the lithium secondary battery containing the iron oxyhydroxynitrate includes the iron oxyhydroxynitrate represented by the following Formula 1:
FeO(NO.sub.3).sub.x(OH).sub.1-x, wherein 0<x<1. [Formula 1]
Magnetic materials with high curie temperatures and dielectric constants
Disclosed herein are ceramic materials, such as bismuth substituted garnets, which can have high curie temperatures and high dielectric constants. In certain implementations, indium can be incorporated into the ceramic to improve certain properties and to avoid calcium compensation. The ceramic materials disclosed herein can be particular advantageous for below resonance applications.
IRON OXYHYDROXYNITRATE HAVING PHOSPHORIC ACID ANION-ADSORBED SURFACE, PREPARATION METHOD THEREFOR, CATHODE COMPRISING IRON OXYHYDROXYNITRATE HAVING PHOSPHORIC ACID ANION-ADSORBED SURFACE FOR LITHIUM SECONDARY BATTERY, AND LITHIUM SECONDARY BATTERY COMPRISING SAME
Disclosed is a modified iron oxyhydroxynitrate including iron oxyhydroxynitrate and hydrogen phosphate ions adsorbed on a surface thereof. Also disclosed is a method for preparing the same, a positive electrode for a lithium secondary battery including the modified iron oxyhydroxynitrate as a positive electrode additive, and a lithium secondary battery including the same.
IRON OXYHYDROXYNITRATE HAVING PHOSPHORIC ACID ANION-ADSORBED SURFACE, PREPARATION METHOD THEREFOR, CATHODE COMPRISING IRON OXYHYDROXYNITRATE HAVING PHOSPHORIC ACID ANION-ADSORBED SURFACE FOR LITHIUM SECONDARY BATTERY, AND LITHIUM SECONDARY BATTERY COMPRISING SAME
Disclosed is a modified iron oxyhydroxynitrate including iron oxyhydroxynitrate and hydrogen phosphate ions adsorbed on a surface thereof. Also disclosed is a method for preparing the same, a positive electrode for a lithium secondary battery including the modified iron oxyhydroxynitrate as a positive electrode additive, and a lithium secondary battery including the same.
FERRITE PARTICLES, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER CORE MATERIAL, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER, AND ELECTROPHOTOGRAPHIC DEVELOPER
The present invention provides: a ferrite particle containing a crystal phase component containing a perovskite crystal represented by the compositional formula RZrO.sub.3 (where R is an alkaline earth metal element); and an electrophotographic developer carrier core material, an electrophotographic developer carrier, and an electrophotographic developer containing the ferrite particles.
Manufacturing method of composite oxide and manufacturing method of power storage device
An object is to reduce variation in shape of crystals that are to be formed. Solutions containing respective raw materials are made in an environment where an oxygen concentration is lower than that in air, the solutions containing the respective raw materials are mixed in an environment where an oxygen concentration is lower than that in air to form a mixture solution, and with use of the mixture solution, a composite oxide is formed by a hydrothermal method.
RECHARGEABLE BATTERY CELL
This disclosure relates to a rechargeable battery cell comprising an active metal, at least one positive electrode, at least one negative electrode, a housing and an electrolyte, the positive electrode being designed as a high-voltage electrode and the electrolyte being based on SO.sub.2 and at least one first conducting salt having the formula (I),
##STR00001##
M being a metal selected from the group formed by alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements, and aluminum; x being an integer from 1 to 3; the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 being selected independently of one another from the group formed by C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.10 alkenyl, C.sub.2-C.sub.10 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl and C.sub.5-C.sub.14 heteroaryl; and Z being aluminum or boron.