A CoVO.sub.x composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 μm thick layer of CoVO.sub.x having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVO.sub.x composite electrode is capable of being used in an electrochemical cell for water oxidation.

A positive electrode active material with high charge and discharge capacity is provided. A positive electrode active material with high charge and discharge voltage is provided. A power storage device that hardly deteriorates is provided. A highly safe power storage device is provided. A novel power storage device is provided. A positive electrode active material containing lithium, a plurality of transition metals, oxygen, and an impurity element. The positive electrode active material includes a first region including a surface portion and a second region provided inward from the first region, and the concentration of a transition metal is higher in the first region than in the second region. An impurity region is included between the first region and the second region.

A lithium cobalt-based positive electrode active material is provided. The lithium cobalt-based positive electrode active material includes a core portion including a lithium cobalt-based oxide represented by Formula 1 and a shell portion including a lithium cobalt-based oxide represented by Formula 2, wherein the lithium cobalt-based positive electrode active material includes 2500 ppm or more, preferably 3000 ppm or more of a doping element M based on the total weight of the positive electrode active material. An inflection point does not appear in a voltage profile measured during charging/discharging a secondary battery including the lithium cobalt-based positive electrode active material.

A positive-electrode active material containing a compound that has a crystal structure belonging to the space group FM-3M and is represented by the composition formula (1):
Li.sub.xMe.sub.yO.sub.αF.sub.β  (1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, and Al, and the following conditions are satisfied. 1.3≤x≤2.2, 0.8≤y≤1.3, 1≤α≤2.93, 0.07≤β≤2.

The present disclosure relates to a positive electrode material which includes a first positive electrode active material and a second positive electrode active material, wherein the second positive electrode active material has an electrical conductivity of 0.1 μS/cm to 150 μS/cm, which is measured after the second positive electrode active material is prepared in the form of a pellet by compressing the second positive electrode active material at a rolling load of 400 kgf to 2,000 kgf, a method of preparing the positive electrode material, and a positive electrode for a lithium secondary battery and a lithium secondary battery which include the positive electrode material.

In an aspect, a ferrite composition comprises a Ru—Co.sub.2Z ferrite having the formula: (Ba.sub.3-xM.sub.x)Co.sub.2(M′Ru).sub.yFe.sub.24-2y-zO.sub.41, wherein M is at least one of Sr, Pb, or Ca; M′ is at least one of Co, Zn, Mg, or Cu; x is 1 to 3; y is greater than 0 to 2; and z is −4 to 4. In another aspect, an article comprises the ferrite composition. In yet another aspect, method of making the ferrite composition comprises mixing ferrite precursor compounds comprising Fe, Ba, Co, and Ru; and sintering the ferrite precursor compounds in an oxygen atmosphere to form the Ru—Co.sub.2Z ferrite.

To provide a ferrite sintered magnet having a high residual magnetic flux density (Br) and a high coercive force (HcJ), and also able to produce at a low cost. The ferrite sintered magnet includes a hexagonal M-type ferrite including A, R, Fe, and Co in an atomic ratio of A.sub.1-xR.sub.x(Fe.sub.12-yCo.sub.y).sub.zO.sub.19. A is at least one selected from Sr, Ba, and Pb. R is La only or La and at least one selected from rare earth elements. 0.13≤x≤0.23, 10.80≤(12−y)z≤12.10, and 0.13≤yz≤0.20 are satisfied.

A ferrite sintered magnet including ferrite grains having a hexagonal crystal structure. The ferrite grains satisfy 0.56≤W≤0.68 where W is an average value of circularities of the ferrite grains in a cross section parallel to an axis of easy magnetization.

The present disclosure discloses a cathode composite material for a lithium-ion battery (LIB), and a preparation method thereof. The cathode composite material for an LIB is composed of a lithium-containing matrix and a three-layer coating layer coated on a surface of the matrix, where the three-layer coating layer includes a lithium-deficient matrix material layer, a lithium-deficient lithium cobalt phosphate (LCP) layer, and a cobalt phosphate layer in sequence from inside to outside. The cathode composite material of the present disclosure can reduce the oxidation of a highly-delithiated cathode material to an electrolyte under high voltage, and has a high energy density.

The perovskite compound according to the invention has a cubic perovskite structure, has high catalytic activity in oxygen reduction and evolution reactions, and has excellent durability, and thus, can be used as a catalyst of electrochemical devices, particularly as a fuel cell catalyst.