The present disclosure provides a method to fabricate three-dimensional transparent glass utilizing polymer plasticity, including the following steps. In step 1, synthesize polymer-glass powder composite containing dynamic chemical bonds, the bond exchange catalyst is added during the synthesis process, and then cure to obtain a two-dimensional sheet shape I, the bond exchange catalyst is used to activate a dynamic chemical bond in step 2. In step 2, shape the two-dimensional sheet shape I obtained in step 1 into a complex three-dimensional shape II under the conditions of the effect of an external force and the activable dynamic chemical bond. In step 3, pyrolyze the composite precursor at high temperature to obtain transparent glass with complex three-dimensional shape II. The present disclosure provides a method in shaping the transparent glass with complex geometries by unique polymer plasticity in lower temperature.

A holding member is used in a glass manufacturing apparatus that cools down a glass raw material that has been levitated by gas and has been heated and melted, and manufactures glass. The holding member includes a gas injection surface that includes a plurality of injection ports from which the gas is injected. The gas injection surface includes a first region and a second region, the first region including first injection ports that are some injection ports of the plurality of injection ports, the second region including second injection ports that are different from the first injection ports from among the plurality of injection ports. The first region is located inside the second region, when the gas injection surface is viewed from the top. An area of the injection ports per unit area of the first region is smaller than the area of the injection ports per the unit area of the second region. The area of the injection ports per the unit area of the first region is a ratio of the total of cross-sectional areas of the first injection ports to the area of the first region when the gas injection surface is viewed from the top. The area of the injection ports per the unit area of the second region is the ratio of the total of cross-sectional areas of the second injection ports to the area of the second region when the gas injection surface is viewed from the top.

The invention relates in a first aspect to a process for preparing a 3-dimensional body, in particular a vitreous or ceramic body, which comprises at least the following steps: a) providing an electrostatically stabilized suspension of particles; b) effecting a local destabilization of the suspension of particles by means of a localized electrical discharge between a charge injector and the suspension at a predetermined position and causing an aggregation and precipitation of the particles at said position; c) repeating step b) at different positions and causing the formation of larger aggregates until a final aggregate of particles representing a (porous) 3-dimensional body (green body) having predetermined dimensions has been formed; wherein the charge injector includes i) at least one discharge electrode which does not contact said suspension of particles or ii) a source of charged particles. A second aspect of the invention relates to a device, in particular for performing the above process, comprising at least the following components: —a vessel for receiving an electrostatically stabilized suspension of particles, —a charge injector, in particular including one or more electrodes or a source of high-energy charged particles, —means for moving the electrode and/or the vessel in the x, y and z directions, —a counter electrode arranged in the vessel for a contact with the suspension of particles, —one or more sensors for determining geometrical and physical parameters within said vessel. In one preferred embodiment, said device further comprises a means for directing a beam of gas-ionizing radiation, in particular a laser beam, to a predetermined position within the vessel.

Provided is a method of producing a manufactured object including forming the manufactured object by performing, once or a plurality of times, a step of forming a powder layer from material powders containing powders of an inorganic compound and a step of irradiating a predetermined region of a surface of the powder layer with an energy beam and thereby fusing/solidifying the material powders. In the step of fusing/solidifying the material powders, an amorphous-rich region and a crystalline-rich region are formed separately by changing at least one of an output of the energy beam, a relative position between the surface of the powder layer and a focus of the energy beam, and a scanning rate.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a regular geometric arrangement, and a method for producing such a filament, are described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of monofilament and fiber with unique decorative or functional properties.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a regular geometric arrangement, and a method for producing such a filament, are described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of monofilament and fiber with unique decorative or functional properties.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a regular geometric arrangement, and a method for producing such a filament, are described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of monofilament and fiber with unique decorative or functional properties.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a regular geometric arrangement, and a method for producing such a filament, are described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of monofilament and fiber with unique decorative or functional properties.

A first aspect of the present invention relates to a glass substrate having a content of alkali metal oxides, as represented by molar percentage based on oxides, of 0 to 0.1%, a devitrification-temperature viscosity of 10.sup.3.2 dPa.Math.s or higher, and an average coefficient of thermal expansion α at 30 to 220° C. of 7.80 to 9.00 (ppm/° C.). A second aspect of the present invention relates to a glass substrate which is to be used for a support substrate for semiconductor packages, the glass substrate having a content of alkali metal oxides, as represented by molar percentage based on oxides, of 0 to 0.1% and a photoelastic constant of 10 to 26 nm/cm/MPa.

A first aspect of the present invention relates to a glass substrate having a content of alkali metal oxides, as represented by molar percentage based on oxides, of 0 to 0.1%, a devitrification-temperature viscosity of 10.sup.3.2 dPa.Math.s or higher, and an average coefficient of thermal expansion α at 30 to 220° C. of 7.80 to 9.00 (ppm/° C.). A second aspect of the present invention relates to a glass substrate which is to be used for a support substrate for semiconductor packages, the glass substrate having a content of alkali metal oxides, as represented by molar percentage based on oxides, of 0 to 0.1% and a photoelastic constant of 10 to 26 nm/cm/MPa.