Patent classifications
C03C21/00
Glass for chemical strengthening
The present invention relates to a glass for chemical strengthening including, in mole percentage on an oxide basis: 45 to 75% of SiO.sub.2; 1 to 30% of Al.sub.2O.sub.3; 1 to 20% of Li.sub.2O; 0 to 5% of Y.sub.2O.sub.3; 0 to 5% of ZrO.sub.2; and 0 to 1% of TiO.sub.2, having a total content of one or more kinds of MgO, CaO, SrO, BaO and ZnO of 1 to 20%, having a total content of Na.sub.2O and K.sub.2O of 0 to 10%, having a total content of B.sub.2O.sub.3 and P.sub.2O.sub.5 of 0 to 10%, and having a value M expressed by the following expression of 1,000 or more: M=−5×[SiO.sub.2]+121×[Al.sub.2O.sub.3]+50×[Li.sub.2O]−35×[Na.sub.2O]+32×[K.sub.2O]+85×[MgO]+54×[CaO]−41×[Sr O]−4×[P.sub.2O.sub.5]+218×[Y.sub.2O.sub.3]+436×[ZrO.sub.2]−1180, in which each of [SiO.sub.2], [Al.sub.2O.sub.3], [Li.sub.2O], [Na.sub.2O], [K.sub.2O], [MgO], [CaO], [SrO], [P.sub.2O.sub.5], [Y.sub.2O.sub.3], and [ZrO.sub.2] designates a content of each component in mole percentage on an oxide basis.
METHOD OF JOINING GLASS ELEMENTS WITH MATERIAL CONTINUITY, GLASS COMPONENT, AND HOUSING, AND VACUUM INSULATING GLASS PANEL COMPRISING THE GLASS COMPONENT
The present invention relates to a method of joining glass elements with material continuity, to a glass component, to a housing, and to a vacuum insulating panel. The method comprises the following steps providing first and second glass elements, with each of the glass elements having at least one joining region having an outer edge to be joined, introducing a metallic material into the first glass element in the region of the joining region of the first glass element, placing the first and second glass elements onto one another such that the first and second glass elements contact one another at least at one outer edge of the respective joining region; and heating the metallic material in the first glass element so that the glass element at least partially melts in the region of the joining region of the first glass element so that a connection with material continuity is produced between the first and second glass elements.
METHOD OF JOINING GLASS ELEMENTS WITH MATERIAL CONTINUITY, GLASS COMPONENT, AND HOUSING, AND VACUUM INSULATING GLASS PANEL COMPRISING THE GLASS COMPONENT
The present invention relates to a method of joining glass elements with material continuity, to a glass component, to a housing, and to a vacuum insulating panel. The method comprises the following steps providing first and second glass elements, with each of the glass elements having at least one joining region having an outer edge to be joined, introducing a metallic material into the first glass element in the region of the joining region of the first glass element, placing the first and second glass elements onto one another such that the first and second glass elements contact one another at least at one outer edge of the respective joining region; and heating the metallic material in the first glass element so that the glass element at least partially melts in the region of the joining region of the first glass element so that a connection with material continuity is produced between the first and second glass elements.
Methods of ceramming glass articles having improved warp
Glass stack configurations including a carrier plate, setter plates, and glass sheets for thermal treatment of the glass sheets to form glass ceramic articles are provided. The glass stacking configurations and components described herein are selected to improve thermal uniformity throughout a glass stack during ceramming processes while maintaining or even reducing the stresses in the resultant glass ceramic article. Accordingly, the glass ceramic articles made according to the various embodiments described herein exhibit improved optical qualities and less warp than glass ceramic articles made according to conventional processes. Various embodiments of carrier plates, setter plates, parting agent compositions, and methods of stacking glass sheets are described.
Glass tube element with improved quality
A glass tube element is provided that includes hollow cylindrical section that has a shell enclosing a lumen and a path extending on a surface of the shell facing away from the lumen. The path extends across a first area of the shell where the stress values are within a first interval. The path also extends across a second area of the shell where the stress values are within a second interval.
Y.SUB.2.O.SUB.3.-containing glass compositions, substrates, and articles
A glass substrate formed from a glass composition is disclosed. In embodiments, the composition comprises: from 60 mol. % to 75 mol. % SiO.sub.2; from 2 mol. % to 15 mol. % Li.sub.2O; from 1.9 mol. % to 15 mol. % Y.sub.2O.sub.3; and at least one of B.sub.2O.sub.3 and Na.sub.2O. B.sub.2O.sub.3+Na.sub.2O is from 2 mol. % to 13 mol. %. Y.sub.2O.sub.3+Al.sub.2O.sub.3 is from 10 mol. % to 24 mol. %. A ratio R.sub.2O/Al.sub.2O.sub.3 is from 0.5 to 4, where R.sub.2O is a total concentration of Li.sub.2O, Na.sub.2O, K.sub.2O, Rb.sub.2O, and Cs.sub.2O. (R.sub.2O+RO)/Al.sub.2O.sub.3 is from 0.5 to 4.5, where RO is a total concentration of BeO, MgO, CaO, SrO, and BaO. The glass substrate has a Young's modulus from 75 gigapascals (GPa) to 110 GPa. The glass substrate is ion exchangeable to form a strengthened glass article.
Glasses having high fracture toughness
A glass composition includes: 50 mol % to 69 mol % SiO.sub.2; 12.5 mol % to 25 mol % Al.sub.2O.sub.3; 0 mol % to 8 mol % B.sub.2O.sub.3; greater than 0 mol % to 4 mol % CaO; greater than 0 mol % to 17.5 mol % MgO; 0.5 mol % to 8 mol % Na.sub.2O; 0 mol % to 2.5 mol % La.sub.2O.sub.3; and greater than 8 mol % to 18 mol % Li.sub.2O, wherein (Li.sub.2O+Na.sub.2O+MgO)/Al.sub.2O.sub.3 is from 0.9 to less than 1.3; and Al.sub.2O.sub.3+MgO+Li.sub.2O+ZrO.sub.2+La.sub.2O.sub.3+Y.sub.2O.sub.3 is from greater than 23 mol % to less than 50 mol %. The glass composition may be characterized by at least one of the following: a K.sub.1C value measured by a chevron short bar method of at least 0.75; and a K.sub.1C value measured by a double torsion method of at least 0.8. The glass composition is chemically strengthenable. The glass composition may be used in a glass article or a consumer electronic product.
Glass articles exhibiting improved fracture performance
Embodiments of this disclosure pertain to a strengthened glass article including a first surface and a second surface opposing the first surface defining a thickness (t) of about less than about 1.1 mm, a compressive stress layer extending from the first surface to a depth of compression (DOC) of about 0.1.Math.t or greater, such that when the glass article fracture, it breaks into a plurality of fragments having an aspect ratio of about 5 or less. In some embodiments, the glass article exhibits an equibiaxial flexural strength of about 20 kgf or greater, after being abraded with 90-grit SiC particles at a pressure of 25 psi for 5 seconds. Devices incorporating the glass articles described herein and methods for making the same are also disclosed.
Salt Bath Compositions and Methods for Regenerating Salt Bath Compositions
Methods for regenerating a salt bath composition include heating the salt bath composition to an ion exchange temperature to form a molten salt bath. The methods may further include contacting at least a portion of an ion-exchangeable article that includes lithium oxide (Li.sub.2O) with the molten salt bath. Lithium cations may diffuse from the ion-exchangeable article and into the molten salt bath. Additionally, the methods may include adding a first phosphate salt to the molten salt bath. A lithium phosphate salt that includes at least a portion of the lithium cations may be formed and precipitate from the molten salt bath. Furthermore, the methods may include adding a multivalent salt that includes a multivalent metal cation to the molten salt bath. A second phosphate salt that includes the multivalent metal cation may be formed and precipitate from the molten salt bath.
SENSOR MODULE AND PROTECTIVE GLASS
A sensor module includes: a base member; at least one of a single or a plurality of sensors and vibrators arranged on the base member, and a protective member constituted of at least one flat surface or a curved surface, provided so as to cover the at least one of the sensors and the vibrators. A part or whole of the protective member is formed of a strengthened glass and the strengthened glass is a chemically strengthened glass or a physically strengthened glass.