C03C21/00

High strength glass-ceramics having petalite and lithium silicate structures

In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO.sub.2; from about 2 wt. % to about 20 wt. % Al.sub.2O.sub.3; from about 5 wt. % to about 20 wt. % Li.sub.2O; greater than 0 wt % to about 3 wt. % Na.sub.2O; a non-zero amount of P.sub.2O.sub.5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO.sub.2. In embodiments, ZrO.sub.2 (wt. %)+P.sub.2O.sub.5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.

Glass-based articles with improved stress profiles

Glass-based articles are provided with improved stress profiles. The glass-based articles provide improved drop performance and damage resistance. The glass-based articles may be produced with a single ion exchange treatment.

Scratch resistant glass and method of making

Glass-based articles comprise stress profiles providing improved scratch resistance. A glass-based article comprises a lithium aluminosilicate composition and a molar ratio of potassium oxide (K.sub.2O) to sodium oxide (Na.sub.2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8. The article comprises sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article and a spike depth of layer that is greater than or equal to 4 micrometers and less than or equal to 8 micrometers. The article may comprise an average compressive stress of greater than or equal to 150 MPa over a depth from 15 micrometers to 40 micrometers.

Chemically strengthened lithium disilicate-petalite glass-ceramics

Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07t to a depth of about 0.26t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18t to about 0.25t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa√m or more as measured according to the double cantilever beam method.

Colored glass articles having improved mechanical durability

A colored glass article may include 50-80 mol % SiO.sub.2; 7-20 mol % Al.sub.2O.sub.3; 1-35 mol % R.sub.2O, wherein R.sub.2O comprises at least one of Li.sub.2O, Na.sub.2O, and K.sub.2O; 1×10.sup.−6-10 mol % of a colorant, wherein the colorant comprises at least one of Cr.sub.2O.sub.3, Au, Ag, CuO, NiO, Co.sub.3O.sub.4, TiO.sub.2, CeO.sub.2; and 12-24 mol % of Al.sub.2O.sub.3+MgO+CaO+ZnO. The colored glass article may have a transmittance color coordinate in the CIELAB color space with an L* value of 55 to 96.5. The colored glass article may have a compressive stress profile with a depth of compression ≥0.15t, a thickness t from 0.4 mm-5 mm, a compressive stress ≥200 MPa, and a central tension ≥60 MPa. The colored glass article may have a dielectric constant from 5.6 to 6.4 over the frequency range from 10 GHz to 60 GHz.

GLASS FOR CHEMICAL STRENGTHENING
20230119617 · 2023-04-20 · ·

The present invention relates to a glass for chemical strengthening including, in mole percentage on an oxide basis: 60 to 72% of SiO.sub.2; 9 to 20% of Al.sub.2O.sub.3; 1 to 15% of Li.sub.2O; 0.1 to 5% of Y.sub.2O.sub.3; 0 to 1.5% of ZrO.sub.2; and 0 to 1% of TiO.sub.2, having a total content of one or more kinds of MgO, CaO, SrO, BaO and ZnO of 1 to 10%, having a total content of Na.sub.2O and K.sub.2O of 1.5 to 10%, having a total content of B.sub.2O.sub.3 and P.sub.2O.sub.5 of 0 to 10%, wherein a ratio ([Al.sub.2O.sub.3]+[Li.sub.2O])/([Na.sub.2O]+[K.sub.2O]+[MgO]+[CaO]+[SrO]+[BaO]+[ZnO]+[ZrO.sub.2]+[Y.sub.2O.sub.3]) is from 0.7 to 3, wherein a ratio [MgO])/([CaO]+[SrO]+[BaO]+[ZnO]) is from 10 to 45, and having a value M expressed by the following expression of 1,100 or more:


M=−5×[SiO.sub.2]+121×[Al.sub.2O.sub.3]+50×[Li.sub.2O]−35×[Na.sub.2O]+32×[K.sub.2O]+85×[MgO]+54×[CaO]−41×[SrO]−4×[P.sub.2O.sub.5]+218×[Y.sub.2O.sub.3]+436×[ZrO.sub.2]−1180, wherein each of [SiO.sub.2], [Al.sub.2O.sub.3], [Li.sub.2O], [Na.sub.2O], [K.sub.2O], [MgO], [CaO], [SrO], [P.sub.2O.sub.5], [Y.sub.2O.sub.3], and [ZrO.sub.2] designates a content of each component in mole percentage on an oxide basis.

TEXTURED GLASS COMPONENT FOR AN ELECTRONIC DEVICE ENCLOSURE
20230124179 · 2023-04-20 ·

The disclosure provides textured glass components as well as electronic device cover assemblies and enclosures which include the textured glass components. In some cases, a protruding portion of the glass component includes a textured region provided over a camera assembly of the electronic device. One or more openings may be provided in the textured region. The textured region may be configured to provide a translucent or hazy appearance to the electronic device while providing a desirable “feel” to the electronic device and level of cleanability.

CHEMICALLY STRENGTHENABLE MACHINABLE GLASS-CERAMICS

A glass-ceramic comprising, in weight percent on an oxide basis, of 50 to 70% SiO.sub.2, 0 to 20% Al.sub.2O.sub.3, 12 to 23% MgO, 0 to 4% Li.sub.2O, 0 to 10% Na.sub.2O, 0 to 10% K.sub.2O, 0 to 5% ZrO.sub.2, and 2 to 12% F, wherein the predominant crystalline phase of said glass-ceramic is a trisilicic mica, a tetrasilicic mica, or a mica solid solution between trisilicic and tetrasilicic, and wherein the total of Na.sub.2O+Li.sub.2O is at least 2 wt. %; wherein the glass-ceramic can be ion-exchanged.

GLASS COMPOSITIONS AND METHODS WITH STEAM TREATMENT HAZE RESISTANCE
20230069661 · 2023-03-02 ·

Glass-based articles that include a compressive stress layer extending from a surface of the glass-based article to a depth of compression are formed by exposing glass-based substrates to water vapor containing environments. The glass-based substrates have compositions selected to avoid the formation of haze during the treatment process. The methods of forming the glass-based articles may include elevated pressures and/or multiple exposures to water vapor containing environments selected to avoid the formation of haze during the treatment process.

GLASS STRUCTURE AND COVER GLASS
20230122091 · 2023-04-20 · ·

A glass structure includes: a glass substrate that includes a thick portion and a thin portion thinner than the thick portion; and a filler that covers a step surface formed by difference in height between the thick portion and the thin portion. A refractive index difference at a wavelength of 555 nm between the glass substrate and the filler is 0.008 or less in an absolute value. A refractive index difference at a wavelength of 507 nm between the glass substrate and the filler is 0.008 or less in an absolute value.