The invention is directed to kits, compositions, tools and methods comprising a cyclic industrial process to form biocement. In particular, the invention is directed to materials and methods for decomposing calcium carbonate into calcium oxide and carbon dioxide at an elevated temperature, reacting calcium oxide with ammonium chloride to form calcium chloride, water, and ammonia gas; and reacting ammonia gas and carbon dioxide at high pressure to form urea and water, which are then utilized to form biocement. This cyclic process can be achieved by combining industrial processes with the resulting product as biocement. The process may involve retention of calcium carbonate currently utilized in the manufacture of Portland Cement.

A method for producing a carbonate-containing species-rich, nitrogen-containing species-free solution from a urea-rich solution is proposed. The method comprising the steps of: providing a first reservoir comprising a first mixture including urea and a catalyser comprising an enzymatic catalyser and/or a microorganism; allowing an enzymatic reaction catalysed by the catalyser to decompose urea, thereby obtaining a second mixture comprising nitrogen-containing species and carbonate-containing species; converting at least some of the nitrogen-containing species into gaseous nitrogen-containing species to obtain a third mixture comprising the gaseous nitrogen-containing species and the carbonate-containing species; filtering the third mixture by a gas- permeable filter, thereby separating at least some of the gaseous nitrogen-containing species from the carbonate-containing species while keeping the catalyser away from the gas-permeable filter; and collecting the so-obtained carbonate-containing species-rich, nitrogen-containing species-free solution.

Disclosed herein are a lightweight geopolymer foam with low thermal conductivity and a manufacturing method therefor in which coal bottom ash and fly ash are used together as materials for the geopolymer foam and silica fume is added to a mixed solution of an alkali activator and sodium hydroxide. The geopolymer foam can be utilized for improving insulation performance and safety for a structure constructed with eco-friendly cement.

A high-strength geopolymer hollow microsphere, a preparation method thereof and a phase change energy storage microsphere are provided, including: dissolving sodium hydroxide, sodium silicate and spheroidizing aid in water to form a solution A, and adding active powder to the solution A, stirring and uniformly mixing to form a slurry B, adding the slurry B to an oil phase, stirring and dispersing into balls, filtering to obtain geopolymer microspheres I, washing the geopolymer microspheres I, and then carrying out a high-temperature calcination to obtain the high-strength geopolymer hollow microspheres II; using the high-strength geopolymer hollow microsphere as a carrier, absorbing a phase change material into the carrier, and mixing a microsphere carrying the phase change material with an epoxy resin, adding a powder dispersant and stirring to disperse the microsphere, after the epoxy resin is solidified, screening the superfluous powder dispersant to obtain the phase energy storage microsphere.

Disclosed is a CO.sub.2 solidified fiber cement board and its preparation method. The matrix composition of the fiber cement board prepared in this disclosure is calcium carbonate, which has high compactness, and the crystal form of calcium carbonate is adjusted by adding shell powder to improve the toughness of the matrix, so that the fiber cement board has excellent mechanics and durability performance. In addition, the preparation process does not require high temperature maintenance, and has the characteristics of normal temperature preparation, which creates conditions for the introduction of organic synthetic fibers, so that the organic synthetic fibers can further improve the brittleness of cement fiberboard. While reducing energy consumption, the preparation process can also effectively solve the problem that excessive pressure is easily generated in the fiberboard under high temperature conditions in the existing high-temperature and high-pressure curing process.

A geopolymer composite binder is provided herein, the composite binder including (i) at least one fly ash material having less than or equal to 15 wt % of calcium oxide; (ii) at least one gelation enhancer; and (iii) at least one hardening enhancer having a different composition from a composition of the at least one fly ash material.

The invention provides novel apparatus and processes for gas flow and conditioning to achieve optimal CO.sub.2 curing of articles of composite materials (e.g., precast objects made of carbonatable calcium silicate-based cements), with solid interior or having hollow interior ducts, channels and chambers or otherwise being hollowed out, as well as the precast objects so made, which are suitable for a variety of applications in construction, pavements and landscaping, and infrastructure.

The present invention relates to artificially reducing the porosity of any potential flow paths in the near-wellbore region of a well or in permeable zones within or surrounding a well. In doing so, the permeability in this the targeted region will be significantly reduced, thus, preventing unwanted flow of subsurface fluids. The present invention concerns a method comprising applying a first and second solution comprising scale precursors to the porous media, wherein following this application, at least a portion of the scale precursors form at least two insoluble salts. Additionally, the present invention concerns a kit of parts comprising the first and second solutions.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 μm. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 μm. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.