A method of manufacturing a composition with hierarchical nanochemical bonding includes making a powder of one or more oxygen containing materials; mixing the powder either with a water solution of organic and/or inorganic acid to form an acidic slurry, or with water to form a hydrated basic slurry; and curing the slurry to form a solid. The powder comprises nanoscale particles, or microscale particles, or a mixture of nanoscale particles and microscale particles.

This invention relates to an adaptable Geopolymer cement composition for application in oil and gas wells having a wide range of downhole temperatures. The base Geopolymer cement composition has an acceptable rheology of below 200 cP and can be tailored by the inclusion of various chemicals to control properties such as thickening time over a wide range of temperatures and densities. The disclosed Geopolymer cement composition is pumpable, mixable and stable. The composition can also be adapted to have expandable and swellable properties.

A geopolymer material made from principal minerals, which comprises SiO.sub.2, Al.sub.2O.sub.3, Fe.sub.2O.sub.3, TiO.sub.2, and optionally trace amounts of calcium. Also disclosed are cementitious material comprised of the geopolymer and concrete made from mixing the geopolymer cementitious material with an alkaline solution. Methods of making the geopolymer composite as well as methods of making the geopolymer concrete are also disclosed.

A smart roof system and method comprising cementitious sheathing sheets for a roof cover that can be installed directly onto the wood roof sheathing of a structure or home. Said cementitious sheathing sheets are laid over wood roof sheathing directly with permanent adhesive. An aluminum expansion joint is installed to serve as an expansion joint between said cementitious sheathing sheets and to provide support for solar panels. Aluminum expansion joints have a lower lip and an upper lip, a lower lip of the aluminum expansion joints serves to support cementitious sheathing sheets over the lower lip with adhesive and create a joint directly over the wood roof sheathing. The cementitious sheathing sheets are laid on the wood roof sheathing with an adhesive designed to adhere in a permanent manner to the cementitious sheathing sheets. A next cementitious sheet is then installed into the lower lip of the aluminum expansion joints and overlap on top of the previous cementitious sheet, bonding by the permanent adhesive. The procedure is repeated forming the roof from lower elevation to higher roof elevation, thereby water will flow over the overlapping sections of cementitious sheathing sheets.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

The invention comprises a cementitious material comprising a natural pozzolan selected from hyaloclastite, sideromelane or tachylite, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to 40 m. The cementitious material also comprising an aqueous alkaline activating solution suitable for forming a geopolymer. A method making a cementitious material is also disclosed.

An uncalcined geopolymer-based refractory material is provided, comprising a matrix of a geopolymer obtainable by polymerization of a mixture consisting of mineral powder, fly ash, and metakaolin; and SiC whiskers embedded in the geopolymer matrix. The material has excellent mechanical properties and high resistance to high temperatures and exhibits a ductile fracture mechanism instead of a brittle fracture mechanism.

The invention is directed to compositions and methods for the manufacture of pigmented solids structures for which can be used for construction and/or decoration. Manufacturing comprises fixing one or more pigments to an aggregate material such as crushed rock, stone or sand. The pigmented aggregate is incubated with urease or urease producing microorganisms, an amount of a nitrogen source such as urea, and an amount of calcium source such as calcium chloride forming calcite bridges between particles of aggregate. The resulting solid has a hardness and colorfastness for most any construction material. Using selected aggregate and pigment, the process also provides for the manufacture of simulated-stone materials such as clay or granite bricks or blocks, marble counter-tops, and more. The invention is also directed to composition containing microorganisms and pigment as kits that can be added to most any aggregate materials.

The invention is directed to compositions and methods for the manufacture of pigmented solids structures for which can be used for construction and/or decoration. Manufacturing comprises fixing one or more pigments to an aggregate material such as crushed rock, stone or sand. The pigmented aggregate is incubated with urease or urease producing microorganisms, an amount of a nitrogen source such as urea, and an amount of calcium source such as calcium chloride forming calcite bridges between particles of aggregate. The resulting solid has a hardness and colorfastness for most any construction material. Using selected aggregate and pigment, the process also provides for the manufacture of simulated-stone materials such as clay or granite bricks or blocks, marble counter-tops, and more. The invention is also directed to composition containing microorganisms and pigment as kits that can be added to most any aggregate materials.

The purpose of the present invention is to provide a preceding material for pumping, a feeding of a very small amount thereof being capable of extending the pumping distance. The preceding material for pumping includes an added cellulose nanofiber and having calcium carbonate as a main component. The present invention enables a thin lubricant layer of a uniform thickness to be formed inside a pipe even when the pipe has a slightly roughened inner surface due to, for example, residues of solidified cement paste or the like, allowing the pumping distance to be extended. Thus, the present invention is suitable, for example, for casting ready-mixed concrete at various construction sites.