Patent classifications
C04B24/00
LIMESTONE CALCINED CLAY CEMENT (LC3) CONSTRUCTION COMPOSITION
A limestone calcined clay cement construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm.sup.2/g, in an amount of 180 to 400 kg per m.sup.3 of the freshly mixed construction composition; b) a supplementary cementitious material having a Dv90 of less than 200 μm, in a total amount of 50 to 100 parts by weight, relative to 100 parts by weight of cementitious binder a), the supplementary cementitious material comprising (b-1) a calcined clay material and (b-2) a carbonate rock powder in a weight ratio of (b-1) to (b-2) in the range of 0.5 to 2; c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH).sub.4.sup.−, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m.sup.3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m.sup.3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m.sup.3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g.Math.L.sup.−1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The limestone calcined clay cement construction composition is a reduced carbon footprint composition and exhibits high early strength, high final strength, sufficient open time and high durability. Ingredients of the construction composition are abundantly available.
LIMESTONE CALCINED CLAY CEMENT (LC3) CONSTRUCTION COMPOSITION
A limestone calcined clay cement construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm.sup.2/g, in an amount of 180 to 400 kg per m.sup.3 of the freshly mixed construction composition; b) a supplementary cementitious material having a Dv90 of less than 200 μm, in a total amount of 50 to 100 parts by weight, relative to 100 parts by weight of cementitious binder a), the supplementary cementitious material comprising (b-1) a calcined clay material and (b-2) a carbonate rock powder in a weight ratio of (b-1) to (b-2) in the range of 0.5 to 2; c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH).sub.4.sup.−, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m.sup.3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m.sup.3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m.sup.3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g.Math.L.sup.−1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The limestone calcined clay cement construction composition is a reduced carbon footprint composition and exhibits high early strength, high final strength, sufficient open time and high durability. Ingredients of the construction composition are abundantly available.
COMPOSITE ARTICLE COMPRISING AEROGEL PARTICLES AND CERAMIC FIBER SHEETS
A method for the preparation of a composite article containing aerogel particles and ceramic fibers, as well as to a composite article obtained by this method, are described.
COMPOSITE ARTICLE COMPRISING AEROGEL PARTICLES AND CERAMIC FIBER SHEETS
A method for the preparation of a composite article containing aerogel particles and ceramic fibers, as well as to a composite article obtained by this method, are described.
COMPOSITE ARTICLE COMPRISING AEROGEL PARTICLES, CERAMIC AND/OR GLASS FIBERS AND OPACIFIERS
A method for the preparation of a composite article containing aerogel particles, graphite and ceramic and/or glass fibers, as well as to a composite article obtained by this method, are described.
COMPOSITE ARTICLE COMPRISING AEROGEL PARTICLES, CERAMIC AND/OR GLASS FIBERS AND OPACIFIERS
A method for the preparation of a composite article containing aerogel particles, graphite and ceramic and/or glass fibers, as well as to a composite article obtained by this method, are described.
Microorganism loaded aggregate and manufacturing methods
The invention is directed to compositions, tools and methods for the manufacture of construction materials, masonry, solid structures and compositions to facilitate dust control. More particularly, the invention is directed to the manufacture of bricks, masonry and other solid structures using small amount of aggregate material that is pre-loaded with spores and/or vegetative bacterial cells.
Microorganism loaded aggregate and manufacturing methods
The invention is directed to compositions, tools and methods for the manufacture of construction materials, masonry, solid structures and compositions to facilitate dust control. More particularly, the invention is directed to the manufacture of bricks, masonry and other solid structures using small amount of aggregate material that is pre-loaded with spores and/or vegetative bacterial cells.
CARBON DIOXIDE-CAPTURING CEMENT COMPOSITIONS AND RELATED METHODS
Cement compositions that can capture carbon dioxide and related methods are generally described.
CARBON DIOXIDE-CAPTURING CEMENT COMPOSITOINS AND RELATED METHODS
Cement compositions that can capture carbon dioxide and related methods are generally described.