Patent classifications
C05B11/00
METHOD, PRODUCT AND SYSTEM FOR COGENERATING FERRIC PHOSPHATE THROUGH NITROPHOSPHATE FERTILIZER DEVICE
The present disclosure discloses a method, product, and system for cogenerating ferric phosphate through a nitrophosphate fertilizer device. The method comprises the steps of: acid-hydrolyzing phosphate rock with a nitric acid, and separating acid-insoluble substances to obtain an acid-hydrolyzed solution; freezing-crystallizing the acid-hydrolyzed solution, and carrying out solid-liquid separation to obtain a first solution; adding a solution containing sulfate ions to the first solution for reaction to obtain a second solution; subjecting the second solution to a denitrification to obtain a third solution; adding ammonia to the third solution for neutralization, and carrying out solid-liquid separation to obtain an ammonium phosphate solution, and adding an iron source to the ammonium phosphate solution for reaction to prepare a ferric phosphate. The present disclosure utilizes phosphate rock raw material to prepare a high-purity ferric phosphate, and by-product can be directly used for fertilizer preparation or as independent product, without waste.
Preparation of an aqueous suspension of phosphate material
The invention relates to a method for preparing an aqueous suspension of at least one phosphate material, comprising, dispersing, in water, particles of phosphate material in the presence of at least one additive of the anionic polymer of acrylic acid or of methacrylic acid type. The suspension according to the invention has a viscosity of less than 1500 mPa.Math.s. The invention also relates to the conditioning of the phosphate material associated with the anionic polymer, for its subsequent treatment with at least one strong acid, for the industrial preparation of phosphoric acid.
Preparation of an aqueous suspension of phosphate material
The invention relates to a method for preparing an aqueous suspension of at least one phosphate material, comprising, dispersing, in water, particles of phosphate material in the presence of at least one additive of the anionic polymer of acrylic acid or of methacrylic acid type. The suspension according to the invention has a viscosity of less than 1500 mPa.Math.s. The invention also relates to the conditioning of the phosphate material associated with the anionic polymer, for its subsequent treatment with at least one strong acid, for the industrial preparation of phosphoric acid.
Decomposition of struvite
A method for decomposing struvite comprises dissolving of a feed material comprising struvite in a mineral acid. Thereby a solution having an acid pH is formed. Magnesium is removed from the solution. The removing of magnesium comprises increasing a pH of the solution to a pH in the range of 4.5 to 6, precipitating magnesium compounds that do not comprise ammonium, and separating the precipitated magnesium compounds from the solution. Thereby, the solution, after the removing of magnesium, comprises an ammonium salt of the mineral acid. An arrangement for performing such a method is also disclosed. Also, a method and arrangement for recovering at least nitrogen from waste material, based on the decomposing of struvite are disclosed.
Decomposition of struvite
A method for decomposing struvite comprises dissolving of a feed material comprising struvite in a mineral acid. Thereby a solution having an acid pH is formed. Magnesium is removed from the solution. The removing of magnesium comprises increasing a pH of the solution to a pH in the range of 4.5 to 6, precipitating magnesium compounds that do not comprise ammonium, and separating the precipitated magnesium compounds from the solution. Thereby, the solution, after the removing of magnesium, comprises an ammonium salt of the mineral acid. An arrangement for performing such a method is also disclosed. Also, a method and arrangement for recovering at least nitrogen from waste material, based on the decomposing of struvite are disclosed.
Method to make phosphoric acid and ammonium phosphates from phosphate minerals
A method of producing ammonium phosphates from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.
Method to make phosphoric acid and ammonium phosphates from phosphate minerals
A method of producing ammonium phosphates from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.
METHOD TO MAKE PHOSPHORIC ACID AND AMMONIUM PHOSPHATES FROM PHOSPHATE MINERAL
A method of producing ammonium phosphates from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.
METHOD TO MAKE PHOSPHORIC ACID AND AMMONIUM PHOSPHATES FROM PHOSPHATE MINERAL
A method of producing ammonium phosphates from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.