The purpose of the present invention is to provide a treatment method by which, even for wastewater with organic constituents constituting a large portion of organic wastewater as a whole and suspended solids (SS) and with a large negative charge ratio, organic nitrogen constituents and phosphorus compounds can be efficiently separated and collected and good-quality separated water can be obtained by reducing the quantity of SS, BOD, COD, and nitrogen constituents in the separated water. Provided is a treatment method for organic waste water, in which a flock is formed by adding a polymer flocculant to organic waste water with organic nitrogen constituent content in relation to suspended solids (SS) being 4-50%/SS and organic nitrogen constituent content being 250-50,000 mg/L, and thereafter, the flock is separated from the organic wastewater by solid-liquid separation.

The purpose of the present invention is to provide a treatment method by which, even for wastewater with organic constituents constituting a large portion of organic wastewater as a whole and suspended solids (SS) and with a large negative charge ratio, organic nitrogen constituents and phosphorus compounds can be efficiently separated and collected and good-quality separated water can be obtained by reducing the quantity of SS, BOD, COD, and nitrogen constituents in the separated water. Provided is a treatment method for organic waste water, in which a flock is formed by adding a polymer flocculant to organic waste water with organic nitrogen constituent content in relation to suspended solids (SS) being 4-50%/SS and organic nitrogen constituent content being 250-50,000 mg/L, and thereafter, the flock is separated from the organic wastewater by solid-liquid separation.

A urea phosphate calcium sulfate (UPCS) fertilizer granule and methods for making and using the same are disclosed. The granule can include urea phosphate and a urea-calcium sulfate (UCS) adduct. The granule can include 22 wt. % to 28 wt. % nitrogen (22 wt. % to 28 wt. % N), an amount of phosphorus equal to that provided by 5 wt. % to 10 wt. % P2O5 (5 wt. % to 10 wt. % P), 2 wt. % to 8 wt. % sulfur (2 wt. % to 8 wt. % S), and 5 wt. % to 11 wt. % calcium (5 wt. % to 11 wt. % Ca).

A urea phosphate calcium sulfate (UPCS) fertilizer granule and methods for making and using the same are disclosed. The granule can include urea phosphate and a urea-calcium sulfate (UCS) adduct. The granule can include 22 wt. % to 28 wt. % nitrogen (22 wt. % to 28 wt. % N), an amount of phosphorus equal to that provided by 5 wt. % to 10 wt. % P2O5 (5 wt. % to 10 wt. % P), 2 wt. % to 8 wt. % sulfur (2 wt. % to 8 wt. % S), and 5 wt. % to 11 wt. % calcium (5 wt. % to 11 wt. % Ca).

Methods are disclosed for the manufacture of nitrogenous phosphoryl compounds as fluid compositions utilizing a reaction medium comprising one or more aprotic organic liquids that are not reactive with one or more phosphoryl chlorides functional groups and optionally one or more non-aqueous organic liquids as processing aides that result in fluid products for delivering the resulting nitrogenous phosphoryl compounds to the surface of a substrate. Methods are disclosed that eliminate the need for one or more of the following: 1) purifying of one or more nitrogenous phosphoryl compounds, 2) stripping of volatile organic solvents, 3) removal of inorganic by-products, 4) generating solid nitrogenous phosphoryl compounds, 5) packaging one or more solid nitrogenous compounds, and 6) dissolving the solid nitrogenous phosphoryl compounds into a liquid delivery system for application to the surface of a substrate. Methods are disclosed that lower the overall manufacturing cost, wherein said fluid nitrogenous phosphoryl compositions comprise liquid solutions, fluid colloids, and fluid suspensions. Fluidized nitrogenous phosphoryl compounds are applied onto fertilizer solid surfaces using simple blending equipment that commingle the composition with solid granules allowing farmers and small co-ops access to high tech, state of the art fertilizers at lower cost.

Methods are disclosed for the manufacture of nitrogenous phosphoryl compounds as fluid compositions utilizing a reaction medium comprising one or more aprotic organic liquids that are not reactive with one or more phosphoryl chlorides functional groups and optionally one or more non-aqueous organic liquids as processing aides that result in fluid products for delivering the resulting nitrogenous phosphoryl compounds to the surface of a substrate. Methods are disclosed that eliminate the need for one or more of the following: 1) purifying of one or more nitrogenous phosphoryl compounds, 2) stripping of volatile organic solvents, 3) removal of inorganic by-products, 4) generating solid nitrogenous phosphoryl compounds, 5) packaging one or more solid nitrogenous compounds, and 6) dissolving the solid nitrogenous phosphoryl compounds into a liquid delivery system for application to the surface of a substrate. Methods are disclosed that lower the overall manufacturing cost, wherein said fluid nitrogenous phosphoryl compositions comprise liquid solutions, fluid colloids, and fluid suspensions. Fluidized nitrogenous phosphoryl compounds are applied onto fertilizer solid surfaces using simple blending equipment that commingle the composition with solid granules allowing farmers and small co-ops access to high tech, state of the art fertilizers at lower cost.

The present application relates to a combined NPK-Si fertilizer product comprising a mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen, phosphorous or potassium, and a particulate amorphous silicon dioxide, wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide is from 10:90 to 90:10, based on the dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium, and the amorphous silicon dioxide contained in the product. The application also relates to the method of production of the inventive NPK-Si fertilizer.

The present application relates to a combined NPK-Si fertilizer product comprising a mineral NPK fertilizer, which comprises at least one nutrient compound of nitrogen, phosphorous or potassium, and a particulate amorphous silicon dioxide, wherein the ratio of the mineral NPK fertilizer to the amorphous silicon dioxide is from 10:90 to 90:10, based on the dry weight of the at least one nutrient compound of nitrogen, phosphorous or potassium, and the amorphous silicon dioxide contained in the product. The application also relates to the method of production of the inventive NPK-Si fertilizer.

A metal-organic framework material fertilizer and a preparation method therefor is provided. The novel fertilizer consists of nutrient molecules and external frameworks thereof, and is characterized in that the external frameworks are formed by coordination of inorganic metal ion clusters to organic joints under hydrothermal conditions. The metal-organic framework materials include two types, i.e., zinc-free and zinc-containing. The hydrothermal synthesis conditions of the novel metal-organic framework material fertilizer are that: the reaction temperature is 100° C., the reaction time is 24 h, the heating rate of the reactor is 2° C./min, and the speed of the stir bar is 120 revolutions per minute. The nutrient contents of the novel fertilizer are as follows: compound I: N: 4-5%, and P: 16-20%; and compound II: N: 5-7%, P: 15-18%, and Zn: 2-3%.

A metal-organic framework material fertilizer and a preparation method therefor is provided. The novel fertilizer consists of nutrient molecules and external frameworks thereof, and is characterized in that the external frameworks are formed by coordination of inorganic metal ion clusters to organic joints under hydrothermal conditions. The metal-organic framework materials include two types, i.e., zinc-free and zinc-containing. The hydrothermal synthesis conditions of the novel metal-organic framework material fertilizer are that: the reaction temperature is 100° C., the reaction time is 24 h, the heating rate of the reactor is 2° C./min, and the speed of the stir bar is 120 revolutions per minute. The nutrient contents of the novel fertilizer are as follows: compound I: N: 4-5%, and P: 16-20%; and compound II: N: 5-7%, P: 15-18%, and Zn: 2-3%.