Methods and system for increasing the water solubility and availability of zinc in granular fertilizers using acid treatments. The treatment of granular fertilizers with an acidic solution increases an amount of water-soluble zinc, which in turn, increases the efficiency of zinc uptake and reduces the costs and equipment otherwise needed to mitigate zinc deficiencies.

Methods and system for increasing the water solubility and availability of zinc in granular fertilizers using acid treatments. The treatment of granular fertilizers with an acidic solution increases an amount of water-soluble zinc, which in turn, increases the efficiency of zinc uptake and reduces the costs and equipment otherwise needed to mitigate zinc deficiencies.

A method for preparing urea ammonium nitrate solution from waste nitric acid after stripping tin from circuit board includes: causing the waste nitric acid after stripping tin and the ammonia water to undergo neutralizing and precipitating reaction through acid-base neutralization, filtering, thereby obtaining tin-containing filter mud and a primary filtrate; adding iron powders into to the primary filtrate to initiate copper-iron replacement reaction, filtering, thereby obtaining iron-containing coarse copper powders and a secondary filtrate; adding hydrogen peroxide to the secondary filtrate, filtering, thereby obtaining an iron-containing sludge and a tertiary filtrate; adding a heavy metal capturing agent to the tertiary filtrate, filtering, thereby obtaining a heavy metal sludge and an ammonium nitrate solution; measuring a concentration of the ammonium nitrate solution, adding urea and liquid fertilizer corrosion inhibitor to obtain a urea/ammonium nitrate dilute solution, evaporating and concentrating the urea/ammonium nitrate dilute solution, thereby obtaining the urea ammonium nitrate solution.

A method for preparing urea ammonium nitrate solution from waste nitric acid after stripping tin from circuit board includes: causing the waste nitric acid after stripping tin and the ammonia water to undergo neutralizing and precipitating reaction through acid-base neutralization, filtering, thereby obtaining tin-containing filter mud and a primary filtrate; adding iron powders into to the primary filtrate to initiate copper-iron replacement reaction, filtering, thereby obtaining iron-containing coarse copper powders and a secondary filtrate; adding hydrogen peroxide to the secondary filtrate, filtering, thereby obtaining an iron-containing sludge and a tertiary filtrate; adding a heavy metal capturing agent to the tertiary filtrate, filtering, thereby obtaining a heavy metal sludge and an ammonium nitrate solution; measuring a concentration of the ammonium nitrate solution, adding urea and liquid fertilizer corrosion inhibitor to obtain a urea/ammonium nitrate dilute solution, evaporating and concentrating the urea/ammonium nitrate dilute solution, thereby obtaining the urea ammonium nitrate solution.

A method for preparing urea ammonium nitrate solution from waste nitric acid after stripping tin from circuit board includes: causing the waste nitric acid after stripping tin and the ammonia water to undergo neutralizing and precipitating reaction through acid-base neutralization, filtering, thereby obtaining tin-containing filter mud and a primary filtrate; adding iron powders into to the primary filtrate to initiate copper-iron replacement reaction, filtering, thereby obtaining iron-containing coarse copper powders and a secondary filtrate; adding hydrogen peroxide to the secondary filtrate, filtering, thereby obtaining an iron-containing sludge and a tertiary filtrate; adding a heavy metal capturing agent to the tertiary filtrate, filtering, thereby obtaining a heavy metal sludge and an ammonium nitrate solution; measuring a concentration of the ammonium nitrate solution, adding urea and liquid fertilizer corrosion inhibitor to obtain a urea/ammonium nitrate dilute solution, evaporating and concentrating the urea/ammonium nitrate dilute solution, thereby obtaining the urea ammonium nitrate solution.

A method of producing fertilizer compositions while producing biogas is disclosed. The method comprises converting an organic material such as organic wastes into fertilizer compositions and biogas. The conversion of the organic material is performed in a fermentation process. In some embodiments, the method comprises preparing a fermenting mixture comprising a starting organic material, a starting bio-stimulant product comprising a plurality of microorganisms, and a starting nitrogen source, and fermenting the fermenting mixture in a fermentation environment for a first time interval to form a fermented mixture comprising the fertilizer composition.

A method of producing fertilizer compositions while producing biogas is disclosed. The method comprises converting an organic material such as organic wastes into fertilizer compositions and biogas. The conversion of the organic material is performed in a fermentation process. In some embodiments, the method comprises preparing a fermenting mixture comprising a starting organic material, a starting bio-stimulant product comprising a plurality of microorganisms, and a starting nitrogen source, and fermenting the fermenting mixture in a fermentation environment for a first time interval to form a fermented mixture comprising the fertilizer composition.

A system and method for providing fertilizer for crop production in an aqueous solution comprising nano-sized fertilizer particles, which are free of any chemical side chain and free any micelle to protect the nano-sized particle from re-agglomeration, suspended therein for improved uptake by the population of the crop.

A system and method for providing fertilizer for crop production in an aqueous solution comprising nano-sized fertilizer particles, which are free of any chemical side chain and free any micelle to protect the nano-sized particle from re-agglomeration, suspended therein for improved uptake by the population of the crop.

Disclosed are compositions and methods of making a liquid fertilizer additive of biodegradable polymeric and/or oligomeric nitrification inhibitors comprised of utilizing a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with cyano-containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary amines, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols.