Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols. Fertilizer compositions are disclosed comprising of a) one or more polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors adducts from the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols b) a non-aqueous organo solvent delivery system (NOSDS), and c) one or more nitrogen sources.

Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols. Fertilizer compositions are disclosed comprising of a) one or more polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors adducts from the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols b) a non-aqueous organo solvent delivery system (NOSDS), and c) one or more nitrogen sources.

A stabilized ammonium humate mixture including an amount of humic acid between about 7.0% to about 10% of the mixture and an amount of ammonia between about 1.0% to about 14% of the mixture, where the remainder of the mixture is water.

A process for preparing humic-mineral agent granules is disclosed. Such a process may comprise providing a humic acid-containing material; crushing the humic acid-containing material to obtain first granules; contacting a quantity of water with the first granules, thereby forming slightly wet granules; blending the slightly wet granules for a period of time, thereby forming blended granules; contacting an amount of alkali with the blended granules, thereby forming alkali-treated granules; and mixing the alkali-treated granules at a temperature high enough to melt organic carbon substances in the alkali-treated granules. The resulting product has biologically, geologically, and chemically active properties, and may be applied to the soil alone or in combination with a commercially available fertilizer. Additionally, the resulting product may be used to detoxify solid or liquid waste products.

A process for preparing humic-mineral agent granules is disclosed. Such a process may comprise providing a humic acid-containing material; crushing the humic acid-containing material to obtain first granules; contacting a quantity of water with the first granules, thereby forming slightly wet granules; blending the slightly wet granules for a period of time, thereby forming blended granules; contacting an amount of alkali with the blended granules, thereby forming alkali-treated granules; and mixing the alkali-treated granules at a temperature high enough to melt organic carbon substances in the alkali-treated granules. The resulting product has biologically, geologically, and chemically active properties, and may be applied to the soil alone or in combination with a commercially available fertilizer. Additionally, the resulting product may be used to detoxify solid or liquid waste products.

A fertilizer granule containing a core containing, phosphoric acid and an urea adduct containing urea and calcium sulfate, and a coat containing an urease inhibitor and a base, the coat forming a coating on an outer surface of the core. Methods of making and using the fertilizer granule are also disclosed.

A fertilizer granule containing a core containing, phosphoric acid and an urea adduct containing urea and calcium sulfate, and a coat containing an urease inhibitor and a base, the coat forming a coating on an outer surface of the core. Methods of making and using the fertilizer granule are also disclosed.

A fertilizer granule containing a core containing, phosphoric acid and an urea adduct containing urea and calcium sulfate, and a coat containing an urease inhibitor and a base, the coat forming a coating on an outer surface of the core. Methods of making and using the fertilizer granule are also disclosed.

Method for producing a urea calcium sulfate (UCS) adduct is disclosed. The method for producing the UCS adduct, includes contacting urea with a moist phosphogypsum containing 10 wt. % to 30 wt. % of moisture, under conditions sufficient to form a slurry comprising formed UCS adduct.

Method for producing a urea calcium sulfate (UCS) adduct is disclosed. The method for producing the UCS adduct, includes contacting urea with a moist phosphogypsum containing 10 wt. % to 30 wt. % of moisture, under conditions sufficient to form a slurry comprising formed UCS adduct.