Patent classifications
C07F7/00
Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.
CURABLE AND HYGROSCOPIC RESIN COMPOSITION FOR SEALING ELECTRONIC DEVICES, SEALING RESIN, AND ELECTRONIC DEVICE
A curable and hygroscopic resin composition for sealing electronic devices, having at least a (meth)acrylate oligomer (a) having the number-average molecular weight of 1,500 to 5,000, a low molecular weight (meth)acrylate (b) having an average molecular weight of 170 to 500, a moisture-reactive organometallic compound (c), and a polymerization initiator (d), wherein the (meth)acrylate oligomer (a) and the low molecular weight (meth)acrylate (b) are multifunctional (meth)acrylates in which the number of (meth)acryloyl groups is from 1.5 to 3 in one molecule of each of the (meth)acrylate oligomer (a) and the low molecular weight (meth)acrylate (b); a sealing resin; and an electronic device.
ALKANE-SOLUBLE NON-METALLOCENE PRECATALYSTS
A compound of formula (1) as drawn in the description, wherein M is a Group 4 metal, one R is a silicon-containing organic solubilizing group, and the other R is a silicon-containing organic solubilizing group or a silicon-free organic solubilizing group. A method of synthesizing the compound (1). A solution of compound (1) in alkane solvent. A catalyst system comprising or made from compound (1) and an activator. A method of polymerizing an olefin monomer with the catalyst system.
ALKANE-SOLUBLE NON-METALLOCENE PRECATALYSTS
A compound of formula (1) as drawn in the description, wherein M is a Group 4 metal, one R is a silicon-containing organic solubilizing group, and the other R is a silicon-containing organic solubilizing group or a silicon-free organic solubilizing group. A method of synthesizing the compound (1). A solution of compound (1) in alkane solvent. A catalyst system comprising or made from compound (1) and an activator. A method of polymerizing an olefin monomer with the catalyst system.
Ligand Compound, Transition Metal Compound, and Catalyst Composition Including the Same
A ligand compound having a novel structure, a transition metal compound including the same, a catalyst composition including the transition metal compound, and a method of preparing an olefin polymer using the catalyst composition are disclosed herein. In some embodiments, the transition metal compound is represented by Formula 1. In some embodiments, the ligand compound is represented by Formula 2.
PYRIDINE COMPLEX OF ZIRCONIUM, CATALYTIC SYSTEM COMPRISING SAID PYRIDINE COMPLEX OF ZIRCONIUM AND PROCESS OF (CO)POLYMERIZATION OF CONJUGATED DIENES
Pyridine complex of zirconium having general formula (I): Said pyridine complex of zirconium having general formula (I) may advantageously be used in a catalytic system for the (co)polymerization of conjugated dienes.
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Polymerizations for olefin-based polymers
The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: ##STR00001##
Polymerizations for olefin-based polymers
The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: ##STR00001##
Complex compounds of germanium, methods for producing same, and drugs
The invention relates to the development of drugs intended for the prophylaxis and/or treatment of viral diseases caused, in particular, by herpes viruses. What are proposed are complex compounds of germanium having the general structural formula:
Ge.sub.x[AD][CA].sub.y[AA].sub.2 (1), where AD is a derivative of a nitrogenous base of the purine series that has antiviral activity and can be selected from guanine derivatives, such as acyclovir, valacyclovir, gancyclovir and pencyclovir, or from adenine derivatives, such as vidarabine; CA is a hydroxycarboxylic acid which can be selected from acids such as (but not limited to) citric acid, lactic acid and malic acid; AA is an amino acid which can be selected from various a-amino acids, such as arginine, gylcine, lysine and threonine, and where x=1-2, y=2-4 and z=0-2. Complex compounds of germanium have a high level of antiviral and immune-stimulating activity and are readily soluble in water. The above mentioned compounds are produced by producing an aqueous suspension of germanium dioxide, adding a hydroxycarboxylic acid, a derivative of a nitrogenous base of the purine series and, optionally, but preferably, an amino acid thereto, heating the mixture produced at a temperature of 40-100° C. for 3-14 hours while stirring and removing the water from the solution, thus producing a complex compound of germanium.
Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility
Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where X is selected from the group consisting of —OR.sup.X or NR.sup.X.sub.2. ##STR00001##