C08B5/00

Phosphoric acid-esterified fine cellulose fiber and method for producing the same

Objects of the present invention are to provide a phosphoric acid-esterified fine cellulose fiber of which slurry shows superior transparency, and to provide a method for producing a phosphorylated fine cellulose fiber showing superior transparency with good efficiency and high yield. According to the present invention, there is provided a phosphoric acid-esterified fine cellulose fiber, of which 0.2 mass % aqueous dispersion shows a solution haze of 15% or lower.

Phosphoric acid-esterified fine cellulose fiber and method for producing the same

Objects of the present invention are to provide a phosphoric acid-esterified fine cellulose fiber of which slurry shows superior transparency, and to provide a method for producing a phosphorylated fine cellulose fiber showing superior transparency with good efficiency and high yield. According to the present invention, there is provided a phosphoric acid-esterified fine cellulose fiber, of which 0.2 mass % aqueous dispersion shows a solution haze of 15% or lower.

Fine cellulose fiber-containing substance, method for manufacturing the same, and fine cellulose fiber dispersion
11220787 · 2022-01-11 · ·

A fine cellulose fiber-containing substance that has excellent dispersibility in water and can be manufactured easily. A method is for manufacturing the fine cellulose fiber-containing substance, and a method is for manufacturing a fine cellulose fiber dispersion. A fine cellulose fiber-containing substance contains fine cellulose fibers into which a phosphite containing a cation of an inorganic substance is introduced. The ratio of the cation of the inorganic substance with respect to 1 g of the fine cellulose fibers is 0.14 mmol or more. In manufacturing the fine cellulose fiber-containing substance, a phosphite is introduced into cellulose fibers, and then the cellulose fibers are defibrated to obtain a dispersion containing fine cellulose fibers, during which an alkali metal ion-containing substance is added to the cellulose fibers, and the dispersion is concentrated. In manufacturing a fine cellulose fiber dispersion, the fine cellulose fiber-containing substance is mixed with water.

FIBROUS CELLULOSE, FIBROUS CELLULOSE DISPERSION, AND PRODUCTION METHOD FOR FIBROUS CELLULOSE
20220002442 · 2022-01-06 · ·

An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa.Math.s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100

FIBROUS CELLULOSE, FIBROUS CELLULOSE DISPERSION, AND PRODUCTION METHOD FOR FIBROUS CELLULOSE
20220002442 · 2022-01-06 · ·

An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa.Math.s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100

COMPOSITE PARTICLES, METHOD OF PRODUCING COMPOSITE PARTICLES AND DRY POWDER OF COMPOSITE PARTICLES, SKIN APPLICATION COMPOSITION AND METHOD OF PRODUCING THE SKIN APPLICATION COMPOSITION
20230320972 · 2023-10-12 · ·

Composite particles that are biodegradable and easy to handle while maintaining the characteristics of cellulose nanofibers, a method of producing composite particles, a dry powder containing the composite particles, and a skin application composition and a method of producing the skin application composition. A composite particle contains at least one type of particle and fine cellulose with which at least part of a surface of the particle is coated, wherein the particle and the fine cellulose are inseparable.

Fine cellulose fiber and method for producing same
11441243 · 2022-09-13 · ·

Fine cellulose fiber has a dispersion with a very high transparency and viscosity. A method is for producing the fine cellulose fiber. In the cellulose fiber, a part of hydroxy groups of cellulose fiber is substituted with a predetermined functional group to introduce an ester of phosphorus-oxo acid, and substituted with a carbamate group to introduce a carbamate. The method for producing fine cellulose fiber includes adding an additive (A) and an additive (B) including at least one of urea and a urea derivative to cellulose fiber, heating the mixture at 100 to 210° C., washing the mixture, and then fibrillating the mixture, the additive (B) being added in an amount of 0.01 to 100 mol based on 1 mol of the additive (A).

CELLULOSE FIBERS, CELLULOSE FIBER-CONTAINING MATERIAL, MOLDED BODY, AND METHOD FOR PRODUCING CELLULOSE FIBERS
20220098798 · 2022-03-31 · ·

The present invention is intended to enhance the transparency of a composition obtained using ultrafine cellulose fibers having phosphorous acid groups, while suppressing the yellowing of the ultrafine cellulose fibers. The present invention relates to cellulose fibers having a fiber width of 1000 nm or less and having a phosphorus oxoacid group or a phosphorus oxoacid group-derived substituent, wherein when a first amount of dissociated acid in the cellulose fibers is set to be A1 and a total amount of dissociated acid in the cellulose fibers is set to be A2, A1 is 1.35 mmol/g or more, and the value of A1/A2 is 0.51 or more, and when a sheet is formed under a predetermined condition, the YI value of the sheet is 6.0 or less.

METHOD FOR PRODUCING CELLULOSE FIBERS, CELLULOSE FIBER-DISPERSED SOLUTION, AND SHEET

The present invention is intended to provide ultrafine cellulose fibers capable of enhancing the transparency of an ultrafine cellulose fiber-dispersed solution having phosphorous acid groups. The present invention relates to a method for producing cellulose fibers, comprising: mixing a compound having a phosphorous acid group and/or a salt thereof and urea and/or a urea derivative into a cellulose raw material to obtain a phosphorous acid esterified cellulose raw material, and performing a fibrillation treatment on the phosphorous acid esterified cellulose raw material to obtain cellulose fibers having a fiber width of 1000 nm or less and having a phosphorous acid group, wherein, in obtaining the phosphorous acid esterified cellulose raw material, the decomposition percentage of the urea and/or the urea derivative is set to be 90% or less.

METHOD FOR PRODUCING CELLULOSE FIBERS, CELLULOSE FIBER-DISPERSED SOLUTION, AND SHEET

The present invention is intended to provide ultrafine cellulose fibers capable of enhancing the transparency of an ultrafine cellulose fiber-dispersed solution having phosphorous acid groups. The present invention relates to a method for producing cellulose fibers, comprising: mixing a compound having a phosphorous acid group and/or a salt thereof and urea and/or a urea derivative into a cellulose raw material to obtain a phosphorous acid esterified cellulose raw material, and performing a fibrillation treatment on the phosphorous acid esterified cellulose raw material to obtain cellulose fibers having a fiber width of 1000 nm or less and having a phosphorous acid group, wherein, in obtaining the phosphorous acid esterified cellulose raw material, the decomposition percentage of the urea and/or the urea derivative is set to be 90% or less.