C08F10/00

Emission Free Fluff Transfer System and Integrated Nitrogen Cycle
20230127887 · 2023-04-27 ·

A hydrocarbon recovery system is integrated with a fluff transfer system. The hydrocarbon recovery system is configured for contacting a wet polymer fluff with a purge gas to provide a purged polymer fluff and an overhead stream, and separating a solids stream, a recovered hydrocarbon stream, and a recovered purge gas from the overhead stream. The polymer fluff transfer system is configured to receive the purged polymer fluff from the hydrocarbon recovery system and transport the purged polymer fluff in the fluff transfer system via circulation of a fluff transfer gas. The hydrocarbon recovery system and the fluff transfer system are integrated by utilizing fluff transfer gas from the fluff transfer system as the purge gas in the hydrocarbon recovery system and/or by utilizing at least a portion of the recovered purge gas from the hydrocarbon recovery system in the fluff transfer system as the fluff transfer gas.

Emission Free Fluff Transfer System and Integrated Nitrogen Cycle
20230127887 · 2023-04-27 ·

A hydrocarbon recovery system is integrated with a fluff transfer system. The hydrocarbon recovery system is configured for contacting a wet polymer fluff with a purge gas to provide a purged polymer fluff and an overhead stream, and separating a solids stream, a recovered hydrocarbon stream, and a recovered purge gas from the overhead stream. The polymer fluff transfer system is configured to receive the purged polymer fluff from the hydrocarbon recovery system and transport the purged polymer fluff in the fluff transfer system via circulation of a fluff transfer gas. The hydrocarbon recovery system and the fluff transfer system are integrated by utilizing fluff transfer gas from the fluff transfer system as the purge gas in the hydrocarbon recovery system and/or by utilizing at least a portion of the recovered purge gas from the hydrocarbon recovery system in the fluff transfer system as the fluff transfer gas.

Vent gas purge optimizer for slurry loop polyethylene reactors

A method for minimizing the amount of catalyst inactivating agent that is present in a liquid fraction recovered from a slurry-based polymer production process, the liquid fraction comprising diluent used in the polymer production process, is disclosed. The method includes steps for controlling the pressure over the liquid fraction collected during diluent recovery so as to minimize the concentration of catalyst inactivating agent that is retained in the recovered liquid fraction. Embodiments of apparatus suitable for conducting the disclosed method are also provided.

Vent gas purge optimizer for slurry loop polyethylene reactors

A method for minimizing the amount of catalyst inactivating agent that is present in a liquid fraction recovered from a slurry-based polymer production process, the liquid fraction comprising diluent used in the polymer production process, is disclosed. The method includes steps for controlling the pressure over the liquid fraction collected during diluent recovery so as to minimize the concentration of catalyst inactivating agent that is retained in the recovered liquid fraction. Embodiments of apparatus suitable for conducting the disclosed method are also provided.

Process for Preparing a Transition Metal Compound
20230118712 · 2023-04-20 ·

The present invention relates to a process for preparing a transition metal compound. Specifically, the present invention relates to a process for preparing a transition metal compound having a non-bridged, asymmetric biscyclopentadienyl group that can be used in the preparation of a catalyst for olefin polymerization. The process for preparing a transition metal compound according to an embodiment of the present invention is capable of conveniently preparing a transition metal compound having a non-bridged, asymmetric biscyclopentadienyl group.

Process for Preparing a Transition Metal Compound
20230118712 · 2023-04-20 ·

The present invention relates to a process for preparing a transition metal compound. Specifically, the present invention relates to a process for preparing a transition metal compound having a non-bridged, asymmetric biscyclopentadienyl group that can be used in the preparation of a catalyst for olefin polymerization. The process for preparing a transition metal compound according to an embodiment of the present invention is capable of conveniently preparing a transition metal compound having a non-bridged, asymmetric biscyclopentadienyl group.

SYSTEM AND METHOD FOR IMPROVING DUMP TANK PURGE TIME

A system including a dump tank to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, the dump tank including a vessel with a reactor product inlet, a motive gas inlet, a purge gas inlet, gas outlet(s), and a fluid outlet, the motive gas inlet for introducing a motive gas into the vessel, the purge gas inlet for introducing a purge gas into the vessel, the one or more gas outlets located at a top of the vessel and the fluid outlet located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer fluidly connected with the dump tank fluid outlet line to allow passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line.

Metallocene compounds, and preparation and use thereof for synthesis of poly-alpha-olefins as lubricating base oil
11655264 · 2023-05-23 ·

The present invention relates to a metallocene compound, and preparation and use thereof, and the compound can be used as a catalyst for synthesis of poly-α-olefin as lubricating base oil. The metallocene compound includes a substituted aryl group, a bridged atom, an optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] pyridyl group or optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] thiopyranyl group, and a metal coordination group. As a catalyst, the metallocene compound is shown to be structurally stable and high in catalytic efficiency, and the preparation of the catalyst is relatively easy in operation, high in yield, low in cost, low in pollution and easy to scale up for industrial production.

Metallocene compounds, and preparation and use thereof for synthesis of poly-alpha-olefins as lubricating base oil
11655264 · 2023-05-23 ·

The present invention relates to a metallocene compound, and preparation and use thereof, and the compound can be used as a catalyst for synthesis of poly-α-olefin as lubricating base oil. The metallocene compound includes a substituted aryl group, a bridged atom, an optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] pyridyl group or optionally unsubstituted, 3-mono-substituted or 3,6-disubstituted 5H-indeno [1,2-b] thiopyranyl group, and a metal coordination group. As a catalyst, the metallocene compound is shown to be structurally stable and high in catalytic efficiency, and the preparation of the catalyst is relatively easy in operation, high in yield, low in cost, low in pollution and easy to scale up for industrial production.

POST-METALLOCENE COMPOUNDS

The present invention relates to a compound according to formula 1: wherein: •each of R.sub.1 to R.sub.12 may individually be a moiety selected from hydrogen, an aryl moiety, an aryl moiety, a halogen, an alkyl or aryl moiety with halogen substituent(s), an alkoxy moiety, a siloxy moiety, or a nitrogen-containing moiety, wherein each R moiety may optionally form a ring structure with an adjacent R moiety; •each of A.sub.1 and A.sub.2 may individually be a moiety selected from: o an element of Group 16 of the periodic system; and o a moiety containing an element of Group 15 of the periodic system; preferably wherein A.sub.1 and A.sub.2 are selected from O or NR.sub.13, wherein R.sub.13 is an alkyl, aryl or aralkyl moiety, preferably a substituted or unsubstituted phenyl moiety, preferably a p-tolyl moiety; •T is a divalent hydrocarbyl moiety; •D is a substituted element of Group 15 or Group 16 of the periodic system, preferably an N(R.sub.14).sub.2 or OR.sub.14 moiety, in which R.sub.14 is selected to be an alkyl moiety, an aryl moiety, or an aralkyl moiety, preferably R.sub.14 is a methyl moiety; •Y is an element selected from Group 15 of the periodic system, preferably N; •Mt is a transition metal, preferably selected from Group 3 or 4 of the periodic system, more preferably selected from Ti, Hf and Zr; •X is a sigma-bonded ligand, preferably selected from a halogen, an alkyl moiety, an aralkyl moiety, an alkoxy moiety, an aryloxy moiety, and a dialkylamine moiety; and Classification: General Business Use •n is the amount of X ligands bonded to X. Such compound allow for use in catalysts that result in high molecular weight polymers, display high catalyst activities and give excellent comonomer incorporation.