C08F10/00

NEW POLYOLEFIN CATALYST AND USE THEREOF
20170349675 · 2017-12-07 ·

Disclosed is a new polyolefin catalyst and preparation therefor. Specifically, disclosed is a catalytic system comprising a new complex of iron, cobalt, nickel, palladium, and platinum. In the presence of the catalytic system, oily polyethylene can be efficiently obtained from simple olefins such as ethylene under mild conditions, highly branched oily alkane mixture is then obtained after hydrogenation. The alkane mixture can be used as a processing aid and a high-performance lubricant base oil. The present invention also provides a method for preparing the catalyst, a method for preparing the highly branched oily alkane mixture and a method for preparing functional polyolefin oil.

TRANSITION METAL COMPOUND AND CATALYST COMPOSITION INCLUDING THE SAME

The present disclosure provides a novel transition metal compound having excellent structural stability together with polymerization reactivity, and thereby is useful as a catalyst in preparing an olefin-based polymer, particularly, a low density olefin-based polymer, and a catalyst composition including the same.

TRANSITION METAL COMPOUND AND CATALYST COMPOSITION INCLUDING THE SAME

The present disclosure provides a novel transition metal compound having excellent structural stability together with polymerization reactivity, and thereby is useful as a catalyst in preparing an olefin-based polymer, particularly, a high molecular weight and low density olefin-based polymer, and a catalyst composition including the same.

Aqueous Composition for Hard Surface Applications with Enhanced Stability
20170349739 · 2017-12-07 ·

The present invention relates to an aqueous composition with enhanced stability for hard surface applications containing at least one lipophilic compound and at least one copolymer, in which the at least one copolymer is a comb-type branched copolymer exhibiting an alternating sequence of monomeric units (a) having at least one hydrophilic group and monomeric units (b) having at least one lipophilic side chain. Moreover, a method for producing said composition as well as the use of the composition is concerned.

Aqueous Composition for Hard Surface Applications with Enhanced Stability
20170349739 · 2017-12-07 ·

The present invention relates to an aqueous composition with enhanced stability for hard surface applications containing at least one lipophilic compound and at least one copolymer, in which the at least one copolymer is a comb-type branched copolymer exhibiting an alternating sequence of monomeric units (a) having at least one hydrophilic group and monomeric units (b) having at least one lipophilic side chain. Moreover, a method for producing said composition as well as the use of the composition is concerned.

POLYOLEFIN PROCESS MONITORING AND CONTROL

Methods of controlling olefin polymerization reactor systems may include a) selecting n input variables, each input variable corresponding to a process condition for an olefin polymerization process; b) identifying m response variables corresponding to a measurable polymer property; c) adjusting one of more of the n input variables using the olefin polymerization reactor system and measuring each of the m response variables as a function of the input variables for olefin polymers; d) analyzing the change in each of the response variables as a function of the input variables to determine coefficients; e) calculating a Response Surface Model (RSM) for each response variable determined in step d); f) applying n selected input variables to the calculated RSM to predict one or more of m target response variables; and g) using the n selected input variables to operate the olefin polymerization reactor system and provide a polyolefin product.

Cyclopropyl substituted metallocene catalysts

This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.

Cyclopropyl substituted metallocene catalysts

This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.

PROCESS FOR TRANSITIONING BETWEEN INCOMPATIBLE CATALYSTS
20170342174 · 2017-11-30 ·

The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.

PROCESS FOR TRANSITIONING BETWEEN INCOMPATIBLE CATALYSTS
20170342174 · 2017-11-30 ·

The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.