The invention relates to an aqueous polymer dispersion which comprises: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived from a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,

with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers also a specific process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives and the resulting adhesive.

Disclosed is a flame-retardant HIPS material and a preparation method thereof, comprising the following components: 79 parts to 91 parts of a HIPS resin; 2 parts to 8 parts of a brominated flame retardant; and 3 parts to 7 parts of an auxiliary flame retardant; wherein the auxiliary flame retardant is a 1,3,5-triazine compound. In the present invention, a synergistic compounding of the brominated flame retardant and the auxiliary flame retardant effectively reduces an amount of the brominated flame retardant, and a stable UL 94 (1.5 mm) V-2 flame-retardant class can be achieved. Compared with the existing brominated flame-retardant HIPS, the present invention has a low halogen content, low gas, high cost performance ratio, relatively good thermal stability, and relatively light corrosiveness to the mold, and can be widely applied in the field of thin-walled parts, such as office equipment, video multimedia, household appliances and the like.

Disclosed is a flame-retardant HIPS material and a preparation method thereof, comprising the following components: 79 parts to 91 parts of a HIPS resin; 2 parts to 8 parts of a brominated flame retardant; and 3 parts to 7 parts of an auxiliary flame retardant; wherein the auxiliary flame retardant is a 1,3,5-triazine compound. In the present invention, a synergistic compounding of the brominated flame retardant and the auxiliary flame retardant effectively reduces an amount of the brominated flame retardant, and a stable UL 94 (1.5 mm) V-2 flame-retardant class can be achieved. Compared with the existing brominated flame-retardant HIPS, the present invention has a low halogen content, low gas, high cost performance ratio, relatively good thermal stability, and relatively light corrosiveness to the mold, and can be widely applied in the field of thin-walled parts, such as office equipment, video multimedia, household appliances and the like.

To provide a resin composition for plating and a plated molded article which are excellent in impact resistance and fluidity and which satisfy plating adhesion strength, plating deposition rate and thermal cycle resistance in a well-balanced manner.

A resin composition for plating, containing a polycarbonate resin (A), a graft copolymer (B) and a copolymer (C), wherein the resin composition satisfies the following conditions (1) to (5): (1) a content of the polycarbonate resin (A) is 20 to 60% by mass based on 100% by mass of a total of (A), (B) and (C); (2) the graft copolymer (B) is a graft copolymer obtained by graft polymerization of a rubbery polymer and a monomer component including an aromatic vinyl-based monomer; (3) the copolymer (C) is a copolymer obtained by polymerization of a monomer component including an aromatic vinyl-based monomer and a vinyl cyanide-based monomer; (4) a content of the rubbery polymer is 7 to 20% by mass relative to the resin composition; and (5) a content of an oligomer component is less than 1% by mass relative to the resin composition.

To provide a resin composition for plating and a plated molded article which are excellent in impact resistance and fluidity and which satisfy plating adhesion strength, plating deposition rate and thermal cycle resistance in a well-balanced manner.

A resin composition for plating, containing a polycarbonate resin (A), a graft copolymer (B) and a copolymer (C), wherein the resin composition satisfies the following conditions (1) to (5): (1) a content of the polycarbonate resin (A) is 20 to 60% by mass based on 100% by mass of a total of (A), (B) and (C); (2) the graft copolymer (B) is a graft copolymer obtained by graft polymerization of a rubbery polymer and a monomer component including an aromatic vinyl-based monomer; (3) the copolymer (C) is a copolymer obtained by polymerization of a monomer component including an aromatic vinyl-based monomer and a vinyl cyanide-based monomer; (4) a content of the rubbery polymer is 7 to 20% by mass relative to the resin composition; and (5) a content of an oligomer component is less than 1% by mass relative to the resin composition.

The invention relates to an aqueous polymer dispersion comprising: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived front a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,
with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers a process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives, and the resulting adhesive.

The invention relates to an aqueous polymer dispersion comprising: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived front a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,
with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers a process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives, and the resulting adhesive.

The invention relates to an aqueous polymer dispersion comprising: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived front a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,
with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers a process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives, and the resulting adhesive.

A toner having a toner particle containing a binder resin and a styrene-acrylic resin, the toner being characterized in that the styrene-acrylic resin is a graft polymer having an aliphatic hydrocarbon compound segment and a styrene-acrylic segment, the styrene-acrylic segment has a specific monomer unit, the melting point of the styrene-acrylic segment is from 30 C. to 80 C., and when the toner is measured using a FT-IR ATR method, the intensity assigned to the styrene-acrylic resin and the intensity assigned to the binder resin satisfy a specific relationship.

A toner having a toner particle containing a binder resin and a styrene-acrylic resin, the toner being characterized in that the styrene-acrylic resin is a graft polymer having an aliphatic hydrocarbon compound segment and a styrene-acrylic segment, the styrene-acrylic segment has a specific monomer unit, the melting point of the styrene-acrylic segment is from 30 C. to 80 C., and when the toner is measured using a FT-IR ATR method, the intensity assigned to the styrene-acrylic resin and the intensity assigned to the binder resin satisfy a specific relationship.