The invention provides an aqueous resin dispersion which can form a coating film excellent in adhesion to a polypropylene base material, and water resistance, and has excellent particle stability. Specifically, it provides an aqueous resin dispersion in which an olefin polymer (A), and a polymer (C) containing a constituent unit derived from a radically polymerizable monomer (B) represented by the following general formula (1) are dispersed in an aqueous medium. (In the general formula (1), R is a hydrogen atom or a methyl group, and X is a straight chain or branched alkylene group having 3 to 5 carbon atoms; and n is an integer of 1 to 20.)

This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

(Meth)acrylate-functionalized branched polyalpha-olefins which are the reaction product of, at least, a) a (meth)acrylate source and b) a hydroxyl-functionalized branched polymerizate of, at least, i) one or more alpha-olefin monomers having at least six carbon atoms per molecule and ii) one or more unsaturated hydroxyl-functionalized comonomers are useful hydrophobic, reactive components of crosslinkable resin compositions additionally containing a polymer (such as a polyolefin) as well as curable compositions containing one or more additional types of (meth)acrylate-functionalized compounds.

(Meth)acrylate-functionalized branched polyalpha-olefins which are the reaction product of, at least, a) a (meth)acrylate source and b) a hydroxyl-functionalized branched polymerizate of, at least, i) one or more alpha-olefin monomers having at least six carbon atoms per molecule and ii) one or more unsaturated hydroxyl-functionalized comonomers are useful hydrophobic, reactive components of crosslinkable resin compositions additionally containing a polymer (such as a polyolefin) as well as curable compositions containing one or more additional types of (meth)acrylate-functionalized compounds.

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B). Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an α,β-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an α,β-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller. Resin (B): a polyolefin resin or a modified product thereof.

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B). Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an α,β-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an α,β-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller. Resin (B): a polyolefin resin or a modified product thereof.

This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

The invention is to provide a method for producing an aqueous resin dispersion capable of forming a coating film superior in adhesion to a polypropylene base material, and water resistance. Specifically, the invention provides a method for producing an aqueous resin dispersion, including a step of mixing and polymerizing a polyolefin dispersion (A), a radically polymerizable monomer (B), and a surfactant for emulsion polymerization (C), wherein the amount of the radically polymerizable monomer (B) mixed is 0.5 to 2 times the solid component of the polyolefin dispersion (A) in terms of parts by mass, and the amount of the solid component of the surfactant for emulsion polymerization (C) mixed is 0 to 3 parts by mass with respect to 100 parts by mass of the radically polymerizable monomer (B).