The present invention relates to opaque polymers functionalized with phosphorus acid groups, composites of TiO.sub.2 particles and the opaque polymers, and methods for their preparation. The composites are useful in coatings formulations and have been shown to exhibit improved hiding benefits in coated substrates over compositions containing non-functionalized opaque polymer and TiO.sub.2.

A hydrophilic siloxane copolymer of siloxane and hydrophilic organic monomer/s The copolymers can be functionalized to make them capable of undergoing further polymerization by thermal or actinic radiations. The hydrophilicity of these polymers can be varied by varying the siloxane versus organic monomer ratio thereby going from water dispersible to soluble states. The siloxane content can be tuned accordingly in order to provide moderate to high oxygen permeability. These copolymers can be used as a single component curable composition which results in hydrogels to minimize the presence of leachable components thus by reducing the processing cost. The polymers may also find applications in personal care formulations as copolymers, film-formers, hydrogels, coating, emulsions/latex etc.

The present invention is to provide a dispersant which has excellent dispersibility and which is able to inhibit the oxidation of dispersed particles. Disclosed is a dispersant comprising a graft copolymer having a constitutional unit represented by the following general formula (I) and a constitutional unit represented by the following general formula (II): ##STR00001##
(Symbols shown in the general formulae (I) and (II) are as described in the Description.)

The present invention is to provide a dispersant which has excellent dispersibility and which is able to inhibit the oxidation of dispersed particles. Disclosed is a dispersant comprising a graft copolymer having a constitutional unit represented by the following general formula (I) and a constitutional unit represented by the following general formula (II): ##STR00001##
(Symbols shown in the general formulae (I) and (II) are as described in the Description.)

The object of the present invention is to provide a resin particle having a protrusion that is more resistant to the detachment and having a uniform protrusion size and protrusion distribution density. The resin particle of the present invention comprises: a spherical part and a peripheral part having a plurality of convex part formed on the surface of the spherical part, wherein the spherical part and the peripheral part comprise a vinyl polymer and/or a polysiloxane component, the spherical part and the peripheral part are different in the composition, the melting point of the peripheral part is not less than 200 C., and the curvature center of the boundary between the peripheral part and the spherical part determined by a transmission electron microscope observation of the cross-section of the resin particle exists in the spherical part.

The object of the present invention is to provide a resin particle having a protrusion that is more resistant to the detachment and having a uniform protrusion size and protrusion distribution density. The resin particle of the present invention comprises: a spherical part and a peripheral part having a plurality of convex part formed on the surface of the spherical part, wherein the spherical part and the peripheral part comprise a vinyl polymer and/or a polysiloxane component, the spherical part and the peripheral part are different in the composition, the melting point of the peripheral part is not less than 200 C., and the curvature center of the boundary between the peripheral part and the spherical part determined by a transmission electron microscope observation of the cross-section of the resin particle exists in the spherical part.

The present invention is a process for preparing a stable aqueous dispersion of polymer particles comprising structural units of a phosphorus acid monomer or a salt thereof and structural units of a photoinitiator monomer. Gloss retention of paints containing the latex prepared by the process of the present invention are improved over paints that do not have photoinitiator chemically bound to the latex particles.

The present invention is a process for preparing a stable aqueous dispersion of polymer particles comprising structural units of a phosphorus acid monomer or a salt thereof and structural units of a photoinitiator monomer. Gloss retention of paints containing the latex prepared by the process of the present invention are improved over paints that do not have photoinitiator chemically bound to the latex particles.

Anion-paired metallocene-containing compounds are generally provided, along with methods of making the same. In one embodiment, the anion-paired metallocene-containing compound includes a cationic metallocene moiety covalently connected to an organic functional group, and an anion paired to the cationic metallocene moiety. Generally, the cationic metallocene moiety comprises two cyclopentadienyl anions bound to a metal center in the oxidation state I.

The present invention is a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a phosphorus acid monomer or a salt thereof and structural units of a photoinitiator monomer. Gloss retention of paints containing the latex described herein is markedly improved over paints that do not have photoinitiator chemically bound to the latex particles.