The object of the present invention is to provide a resin particle having a protrusion that is more resistant to the detachment and having a uniform protrusion size and protrusion distribution density. The resin particle of the present invention comprises: a spherical part and a peripheral part having a plurality of convex part formed on the surface of the spherical part, wherein the spherical part and the peripheral part comprise a vinyl polymer and/or a polysiloxane component, the spherical part and the peripheral part are different in the composition, the melting point of the peripheral part is not less than 200 C., and the curvature center of the boundary between the peripheral part and the spherical part determined by a transmission electron microscope observation of the cross-section of the resin particle exists in the spherical part.

The object of the present invention is to provide a resin particle having a protrusion that is more resistant to the detachment and having a uniform protrusion size and protrusion distribution density. The resin particle of the present invention comprises: a spherical part and a peripheral part having a plurality of convex part formed on the surface of the spherical part, wherein the spherical part and the peripheral part comprise a vinyl polymer and/or a polysiloxane component, the spherical part and the peripheral part are different in the composition, the melting point of the peripheral part is not less than 200 C., and the curvature center of the boundary between the peripheral part and the spherical part determined by a transmission electron microscope observation of the cross-section of the resin particle exists in the spherical part.

A latex polymer of multi-stage polymerization comprising a first stage polymer and a second stage polymer wherein the first stage polymer comprises a first portion of an acrylic monomer and a first portion of a phosphorus acid monomer, and the second stage polymer comprises a second portion of an acrylic monomer and a second portion of a phosphorus acid monomer. A process of making such latex polymer.

A latex polymer of multi-stage polymerization comprising a first stage polymer and a second stage polymer wherein the first stage polymer comprises a first portion of an acrylic monomer and a first portion of a phosphorus acid monomer, and the second stage polymer comprises a second portion of an acrylic monomer and a second portion of a phosphorus acid monomer. A process of making such latex polymer.

Anion-paired metallocene-containing compounds are generally provided, along with methods of making the same. In one embodiment, the anion-paired metallocene-containing compound includes a cationic metallocene moiety covalently connected to an organic functional group, and an anion paired to the cationic metallocene moiety. Generally, the cationic metallocene moiety comprises two cyclopentadienyl anions bound to a metal center in the oxidation state I.

A core-shell type polymeric particle may exhibit good dispersibility in an aqueous medium and excellent flame retardance. A core-shell type polymeric particle may include a core including a hydrophobic polymer (c) and a shell including a copolymer having a repeating unit (a) derived from vinyl phosphonic acid or a vinyl phosphonic acid ester and a repeating unit (b) of formula (): ##STR00001##
wherein R.sup.a is H or a methyl group, R.sup.b is a single bond or a carbonyl group, and ring Q.sup.1 is a substituted or unsubstituted 4 to 10 membered nitrogen-containing heterocycle.

A core-shell type polymeric particle may exhibit good dispersibility in an aqueous medium and excellent flame retardance. A core-shell type polymeric particle may include a core including a hydrophobic polymer (c) and a shell including a copolymer having a repeating unit (a) derived from vinyl phosphonic acid or a vinyl phosphonic acid ester and a repeating unit (b) of formula (): ##STR00001##
wherein R.sup.a is H or a methyl group, R.sup.b is a single bond or a carbonyl group, and ring Q.sup.1 is a substituted or unsubstituted 4 to 10 membered nitrogen-containing heterocycle.

The present invention relates to the use of polymer gels in the preparation of polymer brushes. In particular, the present invention relates to polymer gels swelled in the polymerisation medium. The invention further relates to the use of polymer gels in the formation of polymer brushes on a surface. The present invention provides improved methods for forming polymer brushes on a surface, thus, enabling easy large-scale production of polymer brush-coated surfaces. In particular, the present invention enables application of the polymerisation medium on surfaces of all geometries.

The present invention relates to the use of polymer gels in the preparation of polymer brushes. In particular, the present invention relates to polymer gels swelled in the polymerisation medium. The invention further relates to the use of polymer gels in the formation of polymer brushes on a surface. The present invention provides improved methods for forming polymer brushes on a surface, thus, enabling easy large-scale production of polymer brush-coated surfaces. In particular, the present invention enables application of the polymerisation medium on surfaces of all geometries.

The present invention relates to the use of polymer gels in the preparation of polymer brushes. In particular, the present invention relates to polymer gels swelled in the polymerisation medium. The invention further relates to the use of polymer gels in the formation of polymer brushes on a surface. The present invention provides improved methods for forming polymer brushes on a surface, thus, enabling easy large-scale production of polymer brush-coated surfaces. In particular, the present invention enables application of the polymerisation medium on surfaces of all geometries.