The present invention relates to a curable petroleum resin, a preparation method therefor, and use thereof, wherein the curable petroleum resin comprises a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a cyclic anhydride monomer, and wherein the curable petroleum resin is used as an additive for a reactive polyolefin-based adhesive composition to increase the adhesive strength to a polyolefin-based substrate used for various parts.

Provided is a binder composition for a secondary battery with which it is possible to produce a slurry composition for a secondary battery electrode that has excellent preservation stability and can produce an electrode having excellent peel strength. The binder composition for a secondary battery contains a water-soluble polymer and polyvalent metal ions. The water-soluble polymer includes a vinyl alcohol structural unit and a carboxy group-containing monomer unit. The content of the polyvalent metal ions is not less than 0.1 mass ppm and not more than 10,000 mass ppm relative to the water-soluble polymer.

Provided is a binder composition for a secondary battery with which it is possible to produce a slurry composition for a secondary battery electrode that has excellent preservation stability and can produce an electrode having excellent peel strength. The binder composition for a secondary battery contains a water-soluble polymer and polyvalent metal ions. The water-soluble polymer includes a vinyl alcohol structural unit and a carboxy group-containing monomer unit. The content of the polyvalent metal ions is not less than 0.1 mass ppm and not more than 10,000 mass ppm relative to the water-soluble polymer.

The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I:

##STR00001##

where R, R.sup.1, R.sup.2, Y and x are defined herein. The method also requires the use of special classes on anionic and nonionic surfactants as described herein. The aqueous dispersion prepared by the method of the present invention is useful in a variety of applications ranging from architectural coatings to personal care products.

The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I:

##STR00001##

where R, R.sup.1, R.sup.2, Y and x are defined herein. The method also requires the use of special classes on anionic and nonionic surfactants as described herein. The aqueous dispersion prepared by the method of the present invention is useful in a variety of applications ranging from architectural coatings to personal care products.

Disclosed is a composition comprising a multi-stage flexible acrylic resin and a branched polymer which is a reaction product of reactants comprising one or more monoethylenically unsaturated ester monomers, a chain transfer agent in an amount of 0.1 to 15 weight percent, and a crosslinker in an amount of 0.1 to 15 weight percent of a crosslinker, wherein weight percent is based on total amount of reactants, provided the amount of crosslinker is within +/−5 weight percent of the amount of chain transfer agent, and wherein the crosslinker comprises at least two carbon-carbon double bonds having different reactivity, and films thereof.

A crosslinking material, the crosslinking material comprising the reaction product of a reaction mixture comprising: (ii) ≥70% by weight of a cyclic unsaturated acid anhydride and/or diacid derivative thereof by total solid weight of the monomers from which the crosslinking material is formed; (ii) optionally, an ethylenically unsaturated monomer; and (iii) optionally, an alcohol, amine, thiol and/or water, wherein at least a portion of the cyclic unsaturated acid anhydride and/or diacid derivative thereof is reacted with the alcohol, amine, thiol and/or water, when present; and wherein the crosslinking material has an acid number of at least 100 mg KOH/g.

A crosslinking material, the crosslinking material comprising the reaction product of a reaction mixture comprising: (ii) ≥70% by weight of a cyclic unsaturated acid anhydride and/or diacid derivative thereof by total solid weight of the monomers from which the crosslinking material is formed; (ii) optionally, an ethylenically unsaturated monomer; and (iii) optionally, an alcohol, amine, thiol and/or water, wherein at least a portion of the cyclic unsaturated acid anhydride and/or diacid derivative thereof is reacted with the alcohol, amine, thiol and/or water, when present; and wherein the crosslinking material has an acid number of at least 100 mg KOH/g.

Provided is a (meth)acrylic ester copolymer (B) having a reactive silicon group represented by the following formula (1): —SiR.sup.5.sub.cX.sub.3-c (1). R.sup.5 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is a hydroxy group or a hydrolyzable group, and c is 0 or 1. A monomer component of the copolymer includes a (meth)acrylic ester (b1), a (meth)acrylic ester polymer (b2) having more than one (meth)acryloyl groups per molecule, and a chain transfer agent (b3) having a mercapto group. The monomer component further includes a monomer (b4) having a reactive silicon group and a polymerizable unsaturated group, and/or the chain transfer agent (b3) having a mercapto group further has a reactive silicon group.

Provided is a (meth)acrylic ester copolymer (B) having a reactive silicon group represented by the following formula (1): —SiR.sup.5.sub.cX.sub.3-c (1). R.sup.5 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is a hydroxy group or a hydrolyzable group, and c is 0 or 1. A monomer component of the copolymer includes a (meth)acrylic ester (b1), a (meth)acrylic ester polymer (b2) having more than one (meth)acryloyl groups per molecule, and a chain transfer agent (b3) having a mercapto group. The monomer component further includes a monomer (b4) having a reactive silicon group and a polymerizable unsaturated group, and/or the chain transfer agent (b3) having a mercapto group further has a reactive silicon group.