The present invention relates to an impact resistant (meth) acrylic polymer composition. In particular the present invention it relates to impact resistant polymeric composition suitable for glazing or lightning applications. The invention also relates to a process for manufacturing such a polymeric composition suitable for glazing or lightning applications. More particularly the present invention relates to an impact resistant (meth) acrylic polymer composition and relates also to a process for preparing such impact resistant (meth) acrylic polymer composition and its use in glazing or lightning applications.

The present invention relates to an impact resistant (meth) acrylic polymer composition. In particular the present invention it relates to impact resistant polymeric composition suitable for glazing or lightning applications. The invention also relates to a process for manufacturing such a polymeric composition suitable for glazing or lightning applications. More particularly the present invention relates to an impact resistant (meth) acrylic polymer composition and relates also to a process for preparing such impact resistant (meth) acrylic polymer composition and its use in glazing or lightning applications.

Low dielectric constant curable compositions include a first alkyl (meth)acrylate monomer with 12 or more carbon atoms, a crosslinking monomer, a copolymeric additive of a polyisobutylene-polysiloxane block copolymer, and at least one initiator. The curable composition is solvent free and inkjet printable. Upon curing the curable composition forms a non-crystalline, optically clear layer with a dielectric constant of less than or equal to 3.0 at 1 MegaHertz.

Low dielectric constant curable compositions include a first alkyl (meth)acrylate monomer with 12 or more carbon atoms, a crosslinking monomer, a copolymeric additive of a polyisobutylene-polysiloxane block copolymer, and at least one initiator. The curable composition is solvent free and inkjet printable. Upon curing the curable composition forms a non-crystalline, optically clear layer with a dielectric constant of less than or equal to 3.0 at 1 MegaHertz.

It becomes possible to produce a thermoplastic resin composition having a sea-island structure by a kneading step of kneading a thermoplastic elastomer and/or rubber material having an alkoxysilyl group, in which the alkoxysilyl group is grafted to the thermoplastic elastomer and/or rubber material, and a thermoplastic resin in a melt state in a kneading machine and a dynamic crosslinking step of adding a water component into the kneading machine, forming a silanol group by a hydrolysis reaction of the alkoxysilyl group in the thermoplastic elastomer and/or rubber material having an alkoxysilyl group and the water component in the kneading machine, and subsequently forming a siloxane bond by a condensation reaction between the silanol groups.

It becomes possible to produce a thermoplastic resin composition having a sea-island structure by a kneading step of kneading a thermoplastic elastomer and/or rubber material having an alkoxysilyl group, in which the alkoxysilyl group is grafted to the thermoplastic elastomer and/or rubber material, and a thermoplastic resin in a melt state in a kneading machine and a dynamic crosslinking step of adding a water component into the kneading machine, forming a silanol group by a hydrolysis reaction of the alkoxysilyl group in the thermoplastic elastomer and/or rubber material having an alkoxysilyl group and the water component in the kneading machine, and subsequently forming a siloxane bond by a condensation reaction between the silanol groups.

A multiblock, cationic-functionalized norbornene copolymer is formed by a process including performing a vinyl addition polymerization in the presence of a metal catalyst of a first norbornene monomer substituted with a first alkyl group and a second norbornene monomer substituted with a second alkyl group by adding a predetermined amount of the first norbornene monomer and a predetermined amount of the second norbornene monomer sequentially to the reaction to form blocks of an intermediate norbornene multiblock copolymer. The second alkyl group includes a substituent which undergoes a reaction with a precursor for a cationic group having a volume less than 0.25 cm.sup.3/mol. The process further includes reacting the precursor for the cationic group with the intermediate norbornene multiblock copolymer to form the multiblock, cationic-functionalized norborene copolymer.

A multiblock, cationic-functionalized norbornene copolymer is formed by a process including performing a vinyl addition polymerization in the presence of a metal catalyst of a first norbornene monomer substituted with a first alkyl group and a second norbornene monomer substituted with a second alkyl group by adding a predetermined amount of the first norbornene monomer and a predetermined amount of the second norbornene monomer sequentially to the reaction to form blocks of an intermediate norbornene multiblock copolymer. The second alkyl group includes a substituent which undergoes a reaction with a precursor for a cationic group having a volume less than 0.25 cm.sup.3/mol. The process further includes reacting the precursor for the cationic group with the intermediate norbornene multiblock copolymer to form the multiblock, cationic-functionalized norborene copolymer.

A statistical, cationic-functionalized norbornene copolymer is formed by a process including performing a vinyl addition polymerization in the presence of a metal catalyst of a first norbornene monomer substituted with a first alkyl group and at least a second norbornene monomer substituted with a second alkyl group, to form an intermediate norbornene copolymer. The second alkyl group includes a substituent which undergoes a substitution reaction with a precursor of a cationic group. The process further includes adding the precursor for the cationic group to the intermediate norbornene copolymer to form the cationic functionalized norbornene copolymer. The cationic group has a volume of 0.25 cm.sup.3/mol or greater (for example, a phosphonium group or an imidazolium group).

A statistical, cationic-functionalized norbornene copolymer is formed by a process including performing a vinyl addition polymerization in the presence of a metal catalyst of a first norbornene monomer substituted with a first alkyl group and at least a second norbornene monomer substituted with a second alkyl group, to form an intermediate norbornene copolymer. The second alkyl group includes a substituent which undergoes a substitution reaction with a precursor of a cationic group. The process further includes adding the precursor for the cationic group to the intermediate norbornene copolymer to form the cationic functionalized norbornene copolymer. The cationic group has a volume of 0.25 cm.sup.3/mol or greater (for example, a phosphonium group or an imidazolium group).